Article
Mining & Mineral Processing
Huihui Zeng, Baolin Xing, Yijun Cao, Bing Xu, Lei Hou, Hui Guo, Song Cheng, Guangxu Huang, Chuanxiang Zhang, Qi Sun
Summary: The materialization of coal is an effective and clean pathway for its utilization, and the microstructures of coal-based carbon materials play a crucial role in their functional applications. This study systematically investigates the microstructural evolution of anthracite in the temperature range of 1000-2800 degrees C, providing guidance for the regulation of microstructure in coal-based carbon materials.
INTERNATIONAL JOURNAL OF MINING SCIENCE AND TECHNOLOGY
(2022)
Article
Chemistry, Physical
Daniel J. Rodriguez, Chris Y. Lau, Bryan A. Long, Susanna An Tang, Abigail M. Friese, Scott L. Anderson
Summary: The kinetics of O-2 oxidation for individual graphite and graphene platelet nanoparticles were studied at different temperatures and oxygen partial pressures. The initial oxidation efficiency peaked in the 1200-1500 K range and decreased as temperature increased above 2000 K. Variations in oxidation rates and efficiencies were attributed to differences in the nanoparticles' surface structures.
Article
Chemistry, Physical
Fucheng Xie, Yangpeng Duan, Gaoming Mo, Qing Huang, Zhengren Huang
Summary: PACS is synthesized with higher Al content and its structural evolution and changes in Al structure forms during the polymer-ceramic conversion process are investigated by various analyses. It is found that amorphous SiOxCy, AlOxSiy, and free carbon phases are initially formed. With increasing temperature, SiOxCy separates into SiO2 and reacts with free carbon. The AlOxSiy phase transforms into Al3C4 and Al2O3. Complex reactions occur between Al3C4, Al2O3, and free carbon, leading to the formation of Al4O4C and Al2OC phases. These phases then react with SiC and free carbon to form Al4SiC4. The amorphous carbon phase grows and transforms into a graphitic structure. The existence of Al4O4C, Al2OC, and Al4SiC4 inhibits the growth of beta-SiC and favors the formation of alpha-SiC.
Article
Chemistry, Physical
Shigeharu Takagi, Keiji Shimoda, Jun Haruyama, Hisao Kiuchi, Ken-ichi Okazaki, Toshiharu Fukunaga, Zempachi Ogumi, Takeshi Abe
Summary: In this study, operando structural analyses of graphite electrode in lithium-ion batteries were performed using neutron diffraction and synchrotron radiation X-ray diffraction. The results provide insights into the phase evolution and structural transition of lithium-intercalated graphite. The study reveals that the in-plane structure of graphite transitions from LiC6-type to LiC9-type during lithium de-intercalation, and the LiC9-type arrangement is retained in Li-poor phases. This research is significant for understanding the structural changes in lithium-ion battery materials.
Article
Nanoscience & Nanotechnology
Camila Mora, Antonio Buljan, Toribio Figueroa
Summary: The oxidation reaction of graphite with potassium permanganate in sulfuric acid was studied, and the reaction conditions and sample washing process were analyzed. It was found that longer reaction times, appropriate proportion of potassium permanganate, and room temperature conditions are beneficial for solubility and avoiding damage to the carbon structure. Water was identified as the medium for oxygen transfer during the washing process. Based on these findings, the graphite oxidation process was redefined.
ACS APPLIED NANO MATERIALS
(2022)
Article
Chemistry, Applied
Shisheng Liang, Yucui Hou, Weize Wu, He Li, Zhuosen He, Shuhang Ren
Summary: Direct coal liquefaction is crucial for the global energy industry, with solid coal particles and their residues serving as both reactants and catalyst carriers. The structural characteristics of these residues show changes in the aromatic structure and graphitization degree during the process. This study provides insights into the transformation of coal during liquefaction.
FUEL PROCESSING TECHNOLOGY
(2021)
Article
Energy & Fuels
Ya-fei Chen, Hong Yin, Dong-lin He, Hai-feng Gong, Zhe-zhi Liu, Yun-qi Liu, Xian-ming Zhang, Wan-fen Pu
Summary: This study investigates the evolution of low temperature oxidized coke generated from the pyrolysis of ultra-heavy oil during in-situ combustion. The results show that low temperature oxidation leads to the formation of oxidation groups and promotes the evolution of aromatic structures and functional groups. Additionally, low temperature oxidation reactions have a significant impact on the morphology, oxidizability, and exothermicity of the coke.
Article
Energy & Fuels
Umanga De Silva, Jennifer See, Wipula P. R. Liyanage, Jahangir Masud, Jinpeng Wu, Wanli Yang, Wei-Ting Chen, David Prendergast, Manashi Nath
Summary: This study investigated the evolution of the active surface composition for nickel-selenide and -telluride-based electrocatalysts by intentionally creating nickel-oxide-coated surfaces. The results confirmed the stability of the catalytically active chalcogenide surfaces in alkaline medium, providing evidence that the surface evolves into a mixed anionic (hydroxo)chalcogenide surface. The study also highlighted the significant differences in electrochemical properties between oxide-coated, selenide, and telluride surfaces, emphasizing the importance of understanding the composition changes in chalcogenide surfaces using electrochemical properties.
Article
Chemistry, Analytical
Zhichen Zhang, Kun Chen, Dong Liu, Bin Lou, Min Li, Shuhai Guo, Ran Yu, Bo Wu, Xin Gong, Gang Li
Summary: The study compared needle coke prepared from petroleum feedstock HCTO and coal feedstock LCT, revealing the effects of colloids and phenolic compounds in LCT3 on the carbonaceous structure evolution. Additionally, the calcination process was found to exacerbate structural defects and strains in the pyrolysis products.
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
(2021)
Article
Polymer Science
Dao-Xin Zhang, Lei Ding, Feng Yang, Fang Lan, Ya Cao, Ming Xiang
Summary: This study found that different stretching methods led to different lamellar structural evolution and microvoid variations in beta polypropylene (beta-PP). Simultaneous biaxial stretching resulted in better mechanical properties for the microporous membranes, compared to sequential biaxial stretching.
CHINESE JOURNAL OF POLYMER SCIENCE
(2021)
Article
Energy & Fuels
Hao Zhang, Kuo Li, Junmin Sun, Zhiming Sun, Liang Yuan, Qinfu Liu
Summary: In this study, a series of naturally graphitized coals were characterized using various analysis methods. It was found that the proportion of ordered graphite increased during graphitization, and the compact aromatic rings gradually transformed to loose aromatic rings. The structural evolution can be divided into three stages.
Article
Metallurgy & Metallurgical Engineering
Yu Chen, Jian-chao Pang, Shou-xin Li, Zhe-feng Zhang
Summary: This study investigated the high-temperature oxidation behavior of vermicular graphite iron, finding that oxidation pores and oxide layer often appear on the specimen surface. The oxidation mechanism can be described by a linear relationship, which changes as the oxidation time prolongs.
ACTA METALLURGICA SINICA-ENGLISH LETTERS
(2022)
Article
Chemistry, Multidisciplinary
Zahra Khalilzadeh, Mohsen Abbaspour, Farrokhzad Mohammadi Zonoz
Summary: This study investigates the thermal properties and melting process of polyoxometalate ionic liquids confined into carbon nanotubes using molecular dynamics simulations. The results show that the confined ionic liquids have a higher melting point and thermal stability, with a sharp increase in ion conductivity and self-diffusion coefficient at the melting point.
Article
Chemistry, Physical
Yi Je Cho, David Garcia, Hang Z. Yu, Zhifei Deng, Ling Li, Kathy Lu
Summary: Matrix-grade graphite ARB-B1 oxidation behavior was studied under simulated water ingress accidental conditions, revealing an activation energy of 121.5 kJ/mol and primarily pore diffusion assisted by cracks as the oxidation mechanism. The cracks, originating from the fabrication process, played a crucial role in the oxidation behavior.
Article
Environmental Sciences
Antoine P. Trzcinski, Kouji Harada
Summary: This study demonstrates a novel PFAS remediation process involving adsorption onto graphite intercalated compounds (GIC) and electrochemical oxidation. The process showed efficient adsorption and degradation of PFOS, as well as the production of short chain PFAS by-products.