期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 21, 页码 6302-6305出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201501054
关键词
alkynes; carboxylic acids; palladium; Pligands; synthetic methods
资金
- National Natural Science Foundation of China
- National Basic Research Program of China [2012CB821600]
- Ministry of Education of China [B06005]
A palladium-catalyzed hydrocarboxylation of alkynes with formic acid has been developed. The method provides acrylic acid and derivatives in good yields with high regioselectivity without the need to handle toxic CO gas.
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