期刊
CHINESE JOURNAL OF ORGANIC CHEMISTRY
卷 34, 期 10, 页码 1966-1977出版社
SCIENCE PRESS
DOI: 10.6023/cjoc201404041
关键词
pyrrolophenanthridone; methodology; cross-coupling reaction; transition-metal catalyzed; radical reaction
资金
- National Natural Science Foundation of China [21272276]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1193]
Pyrrolophenanthridone is a common structural motif existing in a number of amaryllidaceae alkaloids, many of which possess a wide range of biological activities. The intriguing structural feature and significant biological activity have attracted much attention from synthetic communities. In the past decades, several excellent synthetic methodologies have been reported, in which intramolecular or intermolecular cross-coupling reaction through transition-metal catalyzed or radical pathway represents the most straightforward method for construction of this skeleton. This review focuses on the construction of pyrrolophenanthridone skeleton and total synthesis of amaryllidaceae alkaloids.
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