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Recent Progress in the Research of the Transition-Metal-Catalyzed C-CN Bonds Coupling Reactions

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CHINESE JOURNAL OF ORGANIC CHEMISTRY
卷 32, 期 2, 页码 294-303

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SCIENCE PRESS
DOI: 10.6023/cjoc1107281

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transition metal; cyanation reaction; reaction mechanism

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Transition-metal-catalyzed cyanation reaction is one of the most attractive modern methods for the synthesis of organic cyanides. Recent development of the transition-metal-catalyzed C-CN bonds coupling reactions is reviewed, which includes the cyanation reactions of aryl, vinyl halides and pseudohalides, arylboronic acids and alkene, alkyne, aromatic hydrocarbon. Their mechanisms are discussed.

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