期刊
CHINESE JOURNAL OF CHEMISTRY
卷 32, 期 9, 页码 833-837出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201400167
关键词
azidotrifluoromethylation; alkenes; azide-containing
资金
- Gansu Province Key Laboratory of Fine Chemical [1206RTSA022]
- Gansu Province Science and Technology Innovation Service Platform Construction Plan [1306TTPA024]
- Gansu Province Containing Fluorine Meticulous Chemicals R&D Platform Project
- Program for Pharmaceutical Intermediates Innovation Research Team in Gansu Province [1207TTCA009]
A novel three-component strategy for the azidotrifluoromethylation of alkenes has been presented here. The reaction proceeded smoothly under gentle temperature and gave the bifunctional olefins in high yields. Furthermore, 1,3-dipolar reactions between azide-containing products and phenylacetylene revealed great potential in molecular modification by using this method.
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