4.5 Article

Metal-Free-Mediated Oxidation Aromatization of 1,4-Dihydropyridines to Pyridines Using Visible Light and Air

期刊

CHINESE JOURNAL OF CHEMISTRY
卷 32, 期 12, 页码 1245-1250

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201400521

关键词

visible light irradiation; eosin Y; molecular oxygen; aromatization; photooxidation

资金

  1. National Natural Science Foundation of China [21172102]
  2. Ministry of Science and Technology of China [2013CB834804]
  3. Fundamental Research Funds for the Central Universities [lzujbky-2013-47]

向作者/读者索取更多资源

A metal-free and environmentally friendly aerobic aromatization photosensitized by organic dye eosin Y bis(tetrabutyl ammonium salt) (TBA-eosinY) has been developed. With the aid of K2CO3, the aerobic catalytic system converts 1,4-dihydropyridines to their corresponding pyridine derivatives efficiently under visible light irradiation (lambda=450 nm) at room temperature.

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