4.5 Article

Influence of A-type Zeolite on Methane Hydrate Formation

期刊

CHINESE JOURNAL OF CHEMICAL ENGINEERING
卷 17, 期 5, 页码 854-859

出版社

CHEMICAL INDUSTRY PRESS
DOI: 10.1016/S1004-9541(08)60287-6

关键词

hydrate; formation; gas storage; A-type zeolite

资金

  1. National Natural Science Foundation of China [50876107]
  2. National Basic Research Program of China [2009CB219504]
  3. NSFC-Guangdong Union Foundation [NSFC-U0733033]
  4. CAS Program [KGCX2-YW-805]

向作者/读者索取更多资源

The porous medium has an important effect on hydrate formation. In this paper, the formation process and the gas storage capacity of the methane hydrate were investigated with A-type zeolite and Sodium Dodecyl Sulfate (SDS) existing in the system. The results show that A-type zeolite can influence methane hydrate formation. At the temperature of 273.5 K and pressure of 8.3 MPa, the distilled water with A-type zeolite can form methane hydrate with gaseous methane in 12 hours. The formation process of the system with A-type zeolite was quite steady and the amount of A-type zeolite can influence the gas storage capacity significantly. The adding of A-type zeolite with 0.067 g.(g water)(-1) into 2 x 10(-3) g.g(-1) SDS-water solution can increase the gas storage capacity, and the maximum increase rate was 31%. Simultaneously the promotion effect on hydrate formation of 3A-type zeolite is much more obvious than that of 5A-type zeolite when the water adding amounts are 0.033 g.g(-1) and 0.067 g.g(-1) at the experimental conditions.

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