期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 1, 页码 427-430出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201507170
关键词
flavins; iron; oxygenation; photocatalysis
资金
- DFG graduate program Chemical Photocatalysis [GRK 1626]
A mixture of the photocatalyst riboflavin tetraacetate (RFT) and the biomimetic non-heme iron complex [Fe(TPA)-(MeCN) (2)](ClO4)(2) (TPA=tris(2-pyridylmethyl)amine) efficiently catalyzes the visible-light-driven aerobic oxidation of alkyl benzenes to ketones and carboxylic acids. An RFTcatalyzed photocycle and the independent action of the iron complex as a catalyst for H2O2 disproportionation and alkyl benzene oxygenation ensure high yields and selectivities.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据