期刊
CHINESE CHEMICAL LETTERS
卷 25, 期 12, 页码 1540-1544出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2014.07.006
关键词
Amine; Alcohol; N-Alkylated amine; Lewis acid; Synthesis
资金
- MOST of China (973 program) [2011CB808600]
- National Natural Science Foundation of China [21072091, 21372195]
- Low Carbon Fatty Amine Engineering Research Center of Zhejiang Province [2012E10033]
A substitution reaction of amines with alcohols for N-alkylated amines has been developed using inexpensive AlCl3 without any ligand or additive. Either aromatic or aliphatic amines and primary or secondary alcohols perform the AlCl3-mediated reaction smoothly to afford various N-alkylated amines in satisfactory yields. (C) 2014 Zhi-Zhen Huang. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
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