期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 5, 页码 1751-1754出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201507952
关键词
addition reaction; amination; boron cluster; carborane; carboryne
资金
- National Basic Research Program of China (973 Program) [2012CB821600]
- National Natural Sciences Foundation of China [21372245]
- Shanghai Pujiang Program [13PJ1410800]
- Youth Innovation Promotion Association CAS [2014230]
- CAS-Croucher
- NSFC/RGC [N_CUHK442/14]
The efficient o-carboryne precursor 1-Li-2-OTf-o-C2B10H10 reacts with lithium amides at room temperature to give a series of N-carboranyl amines in moderate to high isolated yields. This reaction is compatible with a broad substrate scope from primary to secondary, alkyl to aryl amines. The reaction mechanism is also proposed on the basis of experimental results and DFT calculations. This represents the first general and efficient method for the synthesis of 1-(NRR2)-R-1-o-carboranes.
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