期刊
CHIMIA
卷 66, 期 6, 页码 377-381出版社
SWISS CHEMICAL SOC
DOI: 10.2533/chimia.2012.377
关键词
Azaheterocycles; Cyclopropanols; 1,3-Dicarbonyl compounds; Manganese; Radicals; Vinyl azides
资金
- Nanyang Technological University
- Singapore Ministry of Education, and Science & Engineering Research Council (A*STAR) [082 101 0019]
Mn(III)-catalyzed formal [3+2]- and [3+3]-annulations have been developed using readily available vinyl azides with 1,3-dicarbonyl compounds and cyclopropanols. Vinyl azides were successfully applied as a three-atom unit including one nitrogen to prepare various azaheterocycles via Mn(III)-catalyzed radical reactions.
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