期刊
CHIMIA
卷 66, 期 6, 页码 439-441出版社
SWISS CHEMICAL SOC
DOI: 10.2533/chimia.2012.439
关键词
Free radical; Free radical polymerization; Photoinitiators; Photoredox catalysis; Ring opening polymerization
Photoredox catalysis is now well-known in organic synthesis for the formation of free radicals under very soft irradiations conditions (e.g. sunlight, household fluorescence or LED bulbs, Xe lamp). This method has been introduced here to the polymer chemistry area to initiate ring opening polymerizations (ROP) or free radical polymerizations (FRP). The present paper will give an up-to date situation of the photocatalyst achievements in FRP and ROP.
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