期刊
CHIMIA
卷 62, 期 6, 页码 461-464出版社
SWISS CHEMICAL SOC
DOI: 10.2533/chimia.2008.461
关键词
aluminium; asymmetry; catalysis; conjugate addition; copper; magnesium; zinc
This mini-review deals with a special, and challenging, aspect of the asymmetric conjugate addition: the formation of all-carbon quaternary centers by reaction with Michael acceptors bearing a polysubstituted unsaturation. Only copper catalysts allow this transformation, along with a careful choice of primary organometallics and chiral ligand. The resulting adducts are useful intermediates for the synthesis of more complex natural products.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据