期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 33, 页码 9650-9653出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201503442
关键词
cyclization; dimerization; dithiol reagents; quinones; synthetic methods
资金
- JSPS [23000006]
- Grants-in-Aid for Scientific Research [23000006] Funding Source: KAKEN
A viable method is reported for the synthesis of the bicyclo[3.2.1]octadienone scaffold in naturally occurring octaketide dimers. The procedure employs a reductive cyclization reaction mediated by an unusual ethanedithiol monosodium salt.
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