期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 32, 页码 9284-9288出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201503588
关键词
energy transfer; FRET; metal-organic frameworks; polyaromatic hydrocarbons; zinc
资金
- National Research Foundation of Korea (NRF) grant - Korean Government (MEST) [2013R1A2A2A07067841]
- National Research Foundation of Korea [2013R1A2A2A07067841] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
The self-assembly of Zn-II ions with 1,3,5-tris(isonicotinoyloxyethyl)cyanurate produces new topological (4(2)12(4))(3)(4(3))(4) 2D metal-organic frameworks (MOFs) with anion-confining cages. The eclipsed assembly of each 2D MOF by - stacking of cyanurate moieties (3.352(5)angstrom) forms 3D MOFs consisting of nanochannels (10.5 angstrom). Two of the three anions are confined in each peanut-type cage, resulting in hydrophobicity of the nanochannels. The hydrophobic nanochannel effectively adsorbs a wide range of fused aromatic hydrocarbons (FAHs) as monomers or dimers, rendering it potentially highly useful as an energy-transfer material.
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