Article
Chemistry, Multidisciplinary
Xuantong Sun, Xi Wang, Fengqiang Sun, Mingwei Tian, Lijun Qu, Patsy Perry, Huw Ovens, Xuqing Liu
Summary: A green chemistry strategy has been developed to separate and regenerate waste textiles at the molecular level, aiming to reduce the large amount of waste textiles generated by the fast fashion industry. This strategy also provides a new source of fibers to address fossil fuel reserve shortages caused by chemical fiber industries and global food shortages caused by natural fiber production.
ADVANCED MATERIALS
(2021)
Review
Chemistry, Physical
Stavros P. Neofotistos, Andromachi Tzani, Anastasia Detsi
Summary: Ionic liquids are liquids composed of ions with melting points lower than 100 degrees C. They are customizable solvents for a variety of reactions, and recent advancements have made them excellent candidates as phase transfer catalysts. Phase transfer catalysis allows insoluble reactants to transfer to the desired phase, and the fine-tuning capability of ionic liquids epitomizes the sustainability of this field. This report presents a comprehensive overview of their applications from the late 20th century to present.
Review
Chemistry, Multidisciplinary
Aline Andrea Quintana, Alaina Maria Sztapka, Valeria de Carvalho Santos Ebinuma, Christian Agatemor
Summary: This Review discusses the sustainability of ILs and DESs as solvents and how they contribute to sustainable chemical processes by tuning their properties and selecting appropriate precursors.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Materials Science, Multidisciplinary
Qikai Shen, Peipei Li, Weiming Chen, Hongqiang Jin, Jia Yu, Lei Zhu, Zhucheng Yang, Runqing Zhao, Lirong Zheng, Weiguo Song, Changyan Cao
Summary: Ionic liquids (ILs) have the advantages of being low cost, eco-friendly, abundant in heteroatoms, and having excellent solubility and coordination abilities with metal ions, making them suitable precursors for fabricating metal single-atom catalysts (SACs). In this study, various metal single atoms anchored on ultrathin N-doped nanosheets were prepared using ILs and g-C3N4 nanosheets as templates. The Cu-1/NC-1000 catalyst exhibited the highest catalytic activity for benzene oxidation to phenol, with a high benzene conversion rate of 82%, phenol selectivity of 96%, and excellent recyclability.
SCIENCE CHINA-MATERIALS
(2022)
Article
Biochemistry & Molecular Biology
Illia Kapitanov, Marcel Spulak, Milan Pour, Ondrej Soukup, Jan Marek, Daniel Jun, Martin Novak, Joyce S. F. Diz de Almeida, Tanos C. C. Franca, Nicholas Gathergood, Kamil Kuc, Yevgen Karpichev
Summary: We report a green chemistry approach for the preparation of oxime-functionalized ionic liquids as AChE reactivators. The novel oximes showed remarkable activity against AChE inhibited by VX. In addition, the oximes exhibited low toxicity towards bacteria, fungi, and yeasts in in vitro screening experiments.
CHEMICO-BIOLOGICAL INTERACTIONS
(2023)
Article
Chemistry, Multidisciplinary
Toshiyuki Itoh, Yumiko Takagi
Summary: Biocatalysis is an important tool in organic synthesis, chemical compound degradation, and biosensor applications. Laccases, as copper-containing oxidases, catalyze the conversion of polyphenols or amine derivatives using molecular oxygen. In recent years, there has been a growing interest in utilizing laccase-mediated reactions in ionic liquids for selective oxidative chemical conversions.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2021)
Article
Chemistry, Applied
Natalia Podrojkova, Andrej Orinak, Eduardo Garcia-Verdugo, Victor Sans, Marcileia Zanatta
Summary: Ionic liquids (ILs) as catalysts have significant effects on CO2 transformation. Highly functionalizable and immobilizable imidazolium based ILs (ImILs) have been shown to activate CO2 molecules and demonstrate activity towards CO2 cycloaddition reactions. Adding hydroxyl groups enhances the cycloaddition reaction. An ideal system would combine both functionalities for superior performance. The interaction between the cation-anion and the hydroxyl groups needs to be understood for these advantages to be realized. The viability of using ILs as bifunctional catalysts for one-pot reactions is evaluated through theoretical and experimental studies. DFT simulations using halogenated and hydroxyl functionalized ImLs show that the position of the hydroxyl group influences the epoxide opening and activation for the cycloaddition reaction, facilitating catalysis. Experimental results also demonstrate increased selectivity with catalyst immobilization. For the epoxidation reaction, the DFT calculations and experimental results favor hydrolysis reaction.
Review
Chemistry, Inorganic & Nuclear
Marina M. Seitkalieva, Dmitriy E. Samoylenko, Kristina A. Lotsman, Konstantin S. Rodygin, Valentine P. Ananikov
Summary: The development of metal nanoparticle chemistry in ionic liquids has made a significant impact on fields such as catalysis, energy research, nanotechnology, and materials science. Various methods for producing metal nanoparticles in ILs are highlighted, with a focus on catalytic activity in different reactions.
COORDINATION CHEMISTRY REVIEWS
(2021)
Review
Chemistry, Physical
Shrddhaba J. Chudasama, Bhavya J. Shah, Khushi M. Patel, Tejas M. Dhameliya
Summary: Ionic liquids (ILs), with their environmentally friendly and sustainable attributes, have been widely utilized in organic transformations. They possess characteristics such as recyclability, low vapor pressure, and low volatility. This article focuses on the application of ILs in the synthesis of nitrogen and oxygen containing heterocycles, demonstrating their effectiveness as catalysts or solvents in specific reactions.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Green & Sustainable Science & Technology
S. Pal, A. Mukherjee, P. Ghosh
Summary: Natural biopolymers have gained considerable interest for sustainable fiber development due to their renewability and wide degree of functionalities. Ionic liquids have proved to be superior to conventional solvents in terms of extraction efficiency, with added benefits of recyclability and reusability. Imidazolium-based ionic liquids have gained recognition as excellent solvents for processing natural biopolymers due to their tunable structure, ease of synthesis, and favorable physicochemical characteristics.
MATERIALS TODAY SUSTAINABILITY
(2021)
Article
Chemistry, Organic
Haitao Liu, Jingjing Lu, Xiudan Zhao, Tiejun Xu
Summary: Ionic liquids (ILs) have been widely used as catalysts in chemical reactions, and their immobilization on the surface of nanomaterials has been shown to be an efficient strategy for the fabrication of novel and green catalysts.
SYNTHETIC COMMUNICATIONS
(2021)
Article
Green & Sustainable Science & Technology
Elisa Hernandez, Alejandro Belinchon, Elia Ruiz Pachon, Pablo Navarro, Jose Palomar
Summary: This study evaluates the environmental impacts of using ionic liquids in the production of propylene carbonate and proposes a liquid-liquid extraction method as an alternative to traditional distillation-based approaches. The simulations show that tuning operating variables not only improves environmental benefits but also enhances cost-effectiveness. Additionally, the choice of ionic liquids has minimal impact on process sustainability when effective recovery is designed.
ADVANCED SUSTAINABLE SYSTEMS
(2022)
Article
Chemistry, Physical
BoAn Xiao, Seyed Mohsen Sadeghzadeh
Summary: A green and economical method for the oxidation of sulfides to sulfones and sulfoxides in water, and epoxidation of olefins in ethanol with O2 was reported using keplerate nanosized polyoxo-molybdate [Mo368] supported by ionic liquid between DFNS as catalyst. The method exhibited high efficiency, good selectivity, and environmental friendliness.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Multidisciplinary
David Valverde, Raul Porcar, Pedro Lozano, Eduardo Garcia-Verdugo, Santiago Luis
Summary: Supported ionic liquid-like phases (SILLPs) containing Rose Bengal (RB) units are utilized for the development of organocatalytic systems for the cycloaddition of CO2 to epoxides. The activity of supported RB fragments can be adjusted by controlling the nature of SILLPs. This catalytic system, prepared from cheap and commercially available components, shows high activity and stability without decay in activity for at least 10 days under flow conditions.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2021)
Article
Chemistry, Multidisciplinary
Somnath Sarkar, Swarbhanu Ghosh, Robius Sani, Jhumur Seth, Aslam Khan, Sk. Manirul Islam
Summary: By utilizing a postsynthetic modification approach, quaternary ammonium salts were successfully immobilized onto a microporous covalent organic framework (COF), resulting in a metal-free catalyst with high catalytic performance. The catalyst showed efficient coupling of CO2 with epoxides under mild conditions, exhibiting broad scope and functional group tolerance. Additionally, the catalyst can be recovered and reused multiple times with similar performance, making it a promising candidate for industrial implementation.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2023)
Article
Chemistry, Multidisciplinary
Claudio Iacobucci, Samantha Reale, Massimiliano Aschi, Jos Oomens, Giel Berden, Francesco De Angelis
CHEMISTRY-A EUROPEAN JOURNAL
(2018)
Article
Chemistry, Inorganic & Nuclear
Lorenzo Biancalana, Issam Abdalghani, Federica Chiellini, Stefano Zacchini, Guido Pampaloni, Marcello Crucianelli, Fabio Marchetti
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
(2018)
Article
Chemistry, Multidisciplinary
Bruno Mattia Bizzarri, Issam Abdalghani, Lorenzo Botta, Anna Rita Taddei, Stefano Nisi, Marco Ferrante, Maurizio Passacantando, Marcello Crucianelli, Raffaele Saladino
Article
Chemistry, Applied
Francesco Ferella, Lorenzo Biancalana, Fabio Marchetti, Marcello Crucianelli
Review
Chemistry, Physical
Marcello Crucianelli, Bruno Mattia Bizzarri, Raffaele Saladino
Article
Chemistry, Physical
Bruno Mattia Bizzarri, Angelica Fanelli, Davide Piccinino, Marta De Angelis, Camilla Dolfa, Anna Teresa Palamara, Lucia Nencioni, Claudio Zippilli, Marcello Crucianelli, Raffaele Saladino
Article
Chemistry, Physical
Eliana Capecchi, Davide Piccinino, Bruno Mattia Bizzarri, Lorenzo Botta, Marcello Crucianelli, Raffaele Saladino
Article
Chemistry, Physical
Patrizio Campitelli, Massimiliano Aschi, Corrado di Nicola, Fabio Marchetti, Riccardo Pettinari, Marcello Crucianelli
APPLIED CATALYSIS A-GENERAL
(2020)
Review
Biochemistry & Molecular Biology
Patrizio Campitelli, Marcello Crucianelli
Review
Chemistry, Physical
Andrea Lazzarini, Roberta Colaiezzi, Francesco Gabriele, Marcello Crucianelli
Summary: Heterogeneous catalysts are expanding their applications from traditional industrial chemistry to the production of fine chemicals, with a focus on reducing the use of fossil feedstocks. Biomasses, as the most accessible source of organic precursors, require novel catalysts for efficient utilization, while the importance of supports in ensuring stable performance and improving catalytic activity should not be overlooked.
Article
Chemistry, Physical
Giulio Bresciani, Mario Gemmiti, Gianluca Ciancaleoni, Guido Pampaloni, Fabio Marchetti, Marcello Crucianelli
Summary: In this study, easily available niobium and tantalum carbamates were used as effective catalysts for the conversion of alkyl aryl and aromatic sulfides into sulfones. The niobium catalyst 4 exhibited unexpected stability in a protic catalytic environment, and a plausible catalytic cycle was proposed based on DFT studies. The active catalytic species, 4 and its minor mono-methoxide derivative, were found to interconvert through the versatile coordination of the carbamato ligand.
MOLECULAR CATALYSIS
(2021)
Article
Chemistry, Multidisciplinary
Alessandra Biancolillo, Angelo Antonio D'Archivio, Fabio Pietrangeli, Gaia Cesarone, Fabrizio Ruggieri, Martina Foschi, Samantha Reale, Leucio Rossi, Marcello Crucianelli
Summary: This study attempted to discriminate three monovarietal white wines using a data fusion approach. The results showed that the data fusion approach was more effective than individual analytical methods.
APPLIED SCIENCES-BASEL
(2022)
Article
Chemistry, Physical
Roberta Colaiezzi, Chiara Saviozzi, Nicola di Nicola, Stefano Zacchini, Guido Pampaloni, Marcello Crucianelli, Fabio Marchetti, Andrea Di Giuseppe, Lorenzo Biancalana
Summary: The reductive N-monomethylation of nitroarenes can be conveniently realized in one-pot using methanol as the reductant, methylating agent, and solvent. New ruthenium(II) arene complexes were developed as efficient catalytic precursors for the tandem reduction/N-methylation of aromatic nitrocompounds with methanol, starting from commercially available and inexpensive dioxime ligands.
CATALYSIS SCIENCE & TECHNOLOGY
(2023)
Article
Polymer Science
Paola Manini, Valeria Lino, Gerardino D'Errico, Samantha Reale, Alessandra Napolitano, Francesco De Angelis, Marco d'Ischia
Article
Chemistry, Physical
Davide Piccinino, Eliana Capecchi, Lorenzo Botta, Paolo Bollella, Riccarda Antiochia, Marcello Crucianelli, Raffaele Saladino
CATALYSIS SCIENCE & TECHNOLOGY
(2019)