期刊
CHEMSUSCHEM
卷 2, 期 1, 页码 63-70出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.200800162
关键词
carbenes; homogeneous catalysis; palladium; telomerization
资金
- State of Mecklenburg-Western Pomerania
- BMBF (Bundesministerium fur Bildung und Forschung)
- Deutsche Forschungsgemeinschaft
- Evonik Rohm GmbH
The selective telomerization of 1,3-butadiene with seven different linear and cyclic diols proceeds in the presence of in situ generated palladium carbene catalysts. By applying optimized reaction conditions, including very low metal loadings (2-10 ppm), excellent catalyst turnover numbers (>250000) and good chemoselectivities are observed with respect to the mono-octadienyl ether derivatives. This protocol allows the efficient preparation of unsaturated alcohols, which are useful for various applications.
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