期刊
CHEMPHYSCHEM
卷 13, 期 12, 页码 3047-3052出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.201101059
关键词
benzene; diamonds; electrochemistry; oxidation; electron transfer
资金
- Russian Foundation for Basic Research [10-03-00011]
A comparative study of benzene oxidation at boron-doped diamond (BDD) and nitrogenated nanocrystalline diamond (NCD) anodes in 0.5?M K2SO4 aqueous solution is conducted by using cyclic voltammetry and electrochemical impedance spectroscopy. It is shown by measurements of differential capacitance and anodic current that during the benzene oxidation at the BDD electrode, adsorption of a reaction intermediate occurs, which partially blocks the electrode surface and lowers the anodic current. At the NCD electrode, benzene is oxidized concurrently with oxygen evolution, a (quinoid) intermediate being adsorbed at the electrode. The adsorption and the electrode surface blocking are reflected in the impedancefrequency and impedancepotential complex-plane plots.
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