4.7 Article

Modeling urban films using a dynamic multimedia fugacity model

期刊

CHEMOSPHERE
卷 87, 期 9, 页码 1024-1031

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.chemosphere.2011.12.044

关键词

Surface films; Multimedia modeling; Unsteady-state systems; Polychlorinated biphenyls; Semi-volatile organic compounds; Urban environment

资金

  1. Ontario Graduate Scholarship
  2. Lakes Atmospheric Deposition fund
  3. Natural Science and Engineering Research Council (NSERC) of Canada

向作者/读者索取更多资源

A thin film coats impervious urban surfaces that can act as a source or sink of organic pollutants to the greater environment. We review recent developments in the understanding of film and film-associated pollutant behavior and incorporate them into an unsteady-state version of the fugacity based Multimedia Urban Model (MUM), focusing on detailed considerations of surface film dynamics. The model is used to explore the conditions under which these atmospherically-derived films act as a temporary source of chemicals to the air and/or storm water. Assuming film growth of 2.1 nm d(-1) (Wu et al., 2008a), PCB congeners 28 and 180 reach air-film equilibrium within hours and days, respectively. The model results suggest that the film acts as a temporary sink of chemicals from air during dry and cool weather, as a source to air in warmer weather, and as a source to storm water and soil during rain events. Using the downtown area of the City of Toronto Canada, as a case study, the model estimates that nearly 1 g d(-1) of Sigma(5)PCBs are transferred from air to film to storm water. (C) 2012 Elsevier Ltd. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Environmental Sciences

Indoor exposure to phthalates and polycyclic aromatic hydrocarbons (PAHs) to Canadian children: the Kingston allergy birth cohort

Yuchao Wan, Michelle L. North, Garthika Navaranjan, Anne K. Ellis, Jeffrey A. Siegel, Miriam L. Diamond

Summary: This study characterized concentrations of eight phthalates and 12 PAHs in floor dust from the bedrooms of 79 children. Some phthalates were associated with product and material use, while some PAHs were associated with household characteristics. No significant increases in risk of atopy was found based on phthalate or PAH dust concentrations.

JOURNAL OF EXPOSURE SCIENCE AND ENVIRONMENTAL EPIDEMIOLOGY (2022)

Article Engineering, Environmental

Enhancing Scientific Support for the Stockholm Convention's Implementation: An Analysis of Policy Needs for Scientific Evidence

Zhanyun Wang, Sam Adu-Kumi, Miriam L. Diamond, Ramon Guardans, Tom Harner, Agustin Harte, Natsuko Kajiwara, Jana Klanova, Jianguo Liu, Estefania Gastaldello Moreira, Derek C. G. Muir, Noriyuki Suzuki, Victorine Pinas, Timo Seppala, Roland Weber, Bo Yuan

Summary: The Stockholm Convention is crucial in addressing global threats posed by persistent organic pollutants (POPs). Although it successfully identifies new POPs, implementing the convention at the national level remains challenging, particularly for low- and middle-income countries. This analysis aims to identify and recommend the research and scientific support necessary for the convention's timely implementation, providing practical guidance and recommendations for sustaining scientific support.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2022)

Article Engineering, Environmental

Occupational Exposure of Canadian Nail Salon Workers to Plasticizers Including Phthalates and Organophosphate Esters

Linh Nguyen, Miriam L. Diamond, Sheila Kalenge, Tracy L. Kirkham, D. Linn Holness, Victoria H. Arrandale

Summary: This study assessed the personal exposure of nail salon workers in Toronto, Canada to 10 phthalates and 19 organophosphate esters. The results showed significant correlations between the levels of these compounds detected in passive silicone brooches and wristbands and those in active air samplers. Additionally, the higher concentrations of these compounds on the silicone brooches and wristbands suggest that these passive samplers can be used to measure the exposure of nail salon workers.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2022)

Article Environmental Sciences

A fit-for-purpose categorization scheme for microplastic morphologies

Jasmine T. Yu, Miriam L. Diamond, Paul A. Helm

Summary: This paper proposes a hierarchical categorization approach for microplastics, which aims to improve consistency and comparability in classification. A literature review reveals significant variations and inconsistencies in the categorization and grouping schemes for microplastic particles, highlighting the need for a fit-for-purpose classification scheme to meet the information needs of scientists and decision-makers in different research and regulatory objectives.

INTEGRATED ENVIRONMENTAL ASSESSMENT AND MANAGEMENT (2023)

Article Engineering, Environmental

Per- and Polyfluoroalkyl Substances in North American School Uniforms

Chunjie Xia, Miriam L. Diamond, Graham F. Peaslee, Hui Peng, Arlene Blum, Zhanyun Wang, Anna Shalin, Heather D. Whitehead, Megan Green, Heather Schwartz-Narbonne, Diwen Yang, Marta Venier

Summary: This study analyzed 72 children's textile products from US and Canadian stores and found that all products contained PFAS, with 6:2 FTOH being the most abundant compound. School uniforms had higher concentrations of PFAS compared to other items, especially those made of 100% cotton. The estimated potential children's exposure to PFAS through dermal contact with school uniforms was 1.03 ng/kg bw/day.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2022)

Letter Engineering, Environmental

Response to Comment on Occupational Exposure of Canadian Nail Salon Workers to Plasticizers Including Phthalates and Organophosphate Esters

Linh Nguyen, Miriam L. Diamond, Sheila Kalenge, Tracy L. Kirkham, D. Linn Holness, Victoria H. Arrandale

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2022)

Article Environmental Sciences

A science-based agenda for health-protective chemical assessments and decisions: overview and consensus statement

Tracey J. Woodruff, Swati D. G. Rayasam, Daniel A. Axelrad, Patricia D. Koman, Nicholas Chartres, Deborah H. Bennett, Linda S. Birnbaum, Phil Brown, Courtney C. Carignan, Courtney Cooper, Carl F. Cranor, Miriam L. Diamond, Shari Franjevic, Eve C. Gartner, Dale Hattis, Russ Hauser, Wendy Heiger-Bernays, Rashmi Joglekar, Juleen Lam, Jonathan I. Levy, Patrick M. MacRoy, Maricel V. Maffini, Emily C. Marquez, Rachel Morello-Frosch, Keeve E. Nachman, Greylin H. Nielsen, Catherine Oksas, Dimitri Panagopoulos Abrahamsson, Heather B. Patisaul, Sharyle Patton, Joshua F. Robinson, Kathryn M. Rodgers, Mark S. Rossi, Ruthann A. Rudel, Jennifer B. Sass, Sheela Sathyanarayana, Ted Schettler, Rachel M. Shaffer, Bhavna Shamasunder, Peggy M. Shepard, Kristin Shrader-Frechette, Gina M. Solomon, Wilma A. Subra, Laura N. Vandenberg, Julia R. Varshavsky, Roberta F. White, Ken Zarker, Lauren Zeise

Summary: The manufacture and production of industrial chemicals continues to increase, leading to widespread population exposures and resultant health impacts. Low-wealth communities and communities of color often bear disproportionate burdens of exposure and impact. Multiple authoritative bodies and scientific consensus groups have called for actions to prevent harmful exposures via improved policy approaches. We developed consensus recommendations for health-protective, scientific approaches to reduce harmful chemical exposures, which can be applied to current US policies governing industrial chemicals and environmental pollutants.

ENVIRONMENTAL HEALTH (2023)

Review Environmental Sciences

Addressing systemic problems with exposure assessments to protect the public's health

Laura N. Vandenberg, Swati D. G. Rayasam, Daniel A. Axelrad, Deborah H. Bennett, Phil Brown, Courtney C. Carignan, Nicholas Chartres, Miriam L. Diamond, Rashmi Joglekar, Bhavna Shamasunder, Kristin Shrader-Frechette, Wilma A. Subra, Ken Zarker, Tracey J. Woodruff

Summary: Understanding and quantifying human exposures to environmental chemicals is crucial for public health protection. Inadequate exposure assessments conducted by polluting industries or regulatory agencies have led to the disregard of exposure concerns raised by communities and the underestimation of risks, allowing pollutants to go unregulated. Researchers, risk assessors, and policy makers need to address the issues affecting exposure assessments and utilize exposure data to make informed decisions for health protection.

ENVIRONMENTAL HEALTH (2023)

Editorial Material Engineering, Environmental

Key Principles for the Intergovernmental Science-Policy Panel on Chemicals and Waste

Marlene Agerstrand, Kenneth Arinaitwe, Thomas Backhaus, Ricardo O. Barra, Miriam L. Diamond, Joan O. Grimalt, Ksenia Groh, Faith Kandie, Perihan Binnur Kurt-Karakus, Robert J. Letcher, Rainer Lohmann, Rodrigo O. Meire, Temilola Oluseyi, Andreas Schaeffer, Mochamad Septiono, Gabriel Sigmund, Anna Soehl, Temitope O. Sogbanmu, Noriyuki Suzuki, Marta Venier, Penny Vlahos, Martin Scheringer

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2023)

Article Engineering, Environmental

Optimizing Chemicals Management in the United States and Canada through the Essential-Use Approach

Simona A. Balan, David Q. Andrews, Arlene Blum, Miriam L. Diamond, Seth Rojello Fernandez, Elizabeth Harriman, Andrew B. Lindstrom, Anna Reade, Lauren Richter, Rebecca Sutton, Zhanyun Wang, Carol F. Kwiatkowski

Summary: Chemicals have been used to improve industrial and consumer products, but their negative impact on human and ecological health calls for an urgent need to address this issue. The essential-use approach suggests that chemicals should only be used if necessary for health, safety, or society and if there are no viable alternatives. To implement this approach effectively, it is important to identify chemicals of concern, expedite decision-making, apply it early in the development process, and involve experts in making essentiality determinations and sharing information. By optimizing and expanding this approach, it can lead to better chemicals management and encourage the use of safer alternatives for human and ecological health.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2023)

Editorial Material Engineering, Environmental

Environmental Research Addressing Sustainable Development Goals

James R. Mihelcic, Ricardo O. Barra, Bryan W. Brooks, Miriam L. Diamond, Matthew J. Eckelman, Jacqueline MacDonald Gibson, Sunny Guidotti, Atsuko Ikeda-Araki, Manish Kumar, Ynoussa Maiga, Jennifer McConville, Shelly L. Miller, Valeria Pizarro, Fernando Rosario-Ortiz, Shuxiao Wang, Julie B. Zimmerman

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2023)

Article Biodiversity Conservation

Addressing chemical pollution in biodiversity research

Gabriel Sigmund, Marlene Agerstrand, Alexandre Antonelli, Thomas Backhaus, Tomas Brodin, Miriam L. Diamond, Walter R. Erdelen, David C. Evers, Thilo Hofmann, Thorsten Hueffer, Adelene Lai, Joao P. M. Torres, Leonie Mueller, Allison L. Perrigo, Matthias C. Rillig, Andreas Schaeffer, Martin Scheringer, Kristin Schirmer, Ahmed Tlili, Anna Soehl, Rita Triebskorn, Penny Vlahos, Colette vom Berg, Zhanyun Wang, Ksenia J. Groh

Summary: Climate change, biodiversity loss, and chemical pollution are urgent global emergencies that require immediate actions to mitigate. While climate change and biodiversity are often studied together, chemical pollution's contribution to biodiversity loss has been largely overlooked. Failure to address pollution effects may undermine biodiversity protection efforts, highlighting the importance of interdisciplinary collaborations in understanding and countering the negative impact of chemical pollution on ecosystems.

GLOBAL CHANGE BIOLOGY (2023)

Editorial Material Engineering, Environmental

Environmental Research Addressing Sustainable Development Goals

James R. Mihelcic, Ricardo O. Barra, Bryan W. Brooks, Miriam L. Diamond, Matthew J. Eckelman, Jacqueline MacDonald Gibson, Sunny Guidotti Atsuko Ikeda-Araki, Manish Kumar, Ynoussa Maiga, Jennifer McConville, Shelly L. Miller, Valeria Pizarro Fernando Rosario-Ortiz, Shuxiao Wang, Julie B. Zimmerman

ENVIRONMENTAL SCIENCE & TECHNOLOGY LETTERS (2023)

Article Engineering, Environmental

Optimizing Chemicals Management in the United States and Canada through the Essential-Use Approach

Simona A. Balan, David Q. Andrews, Arlene Blum, Miriam L. Diamond, Seth Rojello Fernandez, Elizabeth Harriman, Andrew B. Lindstrom, Anna Reade, Lauren Richter, Rebecca Sutton, Zhanyun Wang, Carol F. Kwiatkowski

Summary: Chemicals have brought improvements to industrial and consumer products, but their use has sometimes caused harm to human and ecological health. The current regulatory systems are insufficient for managing the large number of chemicals in commerce, requiring a new approach. The essential-use approach proposes using chemicals of concern only when necessary for health, safety, or societal functioning, and when no feasible alternatives exist. To implement this approach, governments and businesses should identify chemicals for assessment, streamline decision-making, integrate essential-use considerations early in chemical development, and involve diverse experts. If expanded, this approach can enhance chemicals management and promote safer chemistries, benefiting human and ecological health.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2023)

Article Chemistry, Analytical

Widespread presence of chlorinated paraffins in consumer products

Steven Kutarna, Xuan Du, Miriam L. Diamond, Arlene Blum, Hui Peng

Summary: Short-chain chlorinated paraffins (SCCPs) were classified as substances to be eliminated under the Stockholm Convention due to their persistence and toxicity. Despite their ban in Canada since 2013, SCCPs can still be found at high concentrations in indoor dust. A study found SCCPs in a wide range of products purchased in Canada after 2013, including electronic devices, clothing, plastics (toys), and paintings, indicating ongoing exposure to SCCPs indoors.

ENVIRONMENTAL SCIENCE-PROCESSES & IMPACTS (2023)

暂无数据