Removing and recovering gas-phase elemental mercury by CuxCO3-xO4 (0.75 ≤ x ≤ 2.25) in the presence of sulphur compounds

The Hg-0 oxidation ability and reusability Of CUxO3-xO4 were investigated in an attempt to improve SO2 anti-poisoning ability of metal oxide and produce more economic and effective sorbents for the control of Hg-0 emission from combustion processes. The influence of copper content on CuxCO3-xO4's (0.75 <= x <= 2.25) oxidation ability of Hg-0 in the presence Of SO2 was investigated. According to the X-ray diffraction, Brunauer-Emmett-Teller (BET) and mass balance analysis on mercury, we found that Cu1.5Co1.5O4 showed the highest S-BET and best Hg-0 oxidation ability. With continuous increase of x from 0.75 to 2.25, CuxCO3-xO4's SO2 anti-poisoning ability increased. The analysis results of the X-ray photoelectron spectroscopy manifested that the adsorptive mercury species on spent Cu1.5Co1.5O4 was HgO. The spent Cu1.5Co1.5O4 could be regenerated by thermal decomposition at 673 K and regenerated Cu1.5Co1.5O4 showed higher Hg-0 oxidation ability due to Hg-doping. Regenerated enrichment Hg-0 was collected using activated carbon at an ambient temperature to eliminate the secondary pollution. (c) 2007 Elsevier Ltd. All rights reserved.