期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 20, 期 43, 页码 14120-14125出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201403580
关键词
carbenes; catalysis; NHC ligands; olefin metathesis; ruthenium
资金
- National Science Centre (Poland) [DEC-2012/04A/ST5/00594]
- Operation Programme Innovative Economy (PO IG) [POIG 1.4-4.1]
- Chemical Monthly
Cyclic Ru-phenolates were synthesized, and these compounds were used as olefin metathesis catalysts. Investigation of their catalytic activity pointed out that, after activation with chemical agents, these catalysts promote ring-closing metathesis (RCM), enyne and cross-metathesis (CM) reactions, including butenolysis, with good results. Importantly, these latent catalysts are soluble in neat dicyclopentadiene (DCPD) and show good applicability in ring-opening metathesis polymeriyation (ROMP) of this monomer.
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