期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 21, 期 7, 页码 2750-2754出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201406073
关键词
fluoroarenes; inclusion complexes; macrocycles; shape persistency; X-ray diffraction
资金
- University of Houston
- Norman Hackerman Advanced Research Program
- National Science Foundation [CHE-1151292, CHE-1254897]
- Welch Foundation [E-1571, E-1768, A-1775]
- Camille and Henry Dreyfus Foundation
- European Regional Development Fund [ERAF 2DP/2.1.1.1.0/10/APIA/VIAA/059]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1254897] Funding Source: National Science Foundation
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1151292] Funding Source: National Science Foundation
We report structural characterization of a new member of m-phenylene ethynylene ring family. This shape-persistent macrocycle also co-crystallizes with hexafluoro-, 1,2,4,5-tetrafluoro-, 1,3,5-trifluoro, and 1,4-difluorobenzene. The four complexes are almost isostructural, and all show the fluoroarene included into the central cavity of the macrocycle. Characterized by multiple short C-H center dot center dot center dot F-C contacts, these inclusion complexes further dimerize in the solid state into a 2+2 assembly, in which the two macrocycles embrace each other by their large hydrophobic groups that are rotated by 608 relative to one another.
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