期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 20, 期 26, 页码 8099-8105出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201400303
关键词
alkenes; C-H bond activation; homogeneous catalysis; nickel; regioselectivity
资金
- Taiwan National Science Council [NSC: 101-2628M-001-004-MY3]
- Academia Sinica
We previously reported a highly efficient protocol for bimetallic Ni-Al-catalyzed hydroheteroarylation of styrene with benzimidazole based on C-H bond activation. We have now delineated the mechanism of this process, providing a rationale for an observed switch in regioselectivity in the presence of the Lewis acid, AlMe3. The present mechanistic study gives insights for the rational development of catalysts that exhibit required linear/branched selectivity.
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