4.6 Article

Rhodium-Catalyzed Intramolecular [3+2+2] Cycloadditions between Alkylidenecyclopropanes, Alkynes, and Alkenes

期刊

CHEMISTRY-A EUROPEAN JOURNAL
卷 20, 期 33, 页码 10255-10259

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201402473

关键词

alkylidenecyclopropane; carbocycles; catalysis; cycloadditions; rhodium

资金

  1. Spanish MINECO [SAF2010-20822-C02-01/02, CTQ2010-20714-C02-01/BQU, CSD2007-00006]
  2. ERDF
  3. Xunta de Galicia [GRC2010/12, GR2013-041, INCITE09 209084PR, EM2013/036]
  4. European Research Council [340055]
  5. CAM [S2009/PPQ-1634]

向作者/读者索取更多资源

A Rh-catalyzed intramolecular [3+2+2] cycloaddition is reported. The cycloaddition affords synthetically relevant 5,7,5-fused tricyclic systems of type 2 from readily available dienyne precursors. The transformation takes place with moderate or good yields, high diastereoselectivity, and total chemoselectivity.

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