期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 21, 期 1, 页码 191-198出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201405430
关键词
carbenes; nitrenes; small-molecule activation; thiosulfinylamino group; phosphorus
资金
- DOE [DE-FG02-13ER16370]
- Alexander von Humboldt Foundation
The room-temperature stable phosphinonitrene 1 undergoes a thermal rearrangement into heterocycle 2 through a process involving a nitrene insertion into a CH bond. In the presence of acetonitrile, a nitrene-acetonitrile adduct has been isolated; then it first rearranges into a ketenimine and subsequently into a rare example of diazaphos-phete. Compound 1 also splits water, carbon dioxide, carbon disulfide, and elemental sulfur, although it reacts with white phosphorus, leading to a P5N cluster formally resulting from the insertion of the PN moiety into a P-P edge of the P-4 tetrahedron.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据