期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 20, 期 28, 页码 8584-8588出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201403183
关键词
cyclization; enantioselectivity; intermolecular symmetric structure; magnesium catalysts; site specific selectivity
资金
- NSFC [91213302, 21272102, 21202071]
- National S&T Major Project of China [2012ZX09504001-003]
The first stereocontrolled cross reaction of enones has been realized. A novel combinational magnesium catalyst was designed to address the enantioselectivity problem between reaction partners with an intermolecular symmetric structure and bearing identical functional groups. This new catalytic strategy was proven to be effective to introduce high levels of enantioselectivity in the cross reaction of enones.
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