期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 20, 期 8, 页码 2175-2178出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201304239
关键词
carbyne complexes; demetalation; diphosphines; phosphoniocarbene complexes; phosphorus ylides
资金
- CNRS
- PICS grant (RFBR) [4873 (CNRS)/09-03-91060]
Easily available carbyne complexes of manganese were used as a source of carbyne fragments in an unconventional synthesis of backbone-substituted diphosphinomethanes and cyclic P-ylides upon coupling with secondary or tertiary phosphines, respectively, followed by demetalation under mild conditions.
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