期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 19, 期 34, 页码 11352-11363出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201300538
关键词
asymmetric catalysis; conjugate addition; copper; ligand effects; phosphine ligands
资金
- Swiss National Research Foundation [200020-144344]
- Swiss National Science Foundation (SNF) [200020_144344] Funding Source: Swiss National Science Foundation (SNF)
The copper-catalysed conjugate addition of trialkylaluminium and dialkylzinc reagents to polyconjugated nitroolefins (nitrodiene and nitroenyne derivatives) is reported. A reversed Josiphos ligand L7 allows for the selective 1,4- or 1,6-addition with high enantioselectivities.
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