期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 18, 期 16, 页码 5073-5079出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201102736
关键词
electrochemistry; hematite nanochains; magnetic properties; photocatalytic degradation; sacrificial template
资金
- National Basic Research Program of China [2010CB934700]
- National Natural Science Foundation of China [91022032, 21061160492, J1030412, 50732006]
- International Science & Technology Cooperation Program of China [2010DFA41170]
- National Synchrotron Radiation Laboratory at the University of Science and Technology of China
Unique hematite nanochains self-assembled from a-Fe2O3 nanoparticles can be synthesized by thermal decomposition of [Fe18S25](TETAH)14 as an appropriate nanoribbon precursor (TETAH=protonated triethylenetetramine). Magnetic studies have revealed greatly enhanced coercivity of the 1D hematite nanochains compared with that of dispersed a-Fe2O3 nanoparticles at low temperature, which may be attributed to their increased shape anisotropy and magnetocrystalline anisotropy. The photocatalytic properties of the hematite nanochains have been studied, as well as their electrochemical properties as cathode materials of lithium-ion batteries. The results have shown that both properties are dependent on the BET specific surface areas of the 1D hematite nanochains.
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