Rh-Catalyzed CC Cleavage of Benzyl/Allylic Alcohols to Produce Benzyl/Allylic Amines or other Alcohols by Nucleophilic Addition of Intermediate Rhodacycles to Aldehydes and Imines

Extrusion of CO from Aryl Ketones: Rhodium(I)-Catalyzed CC Bond Cleavage Directed by a Pyridine Group

(2012) Zhi-Quan Lei et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium/Copper-Catalyzed Annulation of Benzimides with Internal Alkynes: Indenone Synthesis through Sequential CH and CN Cleavage

(2012) Bi-Jie Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

[RhIIICp*]-Catalyzed Dehydrogenative ArylAryl Bond Formation

(2012) Joanna Wencel-Delord et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-catalyzed oxidative C2-acylation of indoles with aryl and alkyl aldehydes

(2012) Bing Zhou et al.   CHEMICAL COMMUNICATIONS

Mechanism of the Rhodium(III)-Catalyzed Arylation of Imines via C–H Bond Functionalization: Inhibition by Substrate

(2012) Michael E. Tauchert et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Olefinic C–H Bond Addition to Aryl Aldehyde and Its N-Sulfonylimine via Rh Catalysis

(2012) Yang Li et al.   ORGANIC LETTERS

N-Directing Group Assisted Rhodium-Catalyzed Aryl C–H Addition to Aryl Aldehydes

(2012) Yang Li et al.   ORGANIC LETTERS

Tandem Rh(III)-Catalyzed Oxidative Acylation of Secondary Benzamides with Aldehydes and Intramolecular Cyclization: The Direct Synthesis of 3-Hydroxyisoindolin-1-ones

(2012) Satyasheel Sharma et al.   ORGANIC LETTERS

Rhodium-Catalyzed Synthesis of Branched Amines by Direct Addition of Benzamides to Imines

(2012) Kevin D. Hesp et al.   ORGANIC LETTERS

Rh(I)-Catalyzed Asymmetric 1,2-Addition to α-Diketones with Chiral Sulfur–Alkene Hybrid Ligands

(2012) Xiangqing Feng et al.   ORGANIC LETTERS

Mechanistic understanding of Rh-catalyzed N-sulfonylaldimine insertion into aryl C–H bonds

(2012) Yang Li et al.   Chemical Science

Direct oxidative arylation via rhodium-catalyzed C–C bond cleavage of secondary alcohols with arylsilanes

(2012) Kang Chen et al.   Chemical Science

Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization Reactions

(2011) Denise A. Colby et al.   ACCOUNTS OF CHEMICAL RESEARCH

Grignard-Type Arylation of Aldehydes via a Rhodium-Catalyzed CH Activation under Mild Conditions

(2011) Luo Yang et al.   ADVANCED SYNTHESIS & CATALYSIS

Allyl-, Allenyl-, and Propargyl-Transfer Reactions through Cleavage of CC Bonds Catalyzed by an N-Heterocyclic Carbene/Copper Complex: Synthesis of Multisubstituted Pyrroles

(2011) Masahiro Sai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Direct Addition of Aryl CH Bonds to N-Sulfonyl Aldimines

(2011) Yang Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed, Highly Enantioselective 1,2-Addition of Aryl Boronic Acids to α-Ketoesters and α-Diketones Using Simple, Chiral Sulfur-Olefin Ligands

(2011) Ting-Shun Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of arylketones by ruthenium-catalyzed cross-coupling of aldehydes with arylboronic acids

(2011) Hong Li et al.   CHEMICAL COMMUNICATIONS

Rhodium-catalyzed direct ortho C–H olefination of phenol derivatives

(2011) Chao Feng et al.   CHEMICAL COMMUNICATIONS

Enantioselective total synthesis of (+)-asteriscanolide via Rh(i)-catalyzed [(5+2)+1] reaction

(2011) Yong Liang et al.   CHEMICAL COMMUNICATIONS

Nickel-Catalyzed Intramolecular Nucleophilic Addition of Aryl or Vinyl Chlorides to α-Ketoamides Through CCl Bond Activation

(2011) Jin-Xiu Hu et al.   CHEMISTRY-A EUROPEAN JOURNAL

RhIII-Catalyzed Oxidative Olefination of Vinylic CH Bonds: Efficient and Selective Access to Di-unsaturated α-Amino Acid Derivatives and Other Linear 1,3-Butadienes

(2011) Tatiana Besset et al.   CHEMISTRY-A EUROPEAN JOURNAL

Expanding the Utility of Brønsted Base Catalysis: Biomimetic Enantioselective Decarboxylative Reactions

(2011) Yuanhang Pan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium(III)-Catalyzed Oxidative Coupling of 5-Aryl-1H-pyrazoles with Alkynes and Acrylates

(2011) Xingwei Li et al.   JOURNAL OF ORGANIC CHEMISTRY

A Homogeneous, Recyclable Polymer Support for Rh(I)-Catalyzed C–C Bond Formation

(2011) Ranjan Jana et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed Regioselective Olefination Directed by a Carboxylic Group

(2011) Satoshi Mochida et al.   JOURNAL OF ORGANIC CHEMISTRY

Oxidative Coupling of NH Isoquinolones with Olefins Catalyzed by Rh(III)

(2011) Fen Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Highly Substituted Acenes through Rhodium-Catalyzed Oxidative Coupling of Arylboron Reagents with Alkynes

(2011) Tatsuya Fukutani et al.   JOURNAL OF ORGANIC CHEMISTRY

Chiral Allene-Containing Phosphines in Asymmetric Catalysis

(2011) Feng Cai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Expedient Synthesis ofN-Acyl Anthranilamides and β-Enamine Amides by the Rh(III)-Catalyzed Amidation of Aryl and Vinyl C–H Bonds with Isocyanates

(2011) Kevin D. Hesp et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Arylation of Boc-Imines via C−H Bond Functionalization

(2011) Andy S. Tsai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Directed C−H Olefination Using an Oxidizing Directing Group: Mild, Efficient, and Versatile

(2011) Souvik Rakshit et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diverse Strategies toward Indenol and Fulvene Derivatives: Rh-Catalyzed C−H Activation of Aryl Ketones Followed by Coupling with Internal Alkynes

(2011) Frederic W. Patureau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pyridinyl Directed Alkenylation with Olefins via Rh(III)-Catalyzed C–C Bond Cleavage of Secondary Arylmethanols

(2011) Hu Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(I)-Catalyzed Formal [5 + 1]/[2 + 2 + 1] Cycloaddition of 1-Yne-vinylcyclopropanes and Two CO Units: One-Step Construction of Multifunctional Angular Tricyclic 5/5/6 Compounds

(2011) Mu Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Heterocycle Synthesis Using an Internal Oxidant: Improved Reactivity and Mechanistic Studies

(2011) Nicolas Guimond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Investigating N-methoxy-N′-aryl ureas in oxidative C–H olefination reactions: an unexpected oxidation behaviour

(2011) Jens Willwacher et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhodium-catalyzed C–H activation and conjugate addition under mild conditions

(2011) Luo Yang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhodium-Catalyzed Selective C–H Activation/Olefination of Phenol Carbamates

(2011) Tian-Jun Gong et al.   ORGANIC LETTERS

Rhodium-Catalyzed Selective Olefination of Arene Esters via C−H Bond Activation

(2011) Sae Hume Park et al.   ORGANIC LETTERS

Rhodium-Catalyzed Oxidativeortho-Acylation of Benzamides with Aldehydes: Direct Functionalization of the sp2C–H Bond

(2011) Jihye Park et al.   ORGANIC LETTERS

Catalytic Asymmetric Addition of Arylboronic Acids to Isatins usingC2-Symmetric CationicN-Heterocyclic Carbenes (NHCs) Pd2+Diaqua Complexes as Catalysts

(2011) Zhen Liu et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Intermolecular Direct Amination of Aromatic C–H Bonds with N-Chloroamines

(2011) Ka-Ho Ng et al.   ORGANIC LETTERS

Synthesis of 1-Aminoisoquinolines via Rh(III)-Catalyzed Oxidative Coupling

(2011) Xiaohong Wei et al.   ORGANIC LETTERS

Cu(I)-catalyzed decarboxylative aldol-type and Mannich-type reactions for asymmetric construction of contiguous trisubstituted and quaternary stereocenters

(2011) Liang Yin et al.   TETRAHEDRON

Microwave-assisted nickel(II) acetylacetonate-catalyzed arylation of aldehydes with arylboronic acids

(2011) Wen Chen et al.   TETRAHEDRON LETTERS

Highly Selective Metalations of Pyridines and Related Heterocycles Using New Frustrated Lewis Pairs or tmp-Zinc and tmp-Magnesium Bases with BF3⋅OEt2

(2010) Milica Jaric et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Oxidative Olefination of CH Bonds in Acetophenones and Benzamides

(2010) Frederic W. Patureau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Vinyl Moiety as a Handle for Regiocontrol in the Preparation of Unsymmetrical 2,3-Aliphatic-Substituted Indoles and Pyrroles

(2010) Malcolm P. Huestis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-catalysed amine alkylation with alcohols in water

(2010) Ourida Saidi et al.   CHEMICAL COMMUNICATIONS

Metal-catalysed cleavage of carbon–carbon bonds

(2010) Masahiro Murakami et al.   CHEMICAL COMMUNICATIONS

Rhodium-catalyzed Oxidative Coupling/Cyclization of Benzamides with Alkynes via C–H Bond Cleavage

(2010) Satoshi Mochida et al.   CHEMISTRY LETTERS

Cobalt-Catalyzed Addition Reaction of Organoboronic Acids with Aldehydes: Highly Enantioselective Synthesis of Diarylmethanols

(2010) Jaganathan Karthikeyan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

(2010) Tetsuya Satoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Aryl Ketone Synthesis via Tandem Orthoplatinated Triarylphosphite-Catalyzed Addition Reactions of Arylboronic Acids with Aldehydes Followed by Oxidation

(2010) Yuan-Xi Liao et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed C−C Bond Cleavage: Construction of Acyclic Methyl Substituted Quaternary Stereogenic Centers

(2010) Tobias Seiser et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Substitution Reactions of Propargylic Amines: Importance of C(sp)−C(sp3) Bond Cleavage in Generation of Iminium Intermediates

(2010) Tsuyuka Sugiishi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Arene and Alkene C−H Bond Functionalization Leading to Indoles and Pyrroles

(2010) David R. Stuart et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh Catalyzed Olefination and Vinylation of Unactivated Acetanilides

(2010) Frederic W. Patureau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Intermolecular Hydroarylation of Alkynes

(2010) Derek J. Schipper et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Oxidative Cycloaddition of Benzamides and Alkynes via C−H/N−H Activation

(2010) Todd K. Hyster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pyrrole Synthesis via Allylic sp3C−H Activation of Enamines Followed by Intermolecular Coupling with Unactivated Alkynes

(2010) Souvik Rakshit et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Novel Axially Chiral Phosphine Ligand with a Fluoro Alcohol Moiety for Rh-Catalyzed Asymmetric Arylation of Aromatic Aldehydes

(2010) Satoshi Morikawa et al.   ORGANIC LETTERS

Rh(III)-Catalyzed Tandem Oxidative Olefination−Michael Reactions between Aryl Carboxamides and Alkenes

(2010) Fen Wang et al.   ORGANIC LETTERS

Rhodium-Catalyzed Alkenylation of Nitriles via Silicon-Assisted C−CN Bond Cleavage

(2010) Yusuke Kita et al.   ORGANIC LETTERS

Rh(III)-Catalyzed Oxidative Coupling ofN-Aryl-2-aminopyridine with Alkynes and Alkenes

(2010) Jinlei Chen et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Synthesis of Isoquinolines from Aryl KetoneO-Acyloxime Derivatives and Internal Alkynes

(2010) Pei Chui Too et al.   ORGANIC LETTERS

Rh(III)-Catalyzed Oxidative Coupling of Unactivated Alkenes via C−H Activation

(2010) Andy S. Tsai et al.   ORGANIC LETTERS

Axially chiral C2-symmetric N-heterocyclic carbene (NHC) palladium complexes-catalyzed asymmetric arylation of aldehydes with arylboronic acids

(2010) Rui Zhang et al.   TETRAHEDRON-ASYMMETRY

Combined Rhodium-Catalyzed Carbon-Hydrogen Activation and β-Carbon Elimination to access Eight-Membered Rings

(2009) Damien Crépin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Indanols from tert-Cyclobutanols Using a Rhodium-Catalyzed CC/CH Activation Sequence

(2009) Tobias Seiser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Me-bipam for Enantioselective Ruthenium(II)-Catalyzed Arylation of Aldehydes with Arylboronic Acids

(2009) Yasunori Yamamoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Directed Manganation of Functionalized Arenes and Heterocycles Using tmp2Mn⋅2 MgCl2⋅4 LiCl

(2009) Stefan H. Wunderlich et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemoselectivity in Catalytic CC and CH Bond Activation: Controlling Intermolecular Carboacylation and Hydroarylation of Alkenes

(2009) Michael T. Wentzel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The concise synthesis of chiral tfb ligands and their application to the rhodium-catalyzed asymmetric arylation of aldehydes

(2009) Takahiro Nishimura et al.   CHEMICAL COMMUNICATIONS

Synthesis of 3-hydroxyoxindoles by Pd-catalysed intramolecular nucleophilic addition of aryl halides to α-ketoamides

(2009) Yi-Xia Jia et al.   CHEMICAL COMMUNICATIONS

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

(2009) Denise A. Colby et al.   CHEMICAL REVIEWS

Stereoselective Restructuring of 3-Arylcyclobutanols into 1-Indanols by Sequential Breaking and Formation of Carbon–Carbon Bonds

(2009) Masanori Shigeno et al.   CHEMISTRY-A EUROPEAN JOURNAL

Environmentally benign metal-free decarboxylative aldol and Mannich reactions

(2009) Jérôme Baudoux et al.   GREEN CHEMISTRY

Rhodium-Catalyzed Mono- and Divinylation of 1-Phenylpyrazoles and Related Compounds via Regioselective C−H Bond Cleavage

(2009) Nobuyoshi Umeda et al.   JOURNAL OF ORGANIC CHEMISTRY

A Pd(II)-Catalyzed Ring-Expansion Reaction of Cyclic 2-Azidoalcohol Derivatives: Synthesis of Azaheterocycles

(2009) Shunsuke Chiba et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nucleophile Generation via Decarboxylation: Asymmetric Construction of Contiguous Trisubstituted and Quaternary Stereocenters through a Cu(I)-Catalyzed Decarboxylative Mannich-Type Reaction

(2009) Liang Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isoquinoline Synthesis via Rhodium-Catalyzed Oxidative Cross-Coupling/Cyclization of Aryl Aldimines and Alkynes

(2009) Nicolas Guimond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective metal-catalyzed activation of strained rings

(2009) Tobias Seiser et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Kinetic Resolution of Racemic 1-Alkyl-2-methylenecyclopropanes via Palladium-Catalyzed Silaborative C−C Cleavage

(2009) Toshimichi Ohmura et al.   ORGANIC LETTERS

Direct Functionalization of Nitrogen Heterocycles via Rh-Catalyzed C−H Bond Activation

(2008) Jared C. Lewis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Metal−Organic Cooperative Catalysis in C−H and C−C Bond Activation and Its Concurrent Recovery

(2008) Young Jun Park et al.   ACCOUNTS OF CHEMICAL RESEARCH

A General Method formeta andpara Functionalization of Arenes Using TMP2Mg⋅2 LiCl

(2008) Christoph J. Rohbogner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Synthesis of Primary Amines Directly from Alcohols and Ammonia

(2008) Chidambaram Gunanathan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective CC Bond Activation of Allenyl Cyclobutanes: Access to Cyclohexenones with Quaternary Stereogenic Centers

(2008) Tobias Seiser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Rhodium-Catalyzed Addition of Arylboronic Acids to α-Ketoesters

(2008) Hai-Feng Duan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluorescent Naphthyl- and Anthrylazoles from the Catalytic Coupling of Phenylazoles with Internal Alkynes through the Cleavage of Multiple CH Bonds

(2008) Nobuyoshi Umeda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient 1,2-Addition of Aryl- and Alkenylboronic Acids to Aldehydes Catalyzed by the Palladium/Thioether−Imidazolinium Chloride System

(2008) Masami Kuriyama et al.   JOURNAL OF ORGANIC CHEMISTRY

Axial Coordination of NHC Ligands on Dirhodium(II) Complexes: Generation of a New Family of Catalysts

(2008) Alexandre F. Trindade et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper(II) Acetate-Catalyzed Addition of Arylboronic Acids to Aromatic Aldehydes

(2008) Hanmei Zheng et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Diastereo- and Enantioselective Wagner−Meerwein Shift: Control of Absolute Stereochemistry in the C−C Bond Migration Event

(2008) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Silylation and Intramolecular Arylation of Nitriles via the Silicon-Assisted Cleavage of Carbon−Cyano Bonds

(2008) Mamoru Tobisu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Sequential Carbon−Carbon Bond Cleavage/Formation Producing Arylated Benzolactones

(2008) Takanori Matsuda et al.   ORGANIC LETTERS

Orthoplatinated Triarylphosphite as a Highly Efficient Catalyst for Addition Reactions of Arylboronic Acids with Aldehydes: Low Catalyst Loading Catalysis and a New Tandem Reaction Sequence

(2008) Yuan-Xi Liao et al.   ORGANIC LETTERS

FeCl3-Catalyzed 1,2-Addition Reactions of Aryl Aldehydes with Arylboronic Acids

(2008) Tao Zou et al.   ORGANIC LETTERS

Nickel-Catalyzed Coupling of Alkyne-Tethered Vinylcyclopropanes and Allyl Chloride

(2008) Shin-ichi Ikeda et al.   ORGANOMETALLICS

Transition-Metal-Catalyzed Carbon-Carbon Bond Formation via Carbon-Hydrogen Bond Cleavage

(2008) Fumitoshi Kakiuchi et al.   SYNTHESIS-STUTTGART

Novel cleavage of (E)-allyl vic-diols to aldehydes using the 2nd-generation Grubbs catalyst

(2008) Chunguang Han et al.   TETRAHEDRON LETTERS

Cyclopalladated complexes catalyzed addition of arylboronic acids to aldehydes in neat water

(2008) Ajuan Yu et al.   TETRAHEDRON LETTERS

Nickel salt-catalyzed addition reaction of arylboronic acids to aromatic aldehydes

(2008) Li Zhou et al.   TETRAHEDRON LETTERS

Rhodium-Catalyzed Allylation of Aldehydes with Homoallylic Alcohols by Retroallylation and Isomerization to Saturated Ketones with Conventional or Microwave Heating

(2007) Yuto Sumida et al.   Chemistry-An Asian Journal