期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 17, 期 21, 页码 5903-5907出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201003621
关键词
chemoselectivity; hydrazine; iron; phthalocyanines; reduction; regioselectivity
资金
- CSIR
- UGC
- CSIR
- UGC
Iron phthalocyanine with iron sulfate has been successfully applied for high chemo- and regioselective reduction of aromatic nitro compounds to give the corresponding amines in a green solvent system without using any toxic ligand. The catalytic systems were also compatible with a large range of other reducible functional groups, such as keto, acid, amide, ester, halogen, lactone, nitrile, N-benzyl, O-benzyl, hydroxy, and heterocycles. In the present study, dinitro compounds have been regioselectively reduced to the corresponding amines with high yield. In most of the cases the conversion and selectivity was greater than 99% as determined by GC-MS analysis.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据