Nickel-Catalyzed CH Arylation of Azoles with Haloarenes: Scope, Mechanism, and Applications to the Synthesis of Bioactive Molecules

Oxidative Biaryl Coupling of Thiophenes and Thiazoles with Arylboronic Acids through Palladium Catalysis: Otherwise Difficult C4-Selective CH Arylation Enabled by Boronic Acids

(2011) Sylvia Kirchberg et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

tert-Butoxide-Mediated CH Bond Arylation of Aromatic Compounds with Haloarenes

(2011) Shuichi Yanagisawa et al.   ChemCatChem

Oxidative C–H/C–H Coupling of Azine and Indole/Pyrrole Nuclei: Palladium Catalysis and Synthesis of Eudistomin U

(2011) Atsushi D. Yamaguchi et al.   CHEMISTRY LETTERS

Direct Arylation of Simple Azoles Catalyzed by 1,10-Phenanthroline Containing Palladium Complexes: An Investigation of C4 Arylation of Azoles and the Synthesis of Triarylated Azoles by Sequential Arylation

(2011) Fumitoshi Shibahara et al.   JOURNAL OF ORGANIC CHEMISTRY

Toward Ideal Arene Assembly: Catalytic C-H Bond Arylation of Aromatic Compounds

(2011) Kenichiro Itami   JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN

A General Catalyst for the β-Selective C-H Bond Arylation of Thiophenes with Iodoarenes

(2010) Kirika Ueda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Direct CH Arylation and Alkenylation of Heteroarenes with Organosilicon Reagents

(2010) Hitoshi Hachiya et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative Nickel-Air Catalysis in CH Arylation: Direct Cross-Coupling of Azoles with Arylboronic Acids using Air as Sole Oxidant

(2010) Hitoshi Hachiya et al.   ChemCatChem

Direct multiple C–H bond arylation reaction of heteroarenes catalyzed by cationic palladium complex bearing 1,10-phenanthroline

(2010) Fumitoshi Shibahara et al.   CHEMICAL COMMUNICATIONS

Selective C-4 Alkylation of Pyridine by Nickel/Lewis Acid Catalysis

(2010) Yoshiaki Nakao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bimetallic Nickel Aluminun MediatedPara-Selective Alkenylation of Pyridine: Direct Observation of η2,η1-Pyridine Ni(0)−Al(III) Intermediates Prior to C−H Bond Activation

(2010) Chung-Chih Tsai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Highly Efficient Palladium/Copper Cocatalytic System for Direct Arylation of Heteroarenes: An Unexpected Effect of Cu(Xantphos)I

(2010) Jinkun Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium Catalysis for CH Bond Arylation of Heteroarenes with Iodoarenes

(2009) Benoît Join et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage

(2009) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Direct Arylation of Azine and AzoleN-Oxides: Reaction Development, Scope and Applications in Synthesis

(2009) Louis-Charles Campeau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Reaction of Arylzinc Reagents with N-Aromatic Heterocycles: A Straightforward Approach to C−H Bond Arylation of Electron-Deficient Heteroaromatic Compounds

(2009) Mamoru Tobisu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Direct Alkynylation of Azoles with Alkynyl Bromides

(2009) Naoto Matsuyama et al.   ORGANIC LETTERS

Cp2Ni-KOt-Bu-BEt3(or PPh3) Catalyst System for Direct C−H Arylation of Benzene, Naphthalene, and Pyridine

(2009) Osamu Kobayashi et al.   ORGANIC LETTERS

Nickel-Catalyzed Direct Arylation of Azoles with Aryl Bromides

(2009) Hitoshi Hachiya et al.   ORGANIC LETTERS

Nickel-Catalyzed Biaryl Coupling of Heteroarenes and Aryl Halides/Triflates

(2009) Jérôme Canivet et al.   ORGANIC LETTERS

Direct Functionalization of Nitrogen Heterocycles via Rh-Catalyzed C−H Bond Activation

(2008) Jared C. Lewis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-Catalyzed Direct Arylations of Heteroarenes with Tosylates and Mesylates

(2008) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Coupling of Aryl Bromides in the Presence of Alkyllithium Reagents

(2008) Sarav B. Jhaveri et al.   CHEMISTRY-A EUROPEAN JOURNAL

Total Synthesis of Thiopeptide Antibiotics GE2270A, GE2270T, and GE2270C1

(2008) K. C. Nicolaou et al.   Chemistry-An Asian Journal

Ligandless Microwave-Assisted Pd/Cu-Catalyzed Direct Arylation of Oxazoles

(2008) François Besselièvre et al.   JOURNAL OF ORGANIC CHEMISTRY

Nickel-Catalyzed Alkenylation and Alkylation of Fluoroarenes via Activation of C−H Bond over C−F Bond

(2008) Yoshiaki Nakao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A General Method for Copper-Catalyzed Arylation of Arene C−H Bonds

(2008) Hien-Quang Do et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C2, C5, and C4 AzoleN-Oxide Direct Arylation Including Room-Temperature Reactions

(2008) Louis-Charles Campeau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Strategy for C−H Activation of Pyridines:  Direct C-2 Selective Alkenylation of Pyridines by Nickel/Lewis Acid Catalysis

(2008) Yoshiaki Nakao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Potassiumt-Butoxide Alone Can Promote the Biaryl Coupling of Electron-Deficient Nitrogen Heterocycles and Haloarenes

(2008) Shuichi Yanagisawa et al.   ORGANIC LETTERS

Copper-Mediated C−H Bond Arylation of Arenes with Arylboronic Acids

(2008) Ikuya Ban et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed Carbon-Carbon Bond Formation via Carbon-Hydrogen Bond Cleavage

(2008) Fumitoshi Kakiuchi et al.   SYNTHESIS-STUTTGART

Direct coupling of arenes and iodoarenes catalyzed by a rhodium complex with a strongly π-accepting phosphite ligand

(2008) Shuichi Yanagisawa et al.   TETRAHEDRON

Copper-mediated direct arylation of benzoazoles with aryl iodides

(2008) Tomoki Yoshizumi et al.   TETRAHEDRON LETTERS

Total Synthesis of (−)-Hennoxazole A

(2007) Thomas E. Smith et al.   JOURNAL OF ORGANIC CHEMISTRY