期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 16, 期 4, 页码 1106-1123出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200901923
关键词
coordination polymers; liquid crystals; N ligands; transition metals
资金
- MIUR
- CARIPLO [2007-5117]
- Valle Esina SPA
The preparation, characterization, and optimization of the functional properties of mono- and polynuclear coordination complexes containing heteroaromatic nitrogen ligands are discussed here, taking the advantage of numerous studies performed in our laboratories on exploring a variety of different metal ions and polytopic ligands. We highlight how very minor changes in connectivity, composition, and polarity of the molecular entities employed in the self-assembly steps may significantly affect the structural, thermal, sorptive, magnetic, and mesomorphic behavior of the resulting materials. Examples from three different classes are included: 1) pyrazolate-based polynuclear coordination compounds, 2) homoleptic and heteroleptic coordination polymers, and 3) 2,2'-bipyridine metal-based liquid crystals.
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