4.6 Article

MnOx Nanoparticles Supported on a New Mesostructured Silicate with Textural Porosity

期刊

CHEMISTRY-A EUROPEAN JOURNAL
卷 16, 期 19, 页码 5783-5793

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200902851

关键词

silicate support; manganese oxide; nanoparticles; porosity; structure property relationships

资金

  1. Slovenian Research Agency [PI-0021, P1-00112, 2006600]

向作者/读者索取更多资源

A two-step synthesis of a novel mesostructured silicate. KIL-2, and its manganese-containing analogue. Mn/KIL-2, has been developed. KIL-2 possesses interparticle mesopores with pore dimensions between 5 and 60 urn and a surface area of 448 m(2). The mespores are formed by the aggregation of silica nanoparticles, which creates a network with interparticle voids. The particle size and the pore diameters depend on the temperature of the ageing step (first step) and on the solvothermal treatment in ethanol (second step), respectively. Mn/KIL-2 contains octahedrally coordinated Mn3+ (80%) and tetrahedrally coordinated Mn2+ (20 %) ions. Mn3+ ions are present in the extra-framework MnOx nanoparticles with typical dimensions of 2 nm, which are homogeneously distributed throughout the material. Mn2+ ions occur as isolated manganese framework sites. The material is also able to retain its structure characteristics after the hydrothermal treatment in boiling water. Because of its nontoxic nature and cost-effective synthesis, Mn/KIL-2 thus exhibits properties that are needed for an environment-friendly catalyst.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Chemistry, Applied

Titania versus zinc oxide nanoparticles on mesoporous silica supports as photocatalysts for removal of dyes from wastewater at neutral pH

Darja Maucec, Andraz Suligoj, Alenka Ristic, Goran Drazic, Albin Pintar, Natasa Novak Tusar

CATALYSIS TODAY (2018)

Article Chemistry, Physical

Improved performance of binder-free zeolite Y for low-temperature sorption heat storage

Alenka Ristic, Fabian Fischer, Andreas Hauer, Natasa Zabukovec Logar

JOURNAL OF MATERIALS CHEMISTRY A (2018)

Article Chemistry, Multidisciplinary

New Composite Water Sorbents CaCl2-PHTS for Low-Temperature Sorption Heat Storage:Determination of Structural Properties

Alenka Ristic, Natasa Zabukovec Logar

NANOMATERIALS (2019)

Article Chemistry, Multidisciplinary

New Insights into Manganese Local Environment in MnS-1 Nanocrystals

Alenka Ristic, Matjaz Mazaj, Iztok Arcon, Nina Daneu, Natasa Zabukovec Logar, Roger Glaeser, Natasa Novak Tusar

CRYSTAL GROWTH & DESIGN (2019)

Article Chemistry, Applied

Bimetal Cu-Mn porous silica-supported catalyst for Fenton-like degradation of organic dyes in wastewater at neutral pH

Andraz Suligoj, Alenka Ristic, Goran Drazic, Albin Pintar, Natasa Zabukovec Logar, Natasa Novak Tusar

CATALYSIS TODAY (2020)

Article Chemistry, Physical

Synergistic effect of CuO nanocrystals and Cu-oxo-Fe clusters on silica support in promotion of total catalytic oxidation of toluene as a model volatile organic air pollutant

Petar Djinovic, Alenka Ristic, Tadej Zumbar, Venkata D. B. C. Dasireddy, Mojca Rangus, Goran Drazic, Margarita Popova, Blaz Likozar, Natasa Zabukovec Logar, Natasa Novak Tusar

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

Article Chemistry, Multidisciplinary

Evolution of Surface Catalytic Sites on Bimetal Silica-Based Fenton-Like Catalysts for Degradation of Dyes with Different Molecular Charges

Ivalina Trendafilova, Andraz Suligoj, Alenka Ristic, Nigel Van de Velde, Goran Drazic, Mojca Opresnik, Natasa Zabukovec Logar, Albin Pintar, Natasa Novak Tusar

NANOMATERIALS (2020)

Article Chemistry, Physical

Influence of Alumina Precursor Properties on Cu-Fe Alumina Supported Catalysts for Total Toluene Oxidation as a Model Volatile Organic Air Pollutant

Tadej Zumbar, Alenka Ristic, Goran Drazic, Hristina Lazarova, Janez Volavsek, Albin Pintar, Natasa Zabukovec Logar, Natasa Novak Tusar

Summary: The role of alumina support precursors in Cu-Fe/Al2O3 catalysts for the total oxidation of toluene has been elucidated, with important factors being the structural order of the support precursor, homogeneous distribution of catalytic sites, and metal oxide distribution on the support. Homogeneous distribution of FexOy and CuOx with defined Cu/Fe molar ratio on the Al2O3 support is required for efficient catalytic performance. Introducing low iron concentration during alumina support synthesis procedure leads to a beneficial effect of homogeneous metal oxide distribution on the support.

CATALYSTS (2021)

Article Crystallography

Tailoring Water Adsorption Capacity of APO-Tric

Suzana Mal, Alenka Ristic, Amalija Golobic, Natasa Zabukovec Logar

Summary: The use of ionic liquids as solvents in green synthesis of APO-Tric can enhance the performance of water adsorbents in thermal energy storage and reduce costs. APO-Tric prepared by ionothermal synthesis shows higher water adsorption capacity and more structural defects compared to hydrothermal synthesis.

CRYSTALS (2021)

Article Energy & Fuels

Synthesis of Mesoporous γ-Alumina Support for Water Composite Sorbents for Low Temperature Sorption Heat Storage

Manca Ocvirk, Alenka Ristic, Natasa Zabukovec Logar

Summary: The efficiency of thermochemical heat storage depends on the sorbent used, with higher surface area and pore volume observed in mesoporous gamma-Al2O3 prepared by solvothermal synthesis. Proper design and selection of sorbents are crucial for achieving high-efficiency heat storage.

ENERGIES (2021)

Article Crystallography

Evaluation of ZIF-8 and ZIF-90 as Heat Storage Materials by Using Water, Methanol and Ethanol as Working Fluids

Ciara Byrne, Alenka Ristic, Suzana Mal, Mojca Opresnik, Natasa Zabukovec Logar

Summary: This study examined the potential heat storage applications of two different sodalite-type ZIF structures (ZIF-8 and ZIF-90) for adsorption of water, methanol and ethanol, with ZIF-90-water showing the best desorption enthalpy, fastest sorption kinetics and highest potential for heat storage/reallocation applications. This was attributed to ZIF-90's significantly smaller particle size, higher specific surface area, and presence of mesoporosity and polar groups compared to ZIF-8.

CRYSTALS (2021)

Article Crystallography

Thermal Energy Storage Materials (TESMs)-What Does It Take to Make Them Fly?

Saman Nimali Gunasekara, Camila Barreneche, A. Ines Fernandez, Alejandro Calderon, Rebecca Ravotti, Alenka Ristic, Peter Weinberger, Halime Omur Paksoy, Burcu Kocak, Christoph Rathgeber, Justin Ningwei Chiu, Anastasia Stamatiou

Summary: Thermal Energy Storage Materials (TESMs) show great potential in realizing a carbon neutral future. They are mainly classified into phase change materials (PCMs), thermochemical heat storage materials (TCMs), and sensible thermal energy storage materials (STESMs), each with different advantages and characteristics. Research in TESMs is primarily concentrated in countries such as China, the European Union, and the USA, but there are still obstacles to commercialization and application.

CRYSTALS (2021)

Article Biochemistry & Molecular Biology

Low-Temperature Toluene Oxidation on Fe-Containing Modified SBA-15 Materials

Ivalina Trendafilova, Manuel Ojeda, John M. Andresen, Alenka Ristic, Momtchil Dimitrov, Natasa Novak Tusar, Genoveva Atanasova, Margarita Popova

Summary: Transition metals as catalysts for total VOC oxidation at low temperatures are challenging. This study prepared and tested iron-modified SBA-15, AlSBA-15, and ZrSBA-15 materials with varying Fe loading for toluene oxidation. The results showed that increasing Fe loading improved the oxidation rate and decreased the temperature required for complete toluene removal. Surface properties of the mesoporous support influenced the type and localization of iron oxide species, and 5 wt. % Fe-containing ZrSBA-15 exhibited excellent activity in the total oxidation of toluene at lower temperatures due to the synergistic effect of Fe-Zr and the presence of accessible and stable Fe2+/Fe3+ active sites.

MOLECULES (2023)

Correction Chemistry, Physical

Synergistic effect of CuO nanocrystals and Cu-oxo-Fe clusters on silica support in promotion of total catalytic oxidation of toluene as a model volatile organic air pollutant (vol 268, 118749, 2020)

Petar Djinovic, Alenka Ristic, Tadej Zumbar, Venkata D. B. C. Dasireddy, Mojca Rangus, Goran Drazic, Margarita Popova, Blaz Likozar, Natasa Zabukovec Logar, Natasa Novak Tusar

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

Proceedings Paper Energy & Fuels

New Water Adsorbent for Adsorption Driven Chillers

Alenka Ristic, Andraz Krajnc, Natasa Zabukovec Logar

PROCEEDINGS OF THE ISES EUROSUN 2018 CONFERENCE - 12TH INTERNATIONAL CONFERENCE ON SOLAR ENERGY FOR BUILDINGS AND INDUSTRY (2018)

暂无数据