期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 16, 期 1, 页码 368-375出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200901481
关键词
conjugation; density functional calculations; fluorescence; silicon; spiro compounds
资金
- MEXT
- JSPS
pi-Extended silafluorenes and spirobisilafluorenes bearing electron-donating aminostyryl substituents at the 2,7- or 3,6-positions were synthesized by a Horner-Wadsworth-Emmons reaction. The electronic influence of spirocyclic structure and substitution mode of the aminostyryl substituents was investigated by UV/Vis spectroscopy, which indicated the existence of a spiroconjugation effect in the 3,6-substituted spirobisilafluorene. They exhibited moderate to strong fluorescence emission, and the fluorescence properties were compatible with the UV/Vis absorption characteristics, except for the 3,6-substituted spirobisilafluorene, which showed relatively large enhancement of fluorescence quantum yield and Stokes shift. The influence of the spirocyclic structure and substitution mode on the photophysical properties of the silicon compounds was investigated by DFT calculations.
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