期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 14, 期 34, 页码 10520-10529出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200801149
关键词
macrocycles; organic synthesis; salen; supramolecular chemistry; templates
资金
- Institute of Chemical Research of Catalonia (ICIQ)
- Institucio Catalana de Recerca i Estudis Avancats (ICREA)
- ICREA Funding Source: Custom
Templated approaches towards selective organic synthesis is it common feature in nature in which nucleic acid templated synthesis plays a crucial role in various fundamental biological processes. The key feature that allows control over the amazing selectivity found in natural processes is evidently the effective molarity of the reaction partners that is mediated by the macromolecular templation event. An ongoing challenge within many chemical sciences is to exploit similar templating principles and make use of synthetic systems that are designed for specific chemical conversions. Here. we describe the recent developments that involve (metallo)salen scaffolds that are used for diverse templating events (sale it = N,N'-bis(salicylidene)ethylenediamine dianion).
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