期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 14, 期 36, 页码 11488-11499出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200801702
关键词
heterogeneous catalysis; Lewis acids; magnesium fluoride; sol-gel processes; vitamins
资金
- Alexander von Humboldt Foundation
Novel magnesium fluorides have been prepared by a new fluorolytic sol-gel synthesis for fluoride materials based on aqueous HE By changing the amount of water at constant stoichiometric amount of HE it is possible to tune the surface acidity of the resulting partly hydroxylated magnesium fluorides. These materials possess medium-strength Lewis acid sites and, by increasing the amount of water, Bronsted acid sites as well. Magnesium hydroxyl groups normally have a basic nature and only with this new synthetic route is it possible to create Bronsted acidic magnesium hydroxyl groups. XRD, MAS NMR, TEM, thermal analysis, and elemental analysis have been applied to study the structure, composition, and thermal behaviour of the bulk materials. XPS measurements. FTIR with probe molecules. and the determination of N-2/Ar adsorption-desorption isotherms have been carried Out to investigate the Surface properties. Furthermore, activity data have indicated that the tuning of the acidic properties makes these materials versatile catalysts for different classes of reactions, such as the synthesis of (all-rac)-[alpha]-tocopherol through the condensation of 2.3,6-trimethy1hydroquinone (TMHQ) with isophytol (1p).
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