期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 14, 期 28, 页码 8572-8578出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200800793
关键词
allenes; chemoselectivity; gold; palladium; regioselectivity
资金
- National Natural Science Foundation of China [20423001, 20732005]
- State Key Basic Research & Development Program [2006CB06105]
Efficient room-temperature syntheses of cyclopentenes and 4,5-dihydrofurans with different substitution patterns were performed starting from the same materials (i.e., 2-(2',3'-allenyl)acetyl acetates). Depending on the choice of metal catalyst, the Au-catalyzed reaction afforded C-attack-5-endo cyclization products 2, whereas the Pd-catalyzed one led to the formation of O-attack-5-exo cyclization products 3. The selectivity may be explained by the steric and electronic effects of the substrates and catalysts.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据