Article
Materials Science, Multidisciplinary
K. Willa, R. Willa, F. Hardy, L. Wang, P. Schweiss, T. Wolf, C. Meingast
Summary: In this study, the influence of magnetic fields on the superconductivity and magnetostructural transition in Ba1-xKxFe2As2 was investigated. The results showed that the magnetic field suppresses the reentrance of the orthorhombic phase, indicating that the weakening of the superconducting order is the main cause.
Article
Chemistry, Physical
Colin P. Harmer, Saeed Kamali, Oleg Lebedev, Shannon J. Lee, Raquel A. Ribeiro, Paul C. Canfield, Kirill Kovnir
Summary: Systematic synthesis and characterization of a new tetrahedral FeS-ethylenediamine intercalate compound were conducted. The crystal structure and composition were determined using various techniques, revealing the presence of iron vacancies and their effect on the magnetic properties.
CHEMISTRY OF MATERIALS
(2022)
Article
Multidisciplinary Sciences
Jun Cui, Emil Vinas Bostroem, Mykhaylo Ozerov, Fangliang Wu, Qianni Jiang, Jiun-Haw Chu, Changcun Li, Fucai Liu, Xiaodong Xu, Angel Rubio, Qi Zhang
Summary: The research team observed magnon-induced chiral phonons and chirality selective magnon-phonon hybridization in the antiferromagnet FePSe3, which provides new insights for the development of angular momentum-based hybrid phononic and magnonic devices.
NATURE COMMUNICATIONS
(2023)
Article
Physics, Multidisciplinary
Jia Yu, Tong Liu, BinBin Ruan, Kang Zhao, QingSong Yang, MengHu Zhou, ZhiAn Ren
Summary: The study investigates the evolution of superconductivity and magnetism in EuFeAs2 and Eu0.9Pr0.1FeAs2 through cobalt doping. Cobalt doping has little effect on the Eu-related antiferromagnetic transition in EuFeAs2, but rapidly decreases the Fe-related spin density wave transition temperature, while inducing superconductivity. In Eu0.9Pr0.1FeAs2, magnetism and superconductivity show similar evolutions upon cobalt doping, with the highest transition temperature reaching 30.6 K.
SCIENCE CHINA-PHYSICS MECHANICS & ASTRONOMY
(2021)
Article
Physics, Applied
Karciano J. S. Silva, David A. Landinez-Tellez, Petrucio Barrozo, I. Garcia-Fornaris, J. Albino Aguiar
Summary: This study reports on the sintering, structural, morphological, electrical, and magnetic characterization of the superconducting FeSe0.88. The sample was prepared using the solid-state reaction method at 600 degrees C in an evacuated borosilicate tube. X-ray diffractograms revealed the formation of two minor impurity phases, Fe7Se8 and FeSe, both with hexagonal structures, which are not superconducting. Resistivity measurements showed the onset superconducting temperature at Tconset is approximately 8.6 K. Magnetic measurements demonstrated a ferromagnetic-paramagnetic phase transition around 875 K for the FeSe0.88 compound.
JOURNAL OF SUPERCONDUCTIVITY AND NOVEL MAGNETISM
(2023)
Article
Chemistry, Inorganic & Nuclear
Timothy J. Diethrich, Peter Y. Zavalij, Stephanie Gnewuch, Efrain E. Rodriguez
Summary: Transition-metal thiophosphates and selenophosphates are layered systems that have potential for 2D magnetic phenomena. The crystal structures and magnetic properties of two lithium transition-metal thiophosphates, Li1.56Co0.71P2S6 and Li2.26Fe0.94P2S6, were presented. Both compounds show magnetic anisotropy and no long-range magnetic order down to 5 K. The presence of unusual anions in Li1.56Co0.71P2S6 suggests ambiguity in its oxidation state.
INORGANIC CHEMISTRY
(2021)
Article
Materials Science, Multidisciplinary
Timothy Ferreira, Shree Ram Acharya, Ying Wai Li, David S. Parker, Athena S. Sefat, Valentino R. Cooper
Summary: The study investigates the thermodynamic obstacles faced by 3d elements adopting the infinite layer structure type using SrFeOx system, discussing synthetic considerations for the transformation from ABO(3) to ABO(2), and demonstrating the necessity of H incorporation for stabilizing the SrFeO2 phase.
PHYSICAL REVIEW MATERIALS
(2021)
Article
Chemistry, Physical
Armando Galluzzi, Krastyo Buchkov, Vihren Tomov, Elena Nazarova, Antonio Leo, Gaia Grimaldi, Massimiliano Polichetti
Summary: The magnetization of an Fe(Se, Te) single crystal was measured as a function of temperature and dc magnetic field, revealing the sample's critical temperature and magnetic background. Analysis of the superconducting hysteresis loops showed the presence of a second magnetization peak phenomenon. Investigation of different pinning centers in the sample indicated the existence of collective pinning theory, with calculations of pinning force density performed to evaluate the sample's potential for high-current and high-power applications.
Article
Materials Science, Multidisciplinary
S. L. Skornyakov, V. Anisimov, I Leonov
Summary: The study focuses on the electronic structure of Cu-doped NaFeAs using the DFT+DMFT method, revealing the crucial importance of strong electron-electron interactions and local potential differences between Cu and Fe ions in understanding the spectral properties and magnetic behavior of the material. The research shows a significant orbital-selective localization of Fe 3d states upon Cu doping, leading to a coherence-to-incoherence crossover and potential Mott metal-insulator transition in heavily doped NaFeAs.
Article
Chemistry, Physical
Armando Galluzzi, Antonio Leo, Andrea Masi, Francesca Varsano, Angela Nigro, Gaia Grimaldi, Massimiliano Polichetti
Summary: By analyzing the magnetic behavior of a CaKFe4As4 polycrystalline sample, we have found strong pinning characteristics at different temperatures, which may lead to future improvement in the fabrication of this material.
Article
Chemistry, Multidisciplinary
Armando Galluzzi, Antonio Leo, Andrea Masi, Francesca Varsano, Angela Nigro, Gaia Grimaldi, Massimiliano Polichetti
Summary: This study focuses on the vortex phase diagram of CaKFe4As4, which is helpful for understanding the applicative ranges in field and temperature of these materials. Different magnetic measurements were performed to draw a complete vortex phase diagram for a CaKFe4As4 polycrystalline iron-based superconductor, revealing a second magnetization peak effect and a transition in the vortex lattice from elastic to plastic behavior.
APPLIED SCIENCES-BASEL
(2023)
Article
Physics, Condensed Matter
Raquel Fernandez-Martin, Maria J. Calderon, Laura Fanfarillo, Belen Valenzuela
Summary: The analysis reveals that the orbital matching between the hole and electron pockets is the key parameter determining the momentum dependence and hierarchy of superconducting gaps in iron-based superconductors, rather than the common nesting scenario of Fermi surface matching.
Article
Chemistry, Multidisciplinary
Owen P. Missen, Stuart J. Mills, Stefano Canossa, Joke Hadermann, Gwilherm Nenert, Matthias Weil, Eugen Libowitzky, Robert M. Housley, Werner Artner, Anthony R. Kampf, Michael S. Rumsey, John Spratt, Koichi Momma, Maja A. Dunstan
Summary: The study investigated synthetic and naturally occurring forms of tricopper orthotellurate using different techniques such as 3D electron diffraction, X-ray powder diffraction, Raman, and infrared spectroscopy. It identified two polytypes of the compound, a higher-symmetric cubic form and a lower-symmetric orthorhombic form. Differentiation between these polytypes was achieved through X-ray powder diffraction and Raman spectroscopic analysis.
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS
(2022)
Article
Chemistry, Inorganic & Nuclear
Aleksandra A. Savina, Viktoriia V. Saiutina, Anatolii Morozov, Anton O. Boev, Dmitry A. Aksyonov, Catherine Dejoie, Maria Batuk, Sara Bals, Joke Hadermann, Artem M. Abakumov
Summary: A study found that Li2MoO3, a Li-rich layered rock-salt-type oxide, exhibits a wide range of cationic nonstoichiometry. Solid solutions of Li2+xMo1-xO3(-0.037 <= x <= 0.124) were successfully synthesized through hydrogen reduction of Li2MoO4 at different temperatures. The solid solutions adopt a monoclinically distorted O3-type layered average structure with a robust local ordering of the Li cations and Mo3 triangular clusters. Electron diffraction and aberration-corrected scanning transmission electron microscopy (STEM) were used to examine the local structure, and density functional theory (DFT)-based calculations were performed to support the proposed atomic arrangement and explain the electrochemical behavior of Li2MoO3 in lithium batteries.
INORGANIC CHEMISTRY
(2022)
Article
Materials Science, Ceramics
Alessio Zandona, Sandra Ory, Cecile Genevois, Emmanuel Veron, Aurelien Canizares, Michael J. Pitcher, Mathieu Allix
Summary: The impact of TiO2 additions on the quenchability of melts derived from spodumene, eucryptite, and nepheline was investigated. The results show that the role of TiO2 during devitrification depends on the composition. TiO2 interacts with other glass components and reduces glass stability. The study also suggests that reducing SiO2 content and preferring peraluminous compositions can enhance the glass-forming ability of TiO2-rich aluminosilicate melts.
JOURNAL OF NON-CRYSTALLINE SOLIDS
(2022)
Article
Materials Science, Ceramics
Marion Dubernet, Michael J. Pitcher, Mustapha Zaghrioui, Micka Bah, Julien Bustillo, Fabien Giovannelli, Isabelle Monot-Laffez
Summary: The substitution of Ta in K0.5Na0.5NbO3 lead free piezoelectrics has been shown to improve the piezoelectric properties, but it also leads to heterogeneous microstructures. Two synthesis routes have been studied to prepare K0.5Na0.5Nb0.8Ta0.2O3 (KNNTa) substituted powders. Densified KNNTa ceramics were obtained using spark plasma sintering (SPS), and the use of a synthesized oxide precursor Nb1.6Ta0.4O5 showed successful Ta substitution with enhanced electromechanical coupling coefficients and low electrical losses.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2022)
Article
Chemistry, Multidisciplinary
Dingyue Hu, Karl Dawson, Marco Zanella, Troy D. Manning, Luke M. Daniels, Nigel D. Browning, B. Layla Mehdi, Yaobin Xu, Houari Amari, J. Felix Shin, Michael J. Pitcher, Ruiyong Chen, Hongjun Niu, Bowen Liu, Matthew Bilton, Junyoung Kim, John B. Claridge, Matthew J. Rosseinsky
Summary: This study reports an oxygen cathode material, BSCFW-xMg, that exhibits excellent electrocatalytic performance through the addition of an optimized amount of Mg to the self-assembled nanocomposite BSCFW. The Mg2+ ions concentrate at the interface of BSCFW, resulting in stressed and compositionally inhomogeneous regions. This interfacial chemistry provides an additional degree of freedom for performance optimization and promotes the durability of alkaline-earth based fuel cell materials.
ADVANCED MATERIALS INTERFACES
(2022)
Review
Materials Science, Multidisciplinary
Iva Milisavljevic, Michael J. Pitcher, Jianqiang Li, Sebastien Chenu, Mathieu Allix, Yiquan Wu
Summary: There is a growing research interest in the development and application of transparent ceramics. The advancement in the crystallization of glass into transparent ceramics offers an alternative method to overcome technical difficulties in traditional processing. It allows for the synthesis of high-density/low-porosity transparent ceramics with stable and metastable phases or even non-cubic structures.
INTERNATIONAL MATERIALS REVIEWS
(2023)
Article
Chemistry, Multidisciplinary
Weiwei Cao, Ana Isabel Becerro, Victor Castaing, Xue Fang, Pierre Florian, Franck Fayon, Didier Zanghi, Emmanuel Veron, Alessio Zandona, Cecile Genevois, Michael J. Pitcher, Mathieu Allix
Summary: Y3Al5O12 (YAG) is a widely used phosphor host with optical properties controlled by chemical substitution at YO8 or AlO6/AlO4 sublattices, resulting in different emission wavelengths. Nonstoichiometric compositions of Y3+xAl5-xO12 have been synthesized, allowing for new emission wavelengths and activator ions coordination environments. The nonstoichiometric YAG:Ce3+ system has a different response to up-conversion luminescence compared to stoichiometric counterparts, while the down-conversion emission is weakly affected. This study also demonstrates the synthesis of nonstoichiometric garnet materials, opening possibilities for property tuning and new applications.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Svetlana M. M. Posokhova, Vladimir A. A. Morozov, Dina V. V. Deyneko, Boris S. S. Redkin, Dmitry A. A. Spassky, Vitali Nagirnyi, Alexei A. A. Belik, Joke Hadermann, Erzhena T. T. Pavlova, Bogdan I. I. Lazoryak
Summary: The influence of preparation techniques on the structure and luminescent properties of K5Eu(MoO4)(4) (KEMO) was studied. The different synthesis techniques resulted in variations in the crystal structure of KEMO, with the CZ technique producing a (3 + 1)D incommensurately modulated structure. The crystal grown by the CZ technique also exhibited the highest luminescent intensity and a high quantum yield of 66.5%.
Article
Chemistry, Physical
Nadezhda V. Vladimirova, Alexander S. Frolov, Jaime Sanchez-Barriga, Oliver J. Clark, Fumihiko Matsui, Dmitry Yu Usachov, Matthias Muntwiler, Carolien Callaert, Joke Hadermann, Vera S. Neudachina, Marina E. Tamm, Lada Yashina
Summary: Occupancy of different structural positions in a crystal lattice plays a key role in material properties. X-ray Photoelectron Diffraction (XPD) is a surface science structural method that can be used for occupancy analysis. By studying Sb2(Te1-xSex)3 mixed crystals, we found that XPD data showed excellent agreement with the reference method. We also discovered significant differences in anion occupancy between the surface and bulk.
SURFACES AND INTERFACES
(2023)
Article
Materials Science, Ceramics
Haytem Bazzaoui, Cecile Genevois, Emmanuel Veron, Michael J. Pitcher, Mathieu Allix, Alessio Zandona
Summary: Quartz glass-ceramics with transition metal cations (Fe2+, Ni2+, Co2+) and no lithium, magnesium, or zinc exhibit tunable coefficients of thermal expansion. Co2+ has the lowest coefficient of thermal expansion, nearing zero. The unit cell volume is the key structural parameter leading to low or negative coefficients of thermal expansion.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2023)
Article
Materials Science, Ceramics
Jan Baborak, Maureen Yembele, Petr Varak, Sandra Ory, Emmanuel Veron, Michael J. J. Pitcher, Mathieu Allix, Pavla Nekvindova, Alessio Zandona
Summary: Binary alkali silicate glasses were synthesized as beads using aerodynamic levitation coupled to laser heating. Lithium disilicate beads could be obtained without bubbles, but sodium and potassium silicates were more challenging due to alkali evaporation. The risk of volatilization was evaluated based on the ratios of melting temperatures and provided a qualitative estimation of the differential evaporation risk. The method can evaluate the suitability of aerodynamic levitation synthesis for a specific glass composition.
INTERNATIONAL JOURNAL OF APPLIED GLASS SCIENCE
(2023)
Article
Chemistry, Physical
Andreas Paulus, Mylene Hendrickx, Selma Mayda, Maria Batuk, Gunter Reekmans, Miriam von Holst, Ken Elen, Artem M. M. Abakumov, Peter Adriaensens, Dirk Lamoen, Bart Partoens, Joke Hadermann, Marlies K. K. Van Bael, An Hardy
Summary: Layered Li-rich oxides are promising positive electrodes for Li-ion batteries due to their high specific discharge capacities. However, the anionic redox chemistry in these materials leads to irreversible structural transformations and voltage fade during cycling. In this study, Ti4+-substituted Li2MnO3 was synthesized and its structural stability and electrochemical performance were investigated. The results showed that increasing Ti content to x = 0.2 preserved the layered honeycomb-ordered structure and improved the reversibility of the anionic redox. Molecular dynamics simulations revealed the role of Ti substitution in lowering the activation energy barrier and promoting oxygen redox activity. Optimal electrochemical performance was achieved by carefully optimizing the Ti substitution degree.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Materials Science, Ceramics
Jan Baborak, Petr Varak, Aurelien Canizares, Miroslav Rada, Cecile Genevois, Michael J. Pitcher, Emmanuel Veron, Alessio Zandona, Mathieu Allix, Pavla Nekvindova
Summary: A systematic experimental study was conducted on the Y2O3-Al2O3-SiO2 (YAS) compositional system, focusing on nanoparticle formation in the high SiO2 region. The study compared the unique abilities of aerodynamic levitation coupled with laser heating to conventional melt-quenching. The results showed that in a specific region of the phase diagram, phase separation led to the formation of amorphous SiO2 nanoparticles, and the size and distribution of the nanoparticles could be controlled by both the chosen technology and the starting composition.
CERAMICS INTERNATIONAL
(2023)
Article
Chemistry, Inorganic & Nuclear
Jacinthe Gamon, Jean-Marc Bassat, Antoine Villesuzanne, Mathieu Duttine, Maria Batuk, Daphne Vandemeulebroucke, Joke Hadermann, Fouad Alassani, Francois Weill, Etienne Durand, Alain Demourgues
Summary: Sr2FeO3+x F1-x (x = 0.08, 0.2), an n = 1 Ruddlesden-Popperphase, was synthesized through the oxidation of Sr2FeO3F, and the structural investigation reveals the presence of defect and impurity during the oxidation process. This study provides a basis for further research on the ionic and electronic transport properties of Sr2FeO3.2F0.8 and its application in devices such as solid oxide fuel cells.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Euan M. Duncan, Amandine Ridouard, Franck Fayon, Emmanuel Veron, Cecile Genevois, Mathieu Allix, Christopher M. Collins, Michael J. Pitcher
Summary: Glass-crystallisation synthesis coupled with structure prediction is used to discover a new metastable oxide, Sr2Si3O8, in the SrO-Al2O3-SiO2 phase field. This methodology can be applied to a wide range of oxide chemistries by selecting an appropriate non-equilibrium synthesis route.
CHEMICAL COMMUNICATIONS
(2023)