Use of Trifluoromethyl Groups for Catalytic Benzylation and Alkylation with Subsequent Hydrodefluorination

Late-Stage Fluorination: Fancy Novelty or Useful Tool?

(2015) Constanze N. Neumann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluoropolymers: Origin, Production, and Industrial and Commercial Applications

(2015) James Gardiner   AUSTRALIAN JOURNAL OF CHEMISTRY

C–F bond substitution via aziridinium ion intermediates

(2015) A. M. Träff et al.   CHEMICAL COMMUNICATIONS

Atmospheric Degradation of Ozone Depleting Substances, Their Substitutes, and Related Species

(2015) James B. Burkholder et al.   CHEMICAL REVIEWS

Transition metal complex assisted Csp3–F bond formation

(2015) Xiaoxi Lin et al.   DALTON TRANSACTIONS

Review of recent advances in CF bond activation of aliphatic fluorides

(2015) Qian Shen et al.   JOURNAL OF FLUORINE CHEMISTRY

Ni-Catalyzed Borylation of Aryl Fluorides via C–F Cleavage

(2015) Xiang-Wei Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Consecutive C–F bond activation and C–F bond formation of heteroaromatics at rhodium: the peculiar role of FSi(OEt)3

(2015) A. L. Raza et al.   Chemical Science

Intramolecular C–H insertion vs. Friedel–Crafts coupling induced by silyl cation-promoted C–F activation

(2015) Oliver Allemann et al.   Organic Chemistry Frontiers

Friedel-Crafts Reaction of Benzyl Fluorides: Selective Activation of CF Bonds as Enabled by Hydrogen Bonding

(2014) Pier Alexandre Champagne et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective CF Bond Activation of Hexafluoropropylene on Palladium(0): Formation of a Cationic η2-Perfluoroallylpalladium Complex

(2014) Masato Ohashi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Modern Carbon–Fluorine Bond Forming Reactions for Aryl Fluoride Synthesis

(2014) Michael G. Campbell et al.   CHEMICAL REVIEWS

Advances in Catalytic Enantioselective Fluorination, Mono-, Di-, and Trifluoromethylation, and Trifluoromethylthiolation Reactions

(2014) Xiaoyu Yang et al.   CHEMICAL REVIEWS

Fate and effects of poly- and perfluoroalkyl substances in the aquatic environment: A review

(2014) Lutz Ahrens et al.   ENVIRONMENTAL TOXICOLOGY AND CHEMISTRY

C–F activation and functionalization of perfluoro- and polyfluoroarenes

(2014) Jimmie Weaver et al.   TETRAHEDRON

Catalytic Hydrodefluorination of Fluoromethanes at Room Temperature by Silylium-ion-like Surface Species

(2013) Mike Ahrens et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Fluorinated Building Blocks by Transition-Metal-Mediated Hydrodefluorination Reactions

(2013) Moritz F. Kuehnel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluorine in Pharmaceutical Industry: Fluorine-Containing Drugs Introduced to the Market in the Last Decade (2001–2011)

(2013) Jiang Wang et al.   CHEMICAL REVIEWS

C(sp3)–F Bond Activation of CF3-Substituted Anilines with Catalytically Generated Silicon Cations: Spectroscopic Evidence for a Hydride-Bridged Ru–S Dimer in the Catalytic Cycle

(2013) Timo Stahl et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrophilic Difluoro(phenylthio)methylation: Generation, Stability, and Reactivity of α-Fluorocarbocations

(2013) Nolan M. Betterley et al.   ORGANIC LETTERS

Lewis Acidity of Organofluorophosphonium Salts: Hydrodefluorination by a Saturated Acceptor

(2013) C. B. Caputo et al.   SCIENCE

Main-Group Lewis Acids for C–F Bond Activation

(2013) Timo Stahl et al.   ACS Catalysis

The Lewis acidity of fluorophosphonium salts: access to mixed valent phosphorus(iii)/(v) species

(2012) Lindsay J. Hounjet et al.   DALTON TRANSACTIONS

Protolytic defluorination of trifluoromethyl-substituted arenes

(2011) Anila Kethe et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Activation of Alkyl C–F Bonds by B(C6F5)3: Stoichiometric and Catalytic Transformations

(2011) Christopher B. Caputo et al.   ORGANOMETALLICS

Proton-Catalyzed, Silane-Fueled Friedel-Crafts Coupling of Fluoroarenes

(2011) O. Allemann et al.   SCIENCE

Hydrodefluorination and Other Hydrodehalogenation of Aliphatic Carbon−Halogen Bonds Using Silylium Catalysis

(2010) Christos Douvris et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Organometallic Fluorine Chemistry of Palladium and Rhodium: Studies toward Aromatic Fluorination

(2009) Vladimir V. Grushin   ACCOUNTS OF CHEMICAL RESEARCH

Non-catalytic conversion of C–F bonds of benzotrifluorides to C–C bonds using organoaluminium reagents

(2009) Jun Terao et al.   CHEMICAL COMMUNICATIONS

C−F Bond Activation in Organic Synthesis

(2009) Hideki Amii et al.   CHEMICAL REVIEWS

Brønsted Acid Mediated (sp3)Carbon-Fluorine Bond Activation: Inter- and Intramolecular Arylation of Trifluoromethylated Arenes

(2009) Fei WANG et al.   CHINESE JOURNAL OF CHEMISTRY

Carbon−Carbon Coupling of C(sp3)−F Bonds Using Alumenium Catalysis

(2009) Weixing Gu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrodefluorination of Perfluoroalkyl Groups Using Silylium-Carborane Catalysts

(2008) C. Douvris et al.   SCIENCE