期刊
CHEMISTRY LETTERS
卷 43, 期 12, 页码 1937-1939出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.140810
关键词
-
资金
- JST, ACT-C
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- Grants-in-Aid for Scientific Research [23350017] Funding Source: KAKEN
The cycloisomerization of 1,6-enynes catalyzed by rhodium(III) porphyrin under mild reaction conditions successfully afforded a five-membered ring system. The rhodium porphyrin was found to be a strong it-Lewis acid that could activate alkynes. Thus, rhodium porphyrin-catalyzed intramolecular Friedel-Crafts-type reactions of alkynes with arenes were also accomplished. Furthermore, rhodium porphyrin-catalyzed intermolecular cyclization of alkynes with styrenes afforded the indene derivatives.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据