4.3 Article

Synthesis of Sodium-vanadate-doped Ordered Mesoporous Carbon Foams as Capacitor Electrode Materials

期刊

CHEMISTRY LETTERS
卷 40, 期 3, 页码 236-238

出版社

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2011.236

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资金

  1. National Natural Science Foundation of China [20973127, 20776045, 20736002]
  2. Shanghai Nanotechnology Promotion Center [0952 nm00800]
  3. National High Technology Research and Development Program of China [2008AA062302]
  4. China Postdoctoral Science Foundation [20090460647, 2010030258]
  5. Shanghai Postdoctoral Scientific Program [10R21412100]

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Sodium-vanadate-doped ordered mesoporous carbon foams (V-MCFs) were prepared through an evaporation-induced self assembly strategy. The resultant V-MCFs exhibit highly ordered mesostructure with specific surface areas of 714 m(2) g(-I) and uniform pore sizes of 4.1 nm. The surface wettability and graphitization degree of V-MCFs were increased due to the incorporation of sodium vanadate into the carbon matrix. Besides, sodium vanadate brings a pseudo-capacitive effect in V-MCFs. V-MCFs thus exhibit higher capacitance and fast charge-discharge properties compared with pure mesoporous carbon foams.

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