sp2 C–H bond activation in water and catalytic cross-coupling reactions

Autocatalytic Intermolecular versus Intramolecular Deprotonation in CH Bond Activation of Functionalized Arenes by Ruthenium(II) or Palladium(II) Complexes

(2013) Indira Fabre et al.   CHEMISTRY-A EUROPEAN JOURNAL

Overcoming the “Oxidant Problem”: Strategies to Use O2 as the Oxidant in Organometallic C–H Oxidation Reactions Catalyzed by Pd (and Cu)

(2012) Alison N. Campbell et al.   ACCOUNTS OF CHEMICAL RESEARCH

Controlling Site Selectivity in Palladium-Catalyzed C–H Bond Functionalization

(2012) Sharon R. Neufeldt et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cobalt-Catalyzed Direct Arylation and Benzylation by CH/CO Cleavage with Sulfamates, Carbamates, and Phosphates

(2012) Weifeng Song et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-Catalyzed Oxidant-Free Dehydrogenative CH Bond Functionalization: Selective Preparation of N-Arylpiperidines through Tandem Hydrogen Transfers

(2012) Kedong Yuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beyond Directing Groups: Transition-Metal-Catalyzed CH Activation of Simple Arenes

(2012) Nadine Kuhl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium- and rhodium-catalyzed cross-coupling reaction of acrylamides with alkenes: efficient access to (Z,E)-dienamides

(2012) Jian Zhang et al.   CHEMICAL COMMUNICATIONS

Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization

(2012) Percia Beatrice Arockiam et al.   CHEMICAL REVIEWS

From C(sp2)–H to C(sp3)–H: systematic studies on transition metal-catalyzed oxidative C–C formation

(2012) Bi-Jie Li et al.   CHEMICAL SOCIETY REVIEWS

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

(2012) Guoyong Song et al.   CHEMICAL SOCIETY REVIEWS

Cyclometallation of arylimines and nitrogen-containing heterocycles via room-temperature C–H bond activation with arene ruthenium(ii) acetate complexes

(2012) Bin Li et al.   DALTON TRANSACTIONS

Ruthenium(ii) catalysed synthesis of unsaturated oxazolines via arene C–H bond alkenylation

(2012) Bin Li et al.   GREEN CHEMISTRY

Ruthenium(ii)-catalyzed selective monoarylation in water and sequential functionalisations of C–H bonds

(2012) Percia B. Arockiam et al.   GREEN CHEMISTRY

Excited State Intramolecular Proton Transfer (ESIPT) from Phenol to Carbon in Selected Phenylnaphthols and Naphthylphenols

(2012) Nikola Basarić et al.   JOURNAL OF ORGANIC CHEMISTRY

Pd-Catalyzed Direct Arylation of Polyfluoroarenes on Water under Mild Conditions Using PPh3 Ligand

(2012) Fei Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Functionalization of Methyl Group on Silicon: Iridium-Catalyzed C(sp3)–H Borylation of Methylchlorosilanes

(2012) Toshimichi Ohmura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Borylation of Secondary C–H Bonds in Cyclic Ethers

(2012) Carl W. Liskey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed, Substrate-Directed C–H Borylation Reactions of Benzylic Amines

(2012) Andrew J. Roering et al.   ORGANIC LETTERS

Ruthenium-Catalyzed C–H Bond Arylations of Arenes Bearing Removable Directing Groups via Six-Membered Ruthenacycles

(2012) Lutz Ackermann et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Oxidative C–H Alkenylations of Anilides and Benzamides in Water

(2012) Lutz Ackermann et al.   ORGANIC LETTERS

Well-Defined Ruthenium(II) Carboxylate as Catalyst for Direct C–H/C–O Bond Arylations with Phenols in Water

(2012) Lutz Ackermann et al.   ORGANIC LETTERS

Cationic Ruthenium(II) Catalysts for Oxidative C–H/N–H Bond Functionalizations of Anilines with Removable Directing Group: Synthesis of Indoles in Water

(2012) Lutz Ackermann et al.   ORGANIC LETTERS

Catalytic C–H bond arylation of aryl imines and oxazolines in water with ruthenium(II)-acetate catalyst

(2012) Bin Li et al.   TETRAHEDRON

Ruthenium-catalyzed direct arylation of C–H bonds in aromatic amides containing a bidentate directing group: significant electronic effects on arylation

(2012) Yoshinori Aihara et al.   Chemical Science

Ruthenium-catalyzed direct oxidative alkenylation of arenes through twofold C–H bond functionalization

(2012) Sergei I. Kozhushkov et al.   Chemical Science

Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization Reactions

(2011) Denise A. Colby et al.   ACCOUNTS OF CHEMICAL RESEARCH

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cobalt-Phenanthroline Catalysts for the ortho Alkylation of Aromatic Imines under Mild Reaction Conditions

(2011) Ke Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Activation of a C sp 3H Bond Adjacent to a Nitrogen Atom: A Versatile Approach to Optically Active α-Alkyl α-Amino Acids and C1-Alkylated Tetrahydroisoquinoline Derivatives

(2011) Gen Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-Catalyzed Oxidative Annulation by Cleavage of CH/NH Bonds

(2011) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dehydrogenation and Related Reactions Catalyzed by Iridium Pincer Complexes

(2011) Jongwook Choi et al.   CHEMICAL REVIEWS

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Towards mild metal-catalyzed C–H bond activation

(2011) Joanna Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Ruthenium-catalyzed Oxidative Alkenylation of Arenes via Regioselective C–H Bond Cleavage Directed by a Nitrogen-containing Group

(2011) Yuto Hashimoto et al.   CHEMISTRY LETTERS

The Scope of Ambiphilic Acetate-Assisted Cyclometallation with Half-Sandwich Complexes of Iridium, Rhodium and Ruthenium

(2011) Youcef Boutadla et al.   CHEMISTRY-A EUROPEAN JOURNAL

RhIII-Catalyzed Oxidative Olefination of Vinylic CH Bonds: Efficient and Selective Access to Di-unsaturated α-Amino Acid Derivatives and Other Linear 1,3-Butadienes

(2011) Tatiana Besset et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ruthenium-Catalyzed Isoquinolone Synthesis through CH Activation Using an Oxidizing Directing Group

(2011) Bin Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Greener solvents for ruthenium and palladium-catalysed aromatic C–H bond functionalisation

(2011) Cedric Fischmeister et al.   GREEN CHEMISTRY

TPGS-750-M: A Second-Generation Amphiphile for Metal-Catalyzed Cross-Couplings in Water at Room Temperature

(2011) Bruce H. Lipshutz et al.   JOURNAL OF ORGANIC CHEMISTRY

Cobalt-Catalyzed, Room-Temperature Addition of Aromatic Imines to Alkynes via Directed C–H Bond Activation

(2011) Pin-Sheng Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dehydrogenative [4 + 2] Cycloaddition of Formamides with Alkynes through Double C−H Activation

(2011) Yoshiaki Nakao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Autocatalysis for C–H Bond Activation by Ruthenium(II) Complexes in Catalytic Arylation of Functional Arenes

(2011) Emmanuel Ferrer Flegeau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Chelation-Assisted Transformations Involving Ortho C–H Bond Activation: Regioselective Oxidative Cycloaddition of Aromatic Amides to Alkynes

(2011) Hirotaka Shiota et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Oxidative C–H Bond Alkenylations in Water: Expedient Synthesis of Annulated Lactones

(2011) Lutz Ackermann et al.   ORGANIC LETTERS

Ruthenium-CatalyzedOrtho-Alkenylation of Aromatic Ketones with Alkenes by C–H Bond Activation

(2011) Kishor Padala et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Oxidative Vinylation of Heteroarene Carboxylic Acids with Alkenes via Regioselective C−H Bond Cleavage

(2011) Takumi Ueyama et al.   ORGANIC LETTERS

Ruthenium-Catalyzed C–H/N–O Bond Functionalization: Green Isoquinolone Syntheses in Water

(2011) Lutz Ackermann et al.   ORGANIC LETTERS

H/D Exchange Processes Catalyzed by an Iridium-Pincer Complex

(2011) Vlad M. Iluc et al.   ORGANOMETALLICS

Ruthenium Complexes of κ(P)- and κ(P)-η6-Coordinated KITPHOS Monophosphines: Efficient Catalysts for the Direct Ortho Arylation of 2-Phenylpyridine andN-Phenylpyrazole with Aryl Chlorides

(2011) Simon Doherty et al.   ORGANOMETALLICS

Alkynes as an eco-compatible “on-call” functionality orthogonal to biological conditions in water

(2011) Nick Uhlig et al.   Chemical Science

Synthesis and characterization of a cyclic vinylpalladium(ii) complex: vinylpalladium species as the possible intermediate in the catalytic direct olefination reaction of enamide

(2011) Yun-He Xu et al.   Chemical Science

Sequential Catalysis for the Production of Sterically Hindered Amines: Ru(II)-Catalyzed C–H Bond Activation and Hydrosilylation of Imines

(2011) Bin Li et al.   ACS Catalysis

The Development of Catalytic Nucleophilic Additions of Terminal Alkynes in Water†

(2010) Chao-Jun Li   ACCOUNTS OF CHEMICAL RESEARCH

Hydrogen/Deuterium Exchange Reactions of Olefins with Deuterium Oxide Mediated by the Carbonylchlorohydrido- tris(triphenylphosphine)ruthenium(II) Complex

(2010) Sunny Kai San Tse et al.   ADVANCED SYNTHESIS & CATALYSIS

“On Water” Direct and Site-Selective Pd-Catalysed CH Arylation of (NH)-Indoles

(2010) Lionel Joucla et al.   ADVANCED SYNTHESIS & CATALYSIS

CH Bond Functionalization in Water Catalyzed by Carboxylato Ruthenium(II) Systems

(2010) Percia B. Arockiam et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Cross-Coupling of Internal Alkenes with Terminal Alkenes to Functionalized 1,3-Butadienes Using CH Bond Activation: Efficient Synthesis of Bicyclic Pyridones

(2010) Haifeng Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-catalyzed direct alkylations of (hetero)arenes via C–H bond cleavages with unactivated alkyl halides

(2010) Lutz Ackermann   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Water: Nature’s Reaction Enforcer—Comparative Effects for Organic Synthesis “In-Water” and “On-Water”

(2010) Richard N. Butler et al.   CHEMICAL REVIEWS

Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

(2010) Tetsuya Satoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Alkyne insertion into cyclometallated pyrazole and imine complexes of iridium, rhodium and ruthenium; relevance to catalytic formation of carbo- and heterocycles

(2010) Youcef Boutadla et al.   DALTON TRANSACTIONS

Ruthenium(iv)catalysts for the selective estragole to trans-anetholeisomerization in environmentally friendly media

(2010) Beatriz Lastra-Barreira et al.   GREEN CHEMISTRY

Cationic Pd(II)-Catalyzed Fujiwara−Moritani Reactions at Room Temperature in Water

(2010) Takashi Nishikata et al.   ORGANIC LETTERS

Room-Temperature Direct Arylation of Polyfluorinated Arenes under Biphasic Conditions

(2010) Olivier René et al.   ORGANIC LETTERS

A Highly Efficient Ruthenium(II) Catalyst with (1,2-Diarylvinyl)phosphine Ligands for Direct OrthoArylation of 2-Arylpyridine with Aryl Chlorides

(2010) Bingran Yu et al.   ORGANOMETALLICS

Intermolecular Dehydrative Coupling Reaction of Aryl Ketones with Cyclic Alkenes Catalyzed by a Well-Defined Cationic Ruthenium−Hydride Complex: A Novel Ketone Olefination Method via Vinyl C−H Bond Activation

(2010) Chae S. Yi et al.   ORGANOMETALLICS

Chain-Selective and Regioselective Ethylene and Styrene Dimerization Reactions Catalyzed by a Well-Defined Cationic Ruthenium Hydride Complex: New Insights on the Styrene Dimerization Mechanism

(2010) Do W. Lee et al.   ORGANOMETALLICS

Reactions of Cyclometalated Oxazoline Half-Sandwich Complexes of Iridium and Ruthenium with Alkynes and CO

(2010) David L. Davies et al.   ORGANOMETALLICS

Palladium-catalyzed direct cross-coupling reaction between indenes and electron-deficient alkenes

(2010) Yun-He Xu et al.   TETRAHEDRON LETTERS

Ruthenium(II) Acetate Catalyst for Direct Functionalisation of sp2-CH Bonds with Aryl Chlorides and Access to Tris- Heterocyclic Molecules

(2009) Franc Požgan et al.   ADVANCED SYNTHESIS & CATALYSIS

Room Temperature CH Activation and Cross-Coupling of Aryl Ureas in Water

(2009) Takashi Nishikata et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed Chemoselective ortho Arylation of Aryl Imines by Directed CH Bond Activation

(2009) Naohiko Yoshikai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organic Synthesis “On Water”

(2009) Arani Chanda et al.   CHEMICAL REVIEWS

C−F Bond Activation in Organic Synthesis

(2009) Hideki Amii et al.   CHEMICAL REVIEWS

Hydrophilic Ligands and Their Application in Aqueous-Phase Metal-Catalyzed Reactions

(2009) Kevin H. Shaughnessy   CHEMICAL REVIEWS

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

(2009) Denise A. Colby et al.   CHEMICAL REVIEWS

Hydrogen-Deuterium Exchange Reactions of Aromatic Compounds and Heterocycles by NaBD4-Activated Rhodium, Platinum and Palladium Catalysts

(2009) Volker Derdau et al.   CHEMISTRY-A EUROPEAN JOURNAL

Diethyl carbonate as a solvent for ruthenium catalysed C–H bond functionalisation

(2009) Percia Arockiam et al.   GREEN CHEMISTRY

Mild and Selective Deuteration and Isomerization of Alkenes by a Bifunctional Catalyst and Deuterium Oxide

(2009) Gülin Erdogan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Cross-Coupling Reaction of Simple Alkenes with Acrylates Catalyzed by Palladium Catalyst

(2009) Yun-He Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

AllylicEthersas Educts for Suzuki−Miyaura Couplings in Water at Room Temperature

(2009) Takashi Nishikata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Zn-Mediated, Pd-Catalyzed Cross-Couplings in Water at Room TemperatureWithoutPrior Formation of Organozinc Reagents

(2009) Arkady Krasovskiy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Amino- and Alkoxycarbonylations with Carbamoyl Chlorides and Alkyl Chloroformates via Aromatic C−H Bond Cleavage

(2009) Takuya Kochi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Arylations of 2H-Indazoles On Water

(2009) Stephan A. Ohnmacht et al.   ORGANIC LETTERS

Regioselective Intermolecular Coupling Reaction of Arylketones and Alkenes Involving C−H Bond Activation Catalyzed by anin SituFormed Cationic Ruthenium Hydride Complex

(2009) Chae S. Yi et al.   ORGANOMETALLICS

Cross-Dehydrogenative Coupling (CDC): Exploring C−C Bond Formations beyond Functional Group Transformations

(2008) Chao-Jun Li   ACCOUNTS OF CHEMICAL RESEARCH

Direct arylations on water: synthesis of 2,5-disubstituted oxazoles balsoxin and texaline

(2008) Stephan A. Ohnmacht et al.   CHEMICAL COMMUNICATIONS

Direct Arylation of Arene C−H Bonds by Cooperative Action of NHCarbene−Ruthenium(II) Catalyst and Carbonate via Proton Abstraction Mechanism

(2008) Ismail Özdemir et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Arylation of Oxazoles at C2. A Concise Approach to Consecutively Linked Oxazoles

(2008) Emmanuel Ferrer Flegeau et al.   ORGANIC LETTERS

C−H Bond Activation by Rhodium(I) Phenoxide and Acetate Complexes: Mechanism of H−D Exchange between Arenes and Water

(2008) Susan Kloek Hanson et al.   ORGANOMETALLICS

Transition-Metal-Catalyzed Carbon-Carbon Bond Formation via Carbon-Hydrogen Bond Cleavage

(2008) Fumitoshi Kakiuchi et al.   SYNTHESIS-STUTTGART

[RuCl3(H2O)n]-catalyzed direct arylations

(2008) Lutz Ackermann et al.   TETRAHEDRON