期刊
CHEMICAL RECORD
卷 10, 期 5, 页码 348-358出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.201000029
关键词
Transition metal catalyst; Boron; C-C Bond formation; B-C bond formation; Alkyne
Transition-metal-catalyzed carboborations, in which organic and boryl groups are introduced concomitantly to unsaturated organic molecules, have been developed. Direct carboborations, which proceed via activation of B-C bonds of cyanoboranes and alkynylboranes, and transmetalative carboborations, in which activation of B-Cl bonds is followed by transmetalation from organotin and organozirconium reagents, are overviewed. In addition, as representative results and mechanistic considerations, the scientific background and a personal view behind the study are also described. (C) 2010 The Japan Chemical Journal Forum and Wiley Periodicals, Inc. Chem Rec 10: 348-358; 2010: Published online in Wiley InterScience (www.interscience.wiley.com) DOI 10.1002/tcr.201000029
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