Article
Engineering, Chemical
Qi Ding, Zhaoqiang Zhang, Cong Yu, Peixin Zhang, Jun Wang, Liyun Kong, Xili Cui, Chao-Hong He, Shuguang Deng, Huabin Xing
Summary: The efficient separation of propylene and propane in a phosphate anion-functionalized metal-organic framework was achieved by a synergetic effect of equilibrium and kinetics, offering excellent thermodynamic and kinetic selectivity for C3H6/C3H8 separation. This breakthrough method demonstrates outstanding separation capability and easy regeneration, marking the first observation of equilibrium and kinetics cooperative C3H6/C3H8 adsorption separation in anion-functionalized MOFs.
Article
Chemistry, Physical
Syed Shoaib Ahmad Shah, Tayyaba Najam, Ming Wen, Shuang-Quan Zang, Amir Waseem, Hai-Long Jiang
Summary: Metal-organic frameworks (MOFs) are a promising class of electrocatalysts for CO2 reduction, characterized by high porosity and large surface area. By enhancing performance, exploring the structure-activity relationship, and employing specific structure tuning strategies, novel catalysts can be designed effectively.
Article
Engineering, Chemical
Yong-Zhi Li, Rajamani Krishna, Fan Xu, Wan-Fang Zhang, Yanwei Sui, Lei Hou, Yao-Yu Wang, Zhonghua Zhu
Summary: In this study, a novel microporous Cd-MOF material was constructed with a high C2H2 adsorption capacity, which can efficiently separate C2H2 from gas mixtures. The experimental results and molecular simulation demonstrated the importance of this material in acetylene separation.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Article
Nanoscience & Nanotechnology
Yann Magnin, Estelle Dirand, Guillaume Maurin, Philip L. Llewellyn
Summary: Carbon mitigation is a challenging issue and the selection of the optimum sorbent for CO2 adsorption remains challenging. Metal-organic frameworks (MOFs) have attracted considerable attention, and in this study, CALF-20(Zn) MOF is investigated for its CO2 adsorption and diffusion behavior. The results show unconventional guest-host behaviors in CALF-20 and the presence of water impacts the diffusion coefficient of CO2.
ACS APPLIED NANO MATERIALS
(2023)
Article
Chemistry, Physical
Lan Yang, Qiang Gao, Yan-Mei Zhang, Ruihan Wang, Li-Zhuang Chen
Summary: A microporous heterometal-organic framework, CuIn(ina)4, has been demonstrated to selectively enrich C2H6 over C2H4, showing high separation performance and potential as an ethylene purification material.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Editorial Material
Chemistry, Multidisciplinary
Simon Krause
Summary: This article introduces a method for water isotopes separation using responsive dynamic pore windows in microporous coordination polymers, achieving unprecedented selectivity based on an elegant mechanism.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Physical
Marvin Benzaqui, Mohammad Wahiduzzaman, Heng Zhao, Md Rafiul Hasan, Timothy Steenhaut, Ali Saad, Jerome Marrot, Perine Normand, Jean-Marc Greneche, Nicolas Heymans, Guy de Weireld, Antoine Tissot, William Shepard, Yaroslav Filinchuk, Sophie Hermans, Florent Carn, Magdalena Manlankowska, Carlos Tellez, Joaquin Coronas, Guillaume Maurin, Nathalie Steunou, Christian Serre
Summary: Iron(iii) carboxylate based metal organic frameworks (MOFs)/porous coordination polymers (PCPs) have attracted great interest due to their structural diversity, tunable porosity, stability, functionality, scalability, and green synthesis. This study presents a new Fe(iii) based PCP with one dimensional narrow pore channels decorated with polar groups, which shows moderate CO2 capacity and high CO2/N-2 selectivity. The compatibility of this MOF with elastomer block copolymer allows the production of mixed matrix membranes with improved CO2/N-2 separation performance.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Article
Chemistry, Inorganic & Nuclear
Chaohui He, Peng Zhang, Sai Ma, Yujuan Zhang, Tuoping Hu
Summary: Developing ultra-stable adsorbents with high CO2 adsorption performance is an effective solution for the separation of CO2/CH4 and CO2/N-2.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Multidisciplinary
Min-Bum Kim, Alexander J. Robinson, Maria L. Sushko, Praveen K. Thallapally
Summary: Obtaining pure Xe from various sources is important for the environment and industry. The aluminum-based MOF (Al-SDB) showed high Xe capacity and selectivity for Xe/Kr separation. It also demonstrated potential for PSA process. The breakthrough experiment further confirmed its efficiency in separating Xe/Kr mixtures under flow conditions.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Lingyao Wang, Wanqi Sun, Simon Duttwyler, Yuanbin Zhang
Summary: BSF-3, a functionalized metal organic framework, shows efficient gas adsorption and separation capabilities, particularly for C3H8, C2H2, and CO2. Experimental results confirm that BSF-3 maintains its gas adsorption capacity without loss after repeated cycles, making it suitable for purifying methane from natural gas and pyrolysis gas.
JOURNAL OF SOLID STATE CHEMISTRY
(2021)
Article
Chemistry, Inorganic & Nuclear
Wen-Qian Zhang
Summary: By synthesizing a 3D rigid Ni(II) microporous metal-organic framework, a high capacity and selectivity for CO2 over CH4 has been achieved.
Article
Engineering, Chemical
Qiang Zhang, Lei Zhou, Puxu Liu, Libo Li, Shan-Qing Yang, Zhuo-Fei Li, Tong-Liang Hu
Summary: A new microporous metalorganic framework (NUM-15) with elaborate nanotraps was reported for efficient acetylene (C2H2) capture and separation, showing promising potential for industrial gas separation.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Nanoscience & Nanotechnology
Zhenzi Yu, Dylan M. Anstine, Salah Eddine Boulfelfel, Chenkai Gu, Coray M. Colina, David S. Sholl
Summary: The study investigates various simulation methods for predicting molecule adsorption in metal-organic frameworks (MOFs), finding that adsorption-relaxation simulations are necessary for quantitative predictions in many MOFs, although standard calculations based on rigid structures can also provide useful information.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Multidisciplinary
Danhua Song, Feilong Jiang, Daqiang Yuan, Qihui Chen, Maochun Hong
Summary: A novel metal-organic framework (FJI-H38) with adaptive ultramicropores and multiple active sites has been developed for efficient CO2 separation from air. It has a high adsorption capacity and selectivity for CO2, even in high humidity conditions. The material also exhibits excellent stability, recyclability, and can be synthesized in large quantities, making it a practical adsorbent for trace CO2 capture from the air.
Article
Chemistry, Multidisciplinary
Jinduo Tian, Qihui Chen, Feilong Jiang, Daqiang Yuan, Maochun Hong
Summary: A novel metal-organic framework (MOF) (FJI-H36) with adaptive channels has been developed for the effective capture and dense storage of acetylene (C2H2). The excellent adsorption performance of FJI-H36, including a record-high storage density and low adsorption enthalpy, is attributed to the synergism of active sites, flexible framework, and matched pores. FJI-H36 also exhibits excellent chemical stability and recyclability, making it a practical adsorbent for C2H2 storage.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Engineering, Chemical
Seyed Mojtaba Mirfendereski, Jerry Y. S. Lin
Summary: A hydrophobic MFI zeolite membrane with high ethanol/water separation performance was successfully synthesized through a new method involving dual-layer seeding and varying-temperature secondary growth. The optimized membrane structure consists of a thin, fully inter-grown, and dense top zeolite layer for high selectivity, and a porous low inter-grown bottom zeolite layer to minimize resistance and aluminum transfer. The best supported MFI zeolite membrane exhibits a separation factor of 160 for ethanol/water pervaporation with a total flux of 3 kg m(-2) h(-1).
JOURNAL OF MEMBRANE SCIENCE
(2021)
Editorial Material
Engineering, Chemical
Jerry Y. S. Lin, Rong Wang
JOURNAL OF MEMBRANE SCIENCE
(2021)
Article
Engineering, Chemical
Lie Meng, Oscar Ovalle-Encinia, Jerry Y. S. Lin
Summary: The catalyst-free CCDP membrane reactor offers significantly enhanced WGS performance at high reaction pressures compared to a fixed-bed reactor. At 30 atm and 900 degrees C, WGS conducted in the single-stage, catalyst-free CCDP membrane reactor features a CO conversion >95%, a pure (100%) CO2 flow at the permeate side with ultrahigh CO2 capture ratio (>98%), and a retentate stream consisting of 100% recovered H-2 at a H-2 purity >90%.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2021)
Article
Engineering, Chemical
Oscar Ovalle-Encinia, Han-Chun Wu, Tianjia Chen, Jerry Y. S. Lin
Summary: Experimental and simulation results demonstrate the feasibility of hydrogen production with simultaneous CO2 removal through steam reforming of methane in a CO2-perm-selective membrane reactor. The mathematical model accurately describes the process, showing that adjusting permeation number, Damkohler number, reaction pressure, and sweep side conditions can enhance H2 yield and CO2 recovery.
JOURNAL OF MEMBRANE SCIENCE
(2022)
Article
Energy & Fuels
Fateme Banihashemi, Amr F. M. Ibrahim, Shuguang Deng, Jerry Y. S. Lin
Summary: This study investigates the pyrolysis/gasification process of Galdieria sulphuraria and demonstrates its potential as a low-cost and sustainable energy resource for producing high-quality oil and syngas. The results show that temperature significantly affects the product yield, conversion rate, and gas composition. Catalytic gasification at low temperatures produces hydrogen-enriched syngas and high HHV bio-oil with lower oxygen and nitrogen content.
BIOENERGY RESEARCH
(2023)
Article
Engineering, Chemical
Fateme Banihashemi, Jerry Y. S. Lin
Summary: This study reports the successful synthesis of high-quality and stable ZIF-8 membranes on a sol-gel derived mesoporous gamma-alumina layer coated on top of the alpha-alumina support. The ZIF-8 membranes synthesized on the scalable gamma-alumina coated alpha-alumina support exhibit improved separation performance.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2022)
Article
Engineering, Chemical
Fateme Banihashemi, Jerry Y. S. Lin
Summary: This study investigates the influence of xylene activity on the vapor and liquid permeation/separation performance of b-oriented MFI zeolite membranes. The results showed that the permeance and separation factor increase with temperature, but decrease with increasing xylene activity. B-oriented MFI zeolite membranes exhibit better vapor permeation/separation performance compared to randomly oriented membranes, and show less negative effect of xylene activity on separation factor. However, both types of membranes show poor separation factor when operated in the pervaporation mode.
JOURNAL OF MEMBRANE SCIENCE
(2022)
Article
Engineering, Chemical
Oscar Ovalle-Encinia, Jerry Y. S. Lin
Summary: This study investigates the effects of high transmembrane pressure on CO2 permeation flux and the stability of molten carbonate in ceramic-carbonate dual-phase membranes. The results show a logarithmic relationship between CO2 permeation flux and CO2 pressure ratio, and indicate that CO2 permeation is mainly dominated by carbonate ionic conduction. The membranes exhibit high stability for high-temperature, high-pressure separation and chemical reaction applications.
JOURNAL OF MEMBRANE SCIENCE
(2022)
Article
Electrochemistry
Kishen Rafiz, Dheeraj Ram Lingam Murali, Jerry Y. S. Lin
Summary: This study demonstrates the use of plate-structured gamma-alumina separators with liquid electrolyte to improve the safety and cycling stability of lithium-ion batteries, without compromising battery performance.
ELECTROCHIMICA ACTA
(2022)
Article
Engineering, Environmental
Oscar Ovalle-Encinia, Jerry Y. S. Lin
Summary: Water-gas-shift (WGS) reaction is a crucial step in IGCC power plants with CO2 capture, and using a CO2-permselective ceramic-carbonate dual-phase membrane reactor can enhance hydrogen yield and CO2 capture simultaneously. This study investigates the operation of WGS reaction in a samarium-doped ceria membrane reactor infiltrated with lithium/sodium molten carbonate. The results show that under certain conditions, high CO conversion and CO2 recovery can be achieved, but unwanted carbon deposition is observed in the catalyst-free membrane reactor.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Engineering, Chemical
Tianjia Chen, Yanyang Xu, Yinmin Zhang, Yanbing Gong, Yongfeng Zhang, Jerry Y. S. Lin
Summary: This study reports a new structure of ceramic-carbonate dual-phase hollow fiber membrane with high CO2 permeance and superior mechanical strength for CO2 separation. The unique double-layer structure of the membrane enables a significant improvement in mechanical strength, resulting in a higher CO2 flux.
JOURNAL OF MEMBRANE SCIENCE
(2022)
Article
Materials Science, Multidisciplinary
Oscar Ovalle-Encinia, Jerry Y. S. Lin
Summary: This work evaluates the characteristics of porous ceramic tubes prepared by centrifugal casting (CC) and cold isostatic pressing (CIP) methods. The results show that CIP method produces ceramic tubes with lower porosity and average pore size, suitable for low porosity or dense ceramic tubes, while CC method is suitable for high-porosity ceramic tubes or tubes with pore gradient tube wall.
JOURNAL OF MATERIALS SCIENCE
(2023)
Article
Electrochemistry
Kishen Rafiz, N. R. D. Harika, Jerry Y. S. Lin
Summary: This study reports the use of plate-shaped zeolite particles to form an electrode-coated separator for lithium-metal batteries. These separators show promise in preventing dendrite propagation and have better charge/discharge characteristics compared to traditional separators. The results suggest that the unique physical properties and morphology of the zeolite particles contribute to their effectiveness in homogenizing Li-ion flux and preventing dendrite formation.
ELECTROCHIMICA ACTA
(2023)
Article
Engineering, Chemical
Dheeraj R. L. Murali, Fateme Banihashemi, Jerry Y. S. Lin
Summary: Zeolite membrane separators with tailored pore structure and surface chemistry have been developed for the preparation of fire-safe lithium-ion batteries. Compared to commercial polypropylene (PP) separators, these zeolite separators exhibit better wettability, enabling fabrication of high-performance batteries. The results show that the new fire-safe lithium-ion batteries exhibit excellent charge and discharge characteristics and cycle performance.
JOURNAL OF MEMBRANE SCIENCE
(2023)
Article
Engineering, Chemical
Jerry Y. S. Lin, Oscar Ovalle-Encinia
Summary: This paper presents a theoretical approach for the pressure dependence of gas permeation flux in dual-phase ionic-conducting membranes, using CO2 permeation in samarium-doped-ceria/molten-carbonate membranes as an example. The model shows that gas permeation is controlled by the materials' intrinsic conductivities and the geometric factors of each phase. The topological structure, which is determined by synthesis method and conditions, can lead to different pressure-dependent flux equations.
JOURNAL OF MEMBRANE SCIENCE LETTERS
(2023)
Article
Engineering, Chemical
Qing Han, Mengqing Shi, Linkai Han, Di Liu, Mingwei Tong, Yuxin Xie, Zhonghua Xiang
Summary: Developing highly efficient bifunctional oxygen electrocatalysts is crucial for zinc-air flow batteries. Metal-organic frameworks (MOFs) and covalent organic polymers (COPs) have emerged as promising alternatives due to their designable and controllable atomic-level structures. However, their catalytic performances are limited by conductivity and catalytic activity. In this study, nanosheet FeNi-MOF and iron phthalocyanine rich COP hybrid materials are assembled through the pi-pi stacking effect to create highly efficient bifunctional electrocatalysts. The resulting catalyst exhibits superior catalytic performance and stability, making it a promising candidate for zinc-air flow batteries.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Daria Grigorash, Dmytro Mihrin, Rene Wugt Larsen, Erling H. Stenby, Wei Yan
Summary: The article introduces a new approach to describe the cross-association between molecules, allowing for the simulation of weakly bound molecular complexes with different conformations in mixtures. By incorporating this approach into the equation of state, accurate predictions of vapor-liquid equilibrium and liquid-liquid equilibrium can be made. The new method is validated through experiments on alcohol and acid mixtures, with the results compared to experimental data, demonstrating its accuracy and reliability.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Mohammed Al-Sharabi, Daniel Markl, Vincenzino Vivacqua, Prince Bawuah, Natalie Maclean, Andrew P. E. York, Axel Zeitler
Summary: This study used terahertz pulsed imaging to investigate the transport process of different solvents into ceramic catalytic materials. The results showed that the heating rate of the samples influenced the water transport rate, while the viscosity of 1-octanol slowed down its transport.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Chukwunonso Anyaoku, Sati Bhattacharya, Rajarathinam Parthasarathy
Summary: This study aimed to enhance understanding of settling dynamics in viscoelastic fluids by developing a semi-empirical correlation and a dimensionless ratio, which accurately described the characteristics of settling suspensions.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Antti I. Koponen, Janika Viitala, Atsushi Tanaka, Baranivignesh Prakash, Olli-Ville Laukkanen, Ari Jasberg
Summary: This study focuses on the development of foam application chemicals for the paper and board industry. The research explores the rheology of the polyvinyl alcohol foam used in the process. Measurements were conducted to determine the foam viscosity and slip flow. The results suggest that slip flow contributes significantly to the total flow rate, and the obtained viscosity and slip models provide a solid foundation for industrial processes.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Dalei Sun, Jinghui Cai, Yating Yang, Zhiwu Liang
Summary: In this study, Fe-doped alpha-Bi2O3 catalysts with different Fe/Bi molar ratios were synthesized and utilized in the carbonylation of isobutyl amine with CO2. The results showed that Fe doping significantly enhanced the catalytic abilities of alpha-Bi2O3.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Yuan Tian, Xinxin Wang, Yanrong Liu, Wenping Hu
Summary: This paper predicts the solubility of nitrogen gas in ionic liquids (ILs) using two quantitative structure-property relationship (QSPR) models. By combining machine learning methods and ionic fragments contribution method, the accuracy and reliability of the prediction models are improved.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Liwang Wang, Wei Liu, Pan Yang, Yulong Chang, Xiaoxu Duan, Lingyu Xiao, Yaoming Hu, Jiwei Wu, Liang Ma, Hualin Wang
Summary: This study investigates the effective phase interfacial area (ae) of hydro-jet cyclones at different injection angles. The results show that a 45 degrees upward incidence angle yields the most favorable flow field characteristics for efficient mass transfer. The significant enhancement in ae of the hydro-jet cyclones offers the advantage of reducing equipment volume and cost savings.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Chuanjun Wu, Jiangzhi Chen, Jiyue Sun, I-Ming Chou, Shenghua Mei, Juezhi Lin, Lei Jiang
Summary: In this study, the solubility of H2S hydrate in water was measured using Raman spectroscopy. The results showed that the solubility increases with temperature under certain equilibrium conditions, and the solubility also depends on pressure and temperature under different equilibrium conditions. A thermodynamic model based on the van der Waals-Platteeuw theory was developed to predict the solubility, demonstrating its accuracy.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Lorenzo Brivio, Serena Meini, Mattia Sponchioni, Davide Moscatelli
Summary: This study investigates the influence of three main parameters and proposes a kinetic model to predict the optimal operating conditions for high yield of dimethyl terephthalate (DMT) in the chemical recycling process of polyethylene terephthalate (PET).
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Hongju Lin, Fanhui Liao, Yanchang Chu, Mingyu Xie, Lun Pan, Yuanyuan Wang, Lijian Leng, Donghai Xu, Le Yang, Gangfeng Ouyang
Summary: A honeycomb NiCo/C-Na catalyst with a micro-meso-macroporous structure has been fabricated and shown to have significantly higher catalytic activity for the decarboxylation of fatty acids. It also proves to be efficient in upgrading sludge HTL bio-crude, resulting in a biofuel with decreased viscosity and increased density.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Xiaoxian Li, Rui Li, Min Lin, Mingde Yang, Yulong Wu
Summary: A series of coated non-noble metal porous carbon catalysts were synthesized and applied to the aqueous-phase deoxygenation of algal bio-oil. One of the catalysts showed excellent deoxygenation selectivity and catalytic activity at 250 degrees C. The catalyst exhibited good hydrothermal stability and the reaction mechanism was proposed based on product analysis and active site analysis.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
M. V. Chudakova, M. V. Popov, P. A. Korovchenko, E. O. Pentsak, A. R. Latypova, P. B. Kurmashov, A. A. Pimenov, E. A. Tsilimbaeva, I. S. Levin, A. G. Bannov, A. V. Kleymenov
Summary: A series of catalysts with different potassium contents were prepared using solution combustion synthesis and characterized using various techniques. The results showed that the potassium content affected the phase composition and texture of the catalysts. The addition of a small amount of potassium resulted in a change in particle size distribution, leading to higher hydrogen yield. The Ni-1%K2O/Al2O3 catalyst exhibited the highest hydrogen yield at temperatures of 675 and 750 degrees Celsius.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Aliakbar Roosta, Nima Rezaei
Summary: In this study, we modified the electrolyte cubic plus association equation of state (e-CPA EoS) and integrated it with two electrical conductivity models to estimate the electrical conductivity of 11 monovalent electrolyte solutions in water. The modified e-CPA model demonstrated better performance and the hybridization with electrical conductivity models resulted in two predictive models for estimating the electrical conduction of dilute and concentrated electrolyte solutions. These predictive models showed relative average percentage deviations (AARD) of 11.15% and 13.87% over wide ranges of temperature and electrolyte concentration.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Haoren Niu, Jianzheng Wang, Qingzhu Jia, Qiang Wang, Jin Zhao, Fangyou Yan
Summary: A study developed two quantitative structure-property relationship models for the complexation performance of alpha- and beta-cyclodextrins and validated their stability and predictive ability through internal and external validation. The models showed robustness and satisfactory performance, as demonstrated by the experimental results and model validations. These models can effectively predict the binding constants between cyclodextrins and various types of molecules, providing valuable tools for cyclodextrin design.
CHEMICAL ENGINEERING SCIENCE
(2024)
