Review
Materials Science, Ceramics
Elmira Moosavi-Khoonsari, Jesus Alejandro Arias-Hernandez, Sun Yong Kwon
Summary: Knowledge of thermodynamics and phase equilibria of oxidic materials is critical for advancements in ceramics and glass. Computational thermodynamics has made it possible to predict phase diagrams and chemical reactions, but challenges remain due to unidentified thermodynamic properties of many oxides. Developing a universal model for estimating oxide properties with reliable extrapolation capacity is key. Atomistic models are insufficient, while group contribution-based methods, like the polyhedron model, show potential but need improvements. This paper presents the background and current state of the polyhedron model, discussing its strengths, weaknesses, and the potential for developing an improved version using artificial intelligence.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2023)
Article
Biochemistry & Molecular Biology
Mario R. C. Soromenho, Anastasiia Keba, Jose M. S. S. Esperanca, Mohammad Tariq
Summary: In this study, two thiouronium-based ionic liquids were tested for their ability to affect the formation and growth of CO2 and THF hydrates. It was found that these ionic liquids act as thermodynamic inhibitors and suppress the equilibria of CO2 hydrate formation. The study also emphasizes the importance of the methods and conditions used to screen additives for altering hydrate formation and growth.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2022)
Article
Materials Science, Ceramics
Peide Luo, Xiang Wu, Wenhui Xiao, Fan Zhang, Yao Wang, Dandan Huang, Yong Du
Summary: The phase relations in the ZrO2-Ta2O5-Nb2O5 system were experimentally investigated and thermodynamically modeled. It was found that Ta2O5 and Nb2O5 phases substantially extend into the ternary system, forming a continuous solid solution. Despite initial difficulties in reproducing experimental results, the introduction of ternary mixing parameters allowed for improved thermodynamic descriptions and successful validation of the data.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2022)
Review
Energy & Fuels
Yogendra Kumar, Jitendra S. Sangwai
Summary: Immediate measures are needed to store large quantities of anthropogenic CO2 in geological and oceanic reservoirs to address global warming and climate change. This article discusses the long-term viability, environmental sustainability, and economic potential of CO2 sequestration in the form of hydrates into oceanic and subsea sediments. The analysis shows that CO2 is denser than seawater at depths above 2800 m, providing an additional barrier for CO2 escape.
Article
Engineering, Chemical
Kwangbum Kim, Jeong-Hoon Sa
Summary: Capturing CO2 from exhaust gases by forming clathrate hydrates has great potential due to its mild operating conditions, economic feasibility, and environmental friendliness. However, the slow CO2 uptake kinetics and separation efficiency have hindered the realization of hydrate-based CO2 capture. In this study, the effect of the water-to-gas molar ratio (W/G ratio) on pre-combustion capture using clathrate hydrates was investigated, along with the use of residual liquid water and limiting the concentration of tetrahydrofuran (THF) to improve separation efficiency. Through a comprehensive evaluation, the optimal condition was determined to be 3 mol% THF + high W/G ratio. These findings emphasize the importance of considering the W/G ratio and its combined effects with other parameters for advanced pre-combustion capture using clathrate hydrates towards carbon neutrality.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Article
Engineering, Chemical
Jeong-Hoon Sa, Amadeu K. Sum
Summary: In this study, two different approaches were proposed to estimate the water activity for systems containing inhibitors: ice melting point and activity coefficient models. These methods provide a simple and reliable prediction of hydrate suppression temperatures for inhibited systems, advocating for their use over traditional methods.
Article
Polymer Science
Shreya Shetty, Enrique D. Gomez, Scott T. Milner
Summary: The study used molecular dynamics simulations and morphing method to calculate the interaction parameter chi for real polymer blends, with different transformation schemes needed for different polymers. Predictions for the first three blends agree reasonably with experiments but are sensitive to force field parameters.
Article
Materials Science, Ceramics
Gerson J. Leonel, Manuel Scharrer, Gurpreet Singh, Alexandra Navrotsky
Summary: This study systematically investigates the thermodynamic stability of SiaOb(M)(c)C-d structures derived from polymeric precursors incorporating metal fillers: Ta, Nb, and Hf, at 1200 and 1500°C. The results show that overall incorporation of Hf results in the most thermodynamically stable structures at all synthesis temperatures. SiaOb(M)(c)C-d specimens employing Nb fillers undergo the most stable structural evolution in this temperature range. The choice of metal filler influences composition, structural evolution, and thermodynamic stability in PDCs.
INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY
(2023)
Review
Green & Sustainable Science & Technology
Pekka Taskinen, Katri Avarmaa
Summary: Depleting and increasingly complex mineral resources present challenges for metal production, particularly in the control of iron oxide fluxing in the raw material basis of non-ferrous metals. The targeted metal values as minority components in the ores lead to more complex slag compositions in smelting furnaces.
Article
Thermodynamics
Sanehiro Muromachi
Summary: This study investigates the CO2 capture properties of semiclathrate hydrates formed with different salts, showing that they almost exclusively capture CO2. Among the salts, TBPB exhibits superior gas capture performance, while TBAC captures the least amount of CO2.
Article
Materials Science, Ceramics
Mengchuan Li, Rensheng Li, Tongsheng Zhang
Summary: This study obtained the phase equilibrium data of the SiO2-Ce2O3-CaO-25 wt %Al2O3 system through experimental methods, which is of great significance for the recycling of rare earth resources.
CERAMICS INTERNATIONAL
(2022)
Article
Thermodynamics
Hui Rong, Dan Zhao, Tao Cai, Sid Becker
Summary: This study proposes a reverse flow single-channel inlet and double-channel outlet (SIDO) microcombustor for analyzing the thermal performance and nitrogen oxide emission characteristics of ammonia/hydrogen-fuelled energy conversion systems. The findings show that the SIDO combustor has improved thermal performance and reduced nitrogen oxide emissions. Increasing the inlet pressure improves exergy efficiency and reducing nitrogen oxide emissions. Increasing the inlet flow velocity enhances the temperature uniformity of the combustor wall. This study confirms the viability of using the SIDO reverse flow structure to enhance thermodynamic performances in microcombustion energy conversion systems.
APPLIED THERMAL ENGINEERING
(2023)
Article
Metallurgy & Metallurgical Engineering
Cheng Liu, Qun Luo, Qin-Fen Gu, Qian Li, Kuo-Chih Chou
Summary: This study aims to experimentally determine the phase equilibria relationships of Mg-Ni-Y system, focusing on LPSOs, and establish a thermodynamic description. Four types of LPSOs are confirmed and their formation enthalpies are calculated. A new ternary compound, called tau phase, is observed for the first time, which is significant for the design of advanced magnesium-based alloys.
JOURNAL OF MAGNESIUM AND ALLOYS
(2022)
Article
Engineering, Chemical
Yiqian Ma, Michael Svard, Xiong Xiao, Suchithra Ashoka Sahadevan, James Gardner, Richard T. Olsson, Kerstin Forsberg
Summary: This study investigates the recovery of NiSO4 and CoSO4 hydrates from metal sulfate solutions using eutectic freeze crystallization (EFC). Result shows promising potential of EFC as an alternative method for recovering NiSO4 and CoSO4 hydrates.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Chemistry, Physical
Yuanze Sun, Keyao Li, Yan Su, Jijun Zhao
Summary: This study provides deep insights into the stability mechanism of clathrate hydrates, specifically focusing on the crystal structures and chemical potential phase diagrams of sII hydrates encapsulated with CO2 molecules. The research shows that both partially occupied and fully occupied hydrates are thermodynamically stable under certain pressure and temperature conditions, with the equilibrium temperature decreasing as the relative CO2 chemical potential increases at the same pressure.
JOURNAL OF PHYSICAL CHEMISTRY A
(2021)
Article
Engineering, Chemical
Heecheon Lee, Chaeyeong Seo, Minyong Lee, Jae W. Lee
Summary: A new graphical method based on pinch analysis is demonstrated for the design of pressure-swing distillation (PSD) and heat integration, showing the feasibility through visualization of feed data and temperature contours. The study reveals that different pinch pressures can be achieved in HIPSD system depending on column sequence or pure components separation order, and energy-efficient HIPSD can be achieved by considering pinch constraints.
Article
Chemistry, Multidisciplinary
Ki-Heum Park, Jae W. Lee, Youngsub Lim, Yutaek Seo
Summary: This study aims to design novel compression processes coupled with a cryogenic distillation unit to purify high-CO2 natural gas or biogas. Four different designs are evaluated to determine the required injection pressure and optimize the process design and operation variables. The study also investigates the sudden release of CO2 and recommends a controlled release strategy to avoid the formation of solid CO2.
JOURNAL OF CO2 UTILIZATION
(2022)
Article
Chemistry, Multidisciplinary
Hafizh Rizqullah, Jeongwoo Yang, Jae W. Lee
Summary: This study introduces a temperature swing method for simultaneously producing biodiesel and ethyl levulinate through in-situ transesterification of spent coffee grounds. The effects of temperature and the amounts of catalyst and ethanol were investigated and it was found that temperature predominantly affects the yield. The highest yields were obtained at different temperatures for biodiesel and ethyl levulinate.
KOREAN JOURNAL OF CHEMICAL ENGINEERING
(2022)
Article
Chemistry, Physical
Sung Joon Park, Seung Hee Kang, Hyung-Ki Min, Myung-gi Seo, Sungjoon Kweon, Min Bum Park, Young Heon Choi, Jae W. Lee
Summary: A series of WOx/Al2O3 catalysts with different tungsten contents were prepared and characterized. The results showed that the catalyst with 6.25 wt% tungsten had the highest acidity and exhibited the best catalytic performance in the pyrolysis of HDPE to liquid oil.
MOLECULAR CATALYSIS
(2022)
Review
Engineering, Environmental
Ayeong Byeon, Won Chan Yun, Jong Min Kim, Jae W. Lee
Summary: This review focuses on the application of metal-free heteroatom-doped carbon catalysts in the electrochemical synthesis of hydrogen peroxide through the two-electron oxygen reduction reaction (2e(-) ORR). The electronic properties of carbon can be changed depending on the type of heteroatoms, which significantly affect the ORR catalytic activity. The location of active catalytic sites within the carbon network and the reaction environment, such as pH and electrolyte additives, are also investigated. This review provides fundamental insights into how heteroatoms enhance the electrocatalytic activity of metal-free carbon materials for the 2e(-) ORR.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Environmental
Jeongwoo Yang, Dong Woo Kang, Hodong Kim, Byunghoon Hwang, Jae W. Lee
Summary: The use of a free-standing carbon interlayer in lithium-sulfur batteries shows promise due to its ability to suppress the shuttle effect and provide flexibility. However, the thickness of the interlayer inhibits Li-ion transport. This study addresses this issue by synthesizing a composite with superior pore characteristics and evenly distributed catalytic sites, resulting in improved Li-ion diffusion and redox reaction.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Electrochemistry
Byunghoon Hwang, Jeongwoo Yang, Dohyeun Kim, Won Chan Yun, Jae W. Lee
Summary: We designed a membraneless potassium bromide electrochemical capacitor (ML-PBEC) single cell that generates high energy density and reduces self-discharge. Highly porous carbon with a hierarchical structure was synthesized from CO2 gas, and the effect of nitrogen doping on the CO2-derived carbon materials' electrochemical performance was investigated. The ML-PBEC single cell, using the synthesized carbon as electrodes and a Br-/Br3- redox active aqueous electrolyte, achieved enhanced energy density by suppressing the cross-diffusion of soluble bromine molecules through electrostatic interaction between N-doped sites' protons and polybromide anions even without a membrane.
ELECTROCHIMICA ACTA
(2023)
Article
Chemistry, Multidisciplinary
Jeil Park, Wonhyeong Lee, Jae W. W. Lee
Summary: This study explored the impact of dual impeller geometry on droplet size in the S-PVC polymerization process. A borescope method was used to measure droplet size in a biphasic liquid system, and it was found that replacing the upper paddle impeller with a 20-degree pitched paddle increased the Sauter mean diameter by 46.5%. The Sauter mean diameter also increased with larger impeller diameter and blade width. A revised geometrical factor (F) was considered, and a calculated maximum energy dissipation rate was used to establish a correlation for the Sauter mean diameter.
KOREAN JOURNAL OF CHEMICAL ENGINEERING
(2023)
Article
Energy & Fuels
Dasol Bae, Yikyeom Kim, Eun Hee Ko, Seung Ju Han, Jae W. Lee, Minkyu Kim, Dohyung Kang
Summary: This study investigated the reaction kinetics and mechanism of CH4 pyrolysis in mixtures of molten MnCl2 with various chlorides, and found that MnCl2-KCl mixture showed the lowest apparent activation energy and the highest crystallinity. This suggests that MnCl2-KCl has unique pathways for methane dehydrogenation and carbon formation.
Article
Green & Sustainable Science & Technology
Wonhyeong Lee, Dong Woo Kang, Yun-Ho Ahn, Jae W. Lee
Summary: In this study, a mixture of hydrate seed solution and liquid phase thermodynamic promoter was introduced to promote the formation of hydrogen hydrates for safe hydrogen storage.
RENEWABLE & SUSTAINABLE ENERGY REVIEWS
(2023)
Article
Chemistry, Multidisciplinary
Ki Heum Park, Jae W. Lee, Yutaek Seo
Summary: In this study, a VOC recovery process based on selective condensation was developed. By analyzing the economic benefits, the process efficiency was optimized, and a cascade refrigerant system using carbon dioxide and ammonia was proposed to achieve more efficient and eco-friendly operation of the VOC recovery system.
JOURNAL OF CO2 UTILIZATION
(2023)
Article
Energy & Fuels
Donggun Kim, Minyong Lee, Yongbeom Shin, Jeongwoo Lee, Jae W. Lee
Summary: This study presents a novel process for the direct production of diethyl carbonate and ethylene glycol from ethylene carbonate and ethanol through reactive distillation. By integrating reactive distillation systems and eliminating the need for separating the azeotrope mixture, an energy-efficient process is achieved. Two design alternatives are proposed, with both resulting in reductions in energy consumption, cost, and CO2 emissions compared to conventional processes. These alternatives demonstrate their economic viability and effectiveness in CO2 mitigation.
CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION
(2023)
Article
Engineering, Environmental
Yikyeom Kim, Hyeon Seok Kim, Dohyung Kang, Minkyu Kim, Jae W. Lee
Summary: Chemical looping steam methane reforming (CL-SMR) can produce high-purity hydrogen without additional separation units. The reactivity of LaFeO3 oxygen carrier towards methane can be enhanced by introducing a small amount of iridium. Both particle reduction and oxidation were significantly improved by the presence of iridium, and the preparation pathways of oxygen carriers greatly affected the long-term performance. Although surface iridium species prepared by an impregnation method were severely aggregated during successive redox cycling, B-site incorporation of iridium led to the exsolution of IrOx nanoparticles anchored on the perovskite host and enhanced redox stability, which is essential for the long-term operation of the chemical looping process.
CHEMICAL ENGINEERING JOURNAL
(2023)
Review
Electrochemistry
Ayeong Byeon, Won Chan Yun, Jong Min Kim, Jae W. Lee
Summary: Hydrogen peroxide is widely used in various industries for different purposes, such as water purification and rocket fuels. The conventional method of hydrogen peroxide production consumes a lot of energy and generates chemical waste. Therefore, there is a growing interest in the electrochemical production method using non-precious metal catalysts, such as transition metals and heteroatoms, for eco-friendly and low-energy synthesis. This review focuses on the modification of atomic configuration to enhance the catalytic activity of non-precious metal catalysts for the two-electron oxygen reduction reaction (ORR).
Article
Chemistry, Multidisciplinary
Jeil Park, Wonhyeong Lee, Jae W. W. Lee
Summary: This study investigated the impact of dual impeller geometry on droplet size in S-PVC polymerization process and proposed a correlation equation to estimate droplet size with a certain margin of error, aiding in predicting the normality of the polymerization reaction under specific impeller geometry.
KOREAN JOURNAL OF CHEMICAL ENGINEERING
(2023)
Article
Engineering, Chemical
Qing Han, Mengqing Shi, Linkai Han, Di Liu, Mingwei Tong, Yuxin Xie, Zhonghua Xiang
Summary: Developing highly efficient bifunctional oxygen electrocatalysts is crucial for zinc-air flow batteries. Metal-organic frameworks (MOFs) and covalent organic polymers (COPs) have emerged as promising alternatives due to their designable and controllable atomic-level structures. However, their catalytic performances are limited by conductivity and catalytic activity. In this study, nanosheet FeNi-MOF and iron phthalocyanine rich COP hybrid materials are assembled through the pi-pi stacking effect to create highly efficient bifunctional electrocatalysts. The resulting catalyst exhibits superior catalytic performance and stability, making it a promising candidate for zinc-air flow batteries.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Daria Grigorash, Dmytro Mihrin, Rene Wugt Larsen, Erling H. Stenby, Wei Yan
Summary: The article introduces a new approach to describe the cross-association between molecules, allowing for the simulation of weakly bound molecular complexes with different conformations in mixtures. By incorporating this approach into the equation of state, accurate predictions of vapor-liquid equilibrium and liquid-liquid equilibrium can be made. The new method is validated through experiments on alcohol and acid mixtures, with the results compared to experimental data, demonstrating its accuracy and reliability.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Mohammed Al-Sharabi, Daniel Markl, Vincenzino Vivacqua, Prince Bawuah, Natalie Maclean, Andrew P. E. York, Axel Zeitler
Summary: This study used terahertz pulsed imaging to investigate the transport process of different solvents into ceramic catalytic materials. The results showed that the heating rate of the samples influenced the water transport rate, while the viscosity of 1-octanol slowed down its transport.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Chukwunonso Anyaoku, Sati Bhattacharya, Rajarathinam Parthasarathy
Summary: This study aimed to enhance understanding of settling dynamics in viscoelastic fluids by developing a semi-empirical correlation and a dimensionless ratio, which accurately described the characteristics of settling suspensions.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Antti I. Koponen, Janika Viitala, Atsushi Tanaka, Baranivignesh Prakash, Olli-Ville Laukkanen, Ari Jasberg
Summary: This study focuses on the development of foam application chemicals for the paper and board industry. The research explores the rheology of the polyvinyl alcohol foam used in the process. Measurements were conducted to determine the foam viscosity and slip flow. The results suggest that slip flow contributes significantly to the total flow rate, and the obtained viscosity and slip models provide a solid foundation for industrial processes.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Dalei Sun, Jinghui Cai, Yating Yang, Zhiwu Liang
Summary: In this study, Fe-doped alpha-Bi2O3 catalysts with different Fe/Bi molar ratios were synthesized and utilized in the carbonylation of isobutyl amine with CO2. The results showed that Fe doping significantly enhanced the catalytic abilities of alpha-Bi2O3.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Yuan Tian, Xinxin Wang, Yanrong Liu, Wenping Hu
Summary: This paper predicts the solubility of nitrogen gas in ionic liquids (ILs) using two quantitative structure-property relationship (QSPR) models. By combining machine learning methods and ionic fragments contribution method, the accuracy and reliability of the prediction models are improved.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Liwang Wang, Wei Liu, Pan Yang, Yulong Chang, Xiaoxu Duan, Lingyu Xiao, Yaoming Hu, Jiwei Wu, Liang Ma, Hualin Wang
Summary: This study investigates the effective phase interfacial area (ae) of hydro-jet cyclones at different injection angles. The results show that a 45 degrees upward incidence angle yields the most favorable flow field characteristics for efficient mass transfer. The significant enhancement in ae of the hydro-jet cyclones offers the advantage of reducing equipment volume and cost savings.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Chuanjun Wu, Jiangzhi Chen, Jiyue Sun, I-Ming Chou, Shenghua Mei, Juezhi Lin, Lei Jiang
Summary: In this study, the solubility of H2S hydrate in water was measured using Raman spectroscopy. The results showed that the solubility increases with temperature under certain equilibrium conditions, and the solubility also depends on pressure and temperature under different equilibrium conditions. A thermodynamic model based on the van der Waals-Platteeuw theory was developed to predict the solubility, demonstrating its accuracy.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Lorenzo Brivio, Serena Meini, Mattia Sponchioni, Davide Moscatelli
Summary: This study investigates the influence of three main parameters and proposes a kinetic model to predict the optimal operating conditions for high yield of dimethyl terephthalate (DMT) in the chemical recycling process of polyethylene terephthalate (PET).
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Hongju Lin, Fanhui Liao, Yanchang Chu, Mingyu Xie, Lun Pan, Yuanyuan Wang, Lijian Leng, Donghai Xu, Le Yang, Gangfeng Ouyang
Summary: A honeycomb NiCo/C-Na catalyst with a micro-meso-macroporous structure has been fabricated and shown to have significantly higher catalytic activity for the decarboxylation of fatty acids. It also proves to be efficient in upgrading sludge HTL bio-crude, resulting in a biofuel with decreased viscosity and increased density.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Xiaoxian Li, Rui Li, Min Lin, Mingde Yang, Yulong Wu
Summary: A series of coated non-noble metal porous carbon catalysts were synthesized and applied to the aqueous-phase deoxygenation of algal bio-oil. One of the catalysts showed excellent deoxygenation selectivity and catalytic activity at 250 degrees C. The catalyst exhibited good hydrothermal stability and the reaction mechanism was proposed based on product analysis and active site analysis.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
M. V. Chudakova, M. V. Popov, P. A. Korovchenko, E. O. Pentsak, A. R. Latypova, P. B. Kurmashov, A. A. Pimenov, E. A. Tsilimbaeva, I. S. Levin, A. G. Bannov, A. V. Kleymenov
Summary: A series of catalysts with different potassium contents were prepared using solution combustion synthesis and characterized using various techniques. The results showed that the potassium content affected the phase composition and texture of the catalysts. The addition of a small amount of potassium resulted in a change in particle size distribution, leading to higher hydrogen yield. The Ni-1%K2O/Al2O3 catalyst exhibited the highest hydrogen yield at temperatures of 675 and 750 degrees Celsius.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Aliakbar Roosta, Nima Rezaei
Summary: In this study, we modified the electrolyte cubic plus association equation of state (e-CPA EoS) and integrated it with two electrical conductivity models to estimate the electrical conductivity of 11 monovalent electrolyte solutions in water. The modified e-CPA model demonstrated better performance and the hybridization with electrical conductivity models resulted in two predictive models for estimating the electrical conduction of dilute and concentrated electrolyte solutions. These predictive models showed relative average percentage deviations (AARD) of 11.15% and 13.87% over wide ranges of temperature and electrolyte concentration.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Haoren Niu, Jianzheng Wang, Qingzhu Jia, Qiang Wang, Jin Zhao, Fangyou Yan
Summary: A study developed two quantitative structure-property relationship models for the complexation performance of alpha- and beta-cyclodextrins and validated their stability and predictive ability through internal and external validation. The models showed robustness and satisfactory performance, as demonstrated by the experimental results and model validations. These models can effectively predict the binding constants between cyclodextrins and various types of molecules, providing valuable tools for cyclodextrin design.
CHEMICAL ENGINEERING SCIENCE
(2024)