期刊
CHEMICAL ENGINEERING JOURNAL
卷 353, 期 -, 页码 814-823出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2018.07.159
关键词
Aqueous sodium-ion batteries; NaTi2(PO4)(3); TiN; Electrochemical performance
资金
- National Program on Key Basic Research Project of China (973 Program) [2014CB239701]
- Natural Science Foundation of China [51504139, 51672128, 21773118]
- Anhui Provincial Natural Science Foundation [1708085QE115]
- Provincial Natural Science Research Project of Anhui Colleges [KJ2016A092]
- NUAA [BCXJ16-07, kfjj20170616]
- Funding of Jiangsu Innovation Program for Graduate Education [KYLX16_0341]
- Prospective Joint Research Project of Cooperative Innovation Fund of Jiangsu Province, China [BY2016003-13]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
The TiN coated NaTi2(PO4)(3) with high electrochemical performance as anode materials for aqueous sodium-ion batteries were synthesized successfully by solvothermal routine and subsequent nitriding process in the presence of ammonia. The nitriding process would not change the crystal structure of NaTi2(PO4)(3). However, the Ti4+ in the material can be reduced to Ti3+, and the nitrogen atom can be doped into the material, forming a TiN layer on the surface of the material, which significantly increased the electronic conductivity of NaTi2(PO4)(3) material. By adjusting nitriding time, we have prepared the best nitriding material and the effect of nitriding on NaTi2(PO4)(3) materials has been clearly clarified. The rate capacity and cyclic performance of the TiN tailored NaTi2(PO4)(3) have been greatly improved, which is much better than the pristine phase. The initial capacity of the TiN tailored NaTi2(PO4)(3) can reach 131.9 mAh g(-1), and it can still keep 92 mAh g(-1) after 100 cycles at 2 C.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据