期刊
CHEMICAL ENGINEERING JOURNAL
卷 242, 期 -, 页码 204-210出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2013.12.040
关键词
Chemical looping combustion; Carbon monoxide kinetics
资金
- Department of Energy
Thermogravimetric analysis (TGA) of the reduction behavior of hematite by using continuous streams of 5%, 10%, and 20% CO concentrations in N-2 was conducted at temperatures ranging from 750 to 900 degrees C over ten cycles. The reduced hematite was then oxidized using dry air. The rate of reduction was determined by the sample weight loss. Analysis of the data indicated that the reduction behavior can be described by single rate-determining step and it was controlled by the chemical reaction at the particle surface. The mass spectroscopy analysis of product gas indicated that no carbon deposition was found when operating at these temperature ranges (750-900 degrees C). The analysis of reduction showed that two reduction steps (Fe2O3 -> Fe3O4, Fe3O4 -> FeO) proceed simultaneously. The activation energy was estimated to be 19.0 +/- 0.14 kJ/mole. Published by Elsevier B.V.
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