Article
Chemistry, Multidisciplinary
Malek Y. S. Ibrahim, Jeffrey A. Bennett, Milad Abolhasani
Summary: A study reported a photo flow reactor using Rh/TiO2 photocatalyst to achieve the selective dehydrogenation of 1,2,3,4-tetrahydroquinoline, reducing the optimal Rh loading by 10 times compared to a batch reactor and facilitating catalyst reuse and regeneration, thus overcoming the energy and cost barriers in hydrogen production reaction.
Article
Chemistry, Applied
Matthew W. Halloran, Caitlin Hudecek, Michael D. Burkart
Summary: This article describes a concise methodology for synthesizing acid hydrazides from carboxylic acids via a continuous flow process, achieving yields ranging from 65 to 91%. The method is applicable to a variety of mono- and diacids, including aliphatic, aromatic, and heteroaromatic functionalities, and demonstrates good scalability.
ORGANIC PROCESS RESEARCH & DEVELOPMENT
(2023)
Article
Chemistry, Applied
Francisca Navarro-Fuentes, Mark Andrew Keane, Xiong-Wei Ni
Summary: This paper presents the successful multiphase catalytic hydrogenation of 3-butyn-2-ol over Pd/Al2O3 catalyst in a continuous oscillatory baffled reactor (COBR) for over 12 hours. The catalyst stability and attrition were examined, showing no loss of catalyst during the operation and a slow deactivation rate, indicating significant advantages over batch operation.
ORGANIC PROCESS RESEARCH & DEVELOPMENT
(2021)
Article
Engineering, Chemical
Vincent Goetz, Chloe Dezani, Enrique Ribeiro, Cyril Caliot, Gael Plantard
Summary: This article aims to develop a modeling and simulating tool for the operation of a continuous flow heterogeneous photocatalysis reactor. By focusing on the coupling between radiative transfer and reaction kinetics, and utilizing the Monte Carlo method to solve the radiative transfer equation, the dynamic simulation model has been validated.
Article
Environmental Sciences
Anas Salhi, Sana Esserrar, Bouchra Nechchadi, Mohammed El Amine Ghanjaoui, Abdelkahhar Aguedache, Mohammed El Krati, Soufiane Tahiri
Summary: The aim of this study was to investigate the photocatalytic degradation of Acid Black 24 dye in a continuous flow cascade reactor using immobilized titanium dioxide on a cellulosic material. The results showed a synergistic effect of adsorption and photocatalysis, and various parameters affecting dye removal efficiency were examined. The best degradation yield was achieved in an acidic medium due to the strong attraction between the positively charged catalyst and the anionic dye molecules. The optimal times for achieving the best yields depended on the initial dye concentration, treated solution volume, and reactor feed rate. Additionally, the reuse of the catalytic material was technically feasible, which could reduce the cost of treatment for industrial-scale applications.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2022)
Article
Chemistry, Physical
Rishi Verma, Ritaj Tyagi, Vamsee K. K. Voora, Vivek Polshettiwar
Summary: In this study, the use of nickel-loaded black gold catalyst (black Au-Ni) that absorbs broadband light for photocatalytic hydrodechlorination and propene and acetylene hydrogenation reactions was demonstrated. The black Au-Ni catalyst showed significantly higher activity compared to black Au. The reaction mechanism was supported by various experimental and theoretical evidence, indicating the involvement of photothermal effect and hot carriers in the hydrodechlorination reactions.
Article
Chemistry, Physical
Stefan Simic, Migle Jakstaite, Wilhelm T. . S. Huck, Christoph K. Winkler, Wolfgang Kroutil
Summary: The challenges of light-dependent biocatalytic transformations of lipophilic substrates in aqueous media are addressed through continuous flow reactions. The immobilization of the catalyst on a carrier or using a homogeneous system is determined by the photostability of the catalyst. Homogeneous conditions in the CvFAP-catalyzed photodecarboxylation of palmitic acid achieved a high space-time yield, demonstrating the advantage of continuous flow for photobiocatalytic processes.
Article
Chemistry, Multidisciplinary
Ranjit S. Atapalkar, Amol A. Kulkarni
Summary: A simple and efficient solvent-free protocol for continuous flow synthesis of amides at room temperature is developed using easily available starting materials. N-(3-Dimethylaminopropyl)-N′-ethylcarbodiimide hydrochloride (EDC.HCl) was used as the reagent for the formation of an amide bond without using any metal catalyst or additives. This approach is extended for the synthesis of 36 derivatives and 2 bioactive molecules using different substrates.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Physical
Junqing Guo, Derek Norris, Antonio Ramirez, Jack L. Sloane, Eric M. Simmons, Jacob M. Ganley, Martins S. Oderinde, T. G. Murali Dhar, Geraint H. M. Davies, Trevor C. Sherwood
Summary: The study developed dual nickel photoredox catalysis conditions for the decarboxylative cross-coupling of aryl halides and carboxylic acids containing fully substituted α-carbons. High-throughput experimentation identified Ni(TMHD)(2) as the optimal precatalyst, while the nickel-bipyridyl complexes typically used in decarboxylative couplings predominantly produced undesired C-O products. Computational work provided insights into the potential mechanistic underpinnings for the C-C vs C-O selectivity of the nickel-diketonate complex.
Article
Chemistry, Physical
Stalin Coronel, Diana Endara, Ana Belen Lozada, Lucia E. Manangon-Perugachi, Ernesto de la Torre
Summary: The study evaluated the photocatalytic oxidation of cyanide using TiO2 supported on activated carbon in a continuous flow UV photo-reactor. Results showed that 97% of CN- was degraded within 24 hours due to combined photocatalytic oxidation and adsorption. The design of the continuous photo-reactor and the use of TiO2-AC composites enhanced the photocatalytic cyanide oxidation performance.
Article
Chemistry, Multidisciplinary
Jianle Zhou, Frank Hollmann, Qi He, Wen Chen, Yunjian Ma, Yonghua Wang
Summary: This study engineered a modified form of a photodecarboxylase enzyme and successfully integrated it into a membrane, leading to continuous generation of alkane biofuels. The photoenzyme-loaded membrane demonstrated its capability in converting fatty acids of varying chain lengths and exhibited commendable catalytic proficiency in eight consecutive cycles.
Review
Chemistry, Applied
Sigrid Gavelle, Milan Innocent, Thomas Aubineau, Amandine Guerinot
Summary: This article provides an overview of recent advances in LMCT of carboxylates, with a special focus on mechanistic aspects of these transformations. Carboxylic acids can be considered as ideal biobased feedstocks in sustainable processes, and the photoinduced ligand-to-metal charge transfer offers low-consuming energy source and innovative conditions for mild and highly selective functionalization.
ADVANCED SYNTHESIS & CATALYSIS
(2022)
Article
Chemistry, Physical
Changha Kim, Jinwook Jeong, Mari Vellakkaran, Sungwoo Hong
Summary: This study demonstrates an efficient photocatalytic platform for the C-H alkylation of pyridines at the C4 position using alkyl carboxylic acids as alkylating agents, offering a practical approach for the pyridylation of a diverse range of carboxylic acids and amino acids under mild, metal-free conditions.
Article
Chemistry, Physical
Changha Kim, Jinwook Jeong, Mari Vellakkaran, Sungwoo Hong
Summary: A highly efficient visible-light-mediated C-H alkylation of pyridines at the C4 position using alkyl carboxylic acids as alkylating agents is reported in this study. The released N-centered radical acts as an effective oxidizing agent for single-electron transfer (SET) oxidation to regenerate the photocatalyst, making this photocatalytic system appealing from a mechanistic perspective. The strategy offers a practical approach for the C4-selective pyridylation of carboxylic acids and amino acids with various functional groups under mild, metal-free conditions.
Article
Engineering, Environmental
Zhengya Dong, Stefan D. A. Zondag, Matthias Schmid, Zhenghui Wen, Timothy Noel
Summary: This study describes the development of an ultrasonic milli-reactor to handle challenging solid-containing transformations, showcasing its efficacy in a photochemical oxidation reaction. Ultrasound irradiation improves liquid mixing, gas-liquid mass transfer, and ensures resuspension of settled particles, while enhancing photon absorption by the semiconductor catalyst.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Physical
Xianjie Wang, Christelle Barakat, Zixian Jia, Manolis N. Romanias, Frederic Thevenet, Antoine Rousseau
Summary: While literature studies suggest a positive role of coupling materials with non-thermal plasma for Volatile Organic Compounds (VOC) removal, most focus on direct plasma-material interaction. This study, however, emphasizes the interaction between VOCs and materials, with reactive adsorption of VOCs found to play a key role in enhancing oxidation and mineralization efficiency under post-plasma exposure.
Article
Chemistry, Multidisciplinary
Darya Urupina, Vincent Gaudion, Manolis N. Romanias, Frederic Thevenet
Summary: This study investigated the formation of sulfites and sulfates on the surface of volcanic and desert dusts under atmospheric conditions. It was found that surface composition and water play important roles in the formation process.
ACS EARTH AND SPACE CHEMISTRY
(2022)
Editorial Material
Chemistry, Physical
Chantal Guillard, Didier Robert
Article
Chemistry, Multidisciplinary
Nicolas Crespo-Monteiro, Marwa Hamandi, Maria Alejandra Usuga Higuita, Chantal Guillard, Frederic Dappozze, Damien Jamon, Francis Vocanson, Yves Jourlin
Summary: Surface micro-nanostructuring can enhance the photocatalytic efficiency of sol-gel TiO2 coatings during formic acid degradation, leading to improved functionality and properties. Different factors, such as annealing temperature and layer thickness, can affect the degradation process.
Article
Environmental Sciences
Mohamad N. Zeineddine, Darya Urupina, Manolis N. Romanias, Veronique Riffault, Frederic Thevenet
Summary: The uptake of acetic acid on natural Gobi dust was investigated under different levels of relative humidity. Acetic acid was found to compete with water molecules for adsorption sites on Gobi dust, and its uptake decreased with increasing humidity. Interestingly, at high humidity levels, the uptake of acetic acid led to the formation of oxygenated volatile organic compounds. This study highlights the reactivity of acetic acid on natural mineral dust, and its potential contribution to atmospheric processes.
ATMOSPHERIC ENVIRONMENT
(2023)
Article
Construction & Building Technology
Raphael Brun, Marie Verriele, Manolis N. Romanias, Marion Chenal, Arnaud Soisson, Wolfram Maier, Frederic Thevenet
Summary: This study provides new insights into the uptake abilities of lime-cement-plaster towards indoor pollutants, focusing on formaldehyde. The results show that plaster samples continuously take up 65-77% of the formaldehyde inlet concentration and reveal the heterogeneous Cannizzaro reaction of formaldehyde on the plaster surface. This surface process has the potential to impact indoor air formaldehyde budget and should be considered in indoor air quality models.
BUILDING AND ENVIRONMENT
(2023)
Article
Biochemistry & Molecular Biology
Insaf Abdouli, Frederic Dappozze, Marion Eternot, Chantal Guillard, Nadine Essayem
Summary: This paper provides evidence that the model reaction of aqueous dihydroxyacetone (DHA) conversion is influenced by both the acidity and basicity of TiO2 catalysts. Different products are obtained through two parallel pathways.
Article
Physics, Fluids & Plasmas
Hang Yang, Antoine Rousseau
Summary: The article studies a helium plasma jet driven by 15-18 kHz sinusoidal voltage and its multi-periodic self-triggered mode or random mode based on applied voltage, driven frequency, and inter-electrode gap distance. Most of the observed bullets operate every 2 or 3 sinusoidal periods, resembling pulsed operating mode. The presence of an outer grounded electrode ring is crucial for ignition and enhances the propagation length up to 8 times. Fast imaging reveals pre-ignition self-triggered discharges and accumulation of charges beneath the ground electrode, locally enhancing the electric field. Bullet velocities are compared using optical emission spectrum for different polarities and gap distances.
PLASMA SOURCES SCIENCE & TECHNOLOGY
(2023)
Article
Chemistry, Physical
Nouha Mediouni, Frederic Dappozze, Lhoussain Khrouz, Stephane Parola, Abdesslem Ben Haj Amara, Hafsia Ben Rhaiem, Nicole Jaffrezic-Renault, Philippe Namour, Chantal Guillard
Summary: This study investigated the generation of hydrogen peroxide on commercial and synthesized ZnO from different precursors using model molecules and phenolic intermediates. The results showed that the improved efficiency of ZnO photocatalysis is related to the production of H2O2, the reduction of oxygen vacancies, and the similar number of moles of H2O2 formed per number of carbon atoms removed.
Article
Chemistry, Physical
Jie Yu, Jesus Gonzalez-Cobos, Frederic Dappozze, Nicolas Grimaldos-Osorio, Philippe Vernoux, Angel Caravaca, Chantal Guillard
Summary: In this study, a pioneering photoelectrolyser with a non-noble metal-based photoanode (WO3) was designed, tested and optimized for the valorization of glycerol. The system operated in near-neutral conditions using a proton-exchange membrane (PEM) and selectively oxidized glycerol on the anode while producing purified hydrogen on the cathode. The influence of light irradiation, external bias and cell temperature on the production rates of glyceraldehyde (GAD), dihydroxyacetone (DHA) and hydrogen was investigated, and the long-term stability of the photoelectrolyser was validated.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2023)
Article
Chemistry, Multidisciplinary
Juliette Karpiel, Pierre Lonchambon, Frederic Dappozze, Ileana Florea, Diana Dragoe, Chantal Guillard, Nathalie Herlin-Boime
Summary: In an attempt to produce alkenes efficiently, a photocatalytic process has been developed to selectively obtain ethylene from propionic acid degradation. Copper oxide-modified titanium dioxide nanoparticles were synthesized using laser pyrolysis, and the synthesis atmosphere strongly influenced the morphology and selectivity of the photocatalysts towards different hydrocarbons and H2 products. Under a helium environment, highly dispersed copper species in CuxOy/TiO2 promoted the production of C2H6 and H2, while under an argon environment, copper oxides organized into distinct nanoparticles favored the production of C2H4, with selectivity as high as 85% compared to 1% with pure TiO2.
Article
Environmental Sciences
Jerome Lasne, Darya Urupina, Elena C. Maters, Pierre Delmelle, Manolis N. Romanias, Frederic Thevenet
Summary: Iceland is the largest volcanic dust desert on Earth. The study reveals that volcanic dust particles can interact with atmospheric pollutants, and the reactivity is influenced by humidity and UV light.
ENVIRONMENTAL SCIENCE-ATMOSPHERES
(2022)
Article
Environmental Sciences
Outi Meinander, Pavla Dagsson-Waldhauserova, Pavel Amosov, Elena Aseyeva, Cliff Atkins, Alexander Baklanov, Clarissa Baldo, Sarah L. Barr, Barbara Barzycka, Liane G. Benning, Bojan Cvetkovic, Polina Enchilik, Denis Frolov, Santiago Gasso, Konrad Kandler, Nikolay Kasimov, Jan Kavan, James King, Tatyana Koroleva, Viktoria Krupskaya, Markku Kulmala, Monika Kusiak, Hanna K. Lappalainen, Michal Laska, Jerome Lasne, Marek Lewandowski, Bartlomiej Luks, James B. McQuaid, Beatrice Moroni, Benjamin Murray, Ottmar Moehler, Adam Nawrot, Slobodan Nickovic, Norman T. O'Neill, Goran Pejanovic, Olga Popovicheva, Keyvan Ranjbar, Manolis Romanias, Olga Samonova, Alberto Sanchez-Marroquin, Kerstin Schepanski, Ivan Semenkov, Anna Sharapova, Elena Shevnina, Zongbo Shi, Mikhail Sofiev, Frederic Thevenet, Throstur Thorsteinsson, Mikhail Timofeev, Nsikanabasi Silas Umo, Andreas Uppstu, Darya Urupina, Gyorgy Varga, Tomasz Werner, Olafur Arnalds, Ana Vukovic Vimic
Summary: Dust particles from high latitudes have significant implications for climate and the environment. Identifying the locations and intensity of dust sources in these regions is crucial for understanding their impacts on the Earth's systems. This study quantifies the source intensity of high-latitude dust and identifies its potential global distribution. The findings highlight the seasonal character of most high-latitude dust sources and the influence of weather conditions on dust emissions. Additionally, the study emphasizes the need to improve the representation of high-latitude dust in models and assess its environmental and climate significance.
ATMOSPHERIC CHEMISTRY AND PHYSICS
(2022)
Article
Biochemistry & Molecular Biology
L. M. Betts, F. Dappozze, M. Hamandi, C. Guillard
Summary: The decomposition of ethanol under green conditions for the synthesis of acetal was investigated using TiO2 activated under UV-A radiation. The nature of TiO2 and the presence of Pt were found to affect the formation of acetal and acetaldehyde. Rutile TiO2 without noble metal increased acetal formation, while Pt deposition facilitated acetal formation at lower concentrations of acetaldehyde.
PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES
(2022)
Article
Meteorology & Atmospheric Sciences
Antonia G. Zogka, Manolis N. Romanias, Frederic Thevenet
Summary: The performance of a multi-ion selected ion flow tube mass spectrometer (SIFT-MS) was evaluated for real-time monitoring of formaldehyde (FM) and glyoxal (GL) concentrations. SIFT-MS showed high sensitivity for FM, but sensitivity for GL was affected by humidity. The use of NO+ precursor ion was recommended for reliable detection and quantitation of GL.
ATMOSPHERIC MEASUREMENT TECHNIQUES
(2022)
Article
Engineering, Environmental
Xinping Zhang, Yuxin Guo, Xiaoyang Liu, Shun-Yu Wu, Ya-Xuan Zhu, Shao-Zhe Wang, Qiu-Yi Duan, Ke-Fei Xu, Zi-Heng Li, Xiao-Yu Zhu, Guang-Yu Pan, Fu-Gen Wu
Summary: This study develops a nanotrigger HCFT for simultaneous photodynamic therapy and light-triggered ferroptosis therapy. The nanotrigger can relieve tumor hypoxia, induce enhanced photodynamic reaction, and facilitate the continuation of Fenton reaction, ultimately leading to lethal ferroptosis in tumor cells.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Olumide Bolarinwa Ayodele, Toyin Daniel Shittu, Olayinka S. Togunwa, Dan Yu, Zhen-Yu Tian
Summary: This study focused on the semihydrogenation of acetylene in an ethylene-rich stream using two alloyed Pt catalysts PtCu and PtCo. The PtCu catalyst showed higher activity and ethylene yield compared to PtCo due to its higher unoccupied Pt d-orbital density. This indicates that alloying Pt with Cu is more promising for industrial relevant SHA catalyst.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Guowei Chen, Wen-Cheng Chen, Yaozu Su, Ruicheng Wang, Jia-Ming Jin, Hui Liang, Bingxue Tan, Dehua Hu, Shaomin Ji, Hao-Li Zhang, Yanping Huo, Yuguang Ma
Summary: This study proposes an intramolecular dual-locking design for organic luminescent materials, achieving high luminescence efficiency and performance for deep-blue organic light-emitting diodes. The material also exhibits unique mechanochromic luminescence behavior and strong fatigue resistance.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Joren van Stee, Gregory Hermans, Jinu Joseph John, Koen Binnemans, Tom Van Gerven
Summary: This work presents a continuous solvent extraction method for the separation of cobalt and nickel in a millifluidic system using Cyphos IL 101 (C101) as the extractant. The optimal conditions for extraction performance and solvent properties were determined by investigating the effects of channel length, flow rate, and temperature. The performance of a developed manifold structure was compared to a single-channel system, and excellent separation results were achieved. The continuous separation process using the manifold structure resulted in high purity cobalt and nickel products.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Yan Xu, Jingai Jiang, Xinyi Lv, Hui Li, Dongliang Yang, Wenjun Wang, Yanling Hu, Longcai Liu, Xiaochen Dong, Yu Cai
Summary: A programmed gas release nanoparticle was developed to address the challenges in treating diabetic infected wounds. It effectively removes drug-resistant pathogens and remodels the wound microenvironment using NO and H2S. The nanoparticle can eliminate bacteria and promote wound healing through antibacterial and anti-inflammatory effects.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Tong Xia, Zhilin Xi, Lianquan Suo, Chen Wang
Summary: This study investigated a highly efficient coal dust suppressant with low initial viscosity and high adhesion-solidification properties. The results demonstrated that the dust suppressant formed a network of multiple hydrogen bonding cross-linking and achieved effective adhesion and solidification of coal dust through various chemical reactions.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Jinzhi Cai, Zhenshan Li
Summary: A density functional theory-based rate equation was developed to predict the gas-solid reaction kinetics of CaO carbonation with CO2 in calcium looping. The negative activation energy of CaO carbonation close to equilibrium was accurately predicted through experimental validation.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Jianxiong Chen, Fuhao Ren, Ningning Yin, Jie Mao
Summary: This study presents an economically efficient and easily implementable surface modification approach to enhance the high-temperature electrical insulation and energy storage performance of polymer dielectrics. The self-assembly of high-insulation-performance boron nitride nanosheets (BNNS) on the film surface through electrostatic interactions effectively impedes charge injection from electrodes while promoting charge dissipation and heat transfer.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Zijian Li, Zhaohui Yang, Shao Wang, Hongxia Luo, Zhimin Xue, Zhenghui Liu, Tiancheng Mu
Summary: This study reports a strategy for upgrading polyester plastics into value-added chemicals using electrocatalytic methods. By inducing the targeted transfer of *OH species, polyethylene terephthalate was successfully upgraded into potassium diformate with high purity. This work not only develops an excellent electrocatalyst, but also provides guidance for the design of medium entropy metal oxides.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Navneet Singh Shekhawat, Surendra Kumar Patra, Ashok Kumar Patra, Bamaprasad Bag
Summary: This study primarily focuses on developing a sulphur dyeing process at room temperature using bacterial Lysate, which is environmentally friendly, energy and cost effective, and sustainable. The process shows promising improvements in dye uptake and fastness properties.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Dengjia Shen, Hongyang Ma, Madani Khan, Benjamin S. Hsiao
Summary: This study developed cationic PVC nanofibrous membranes with high filtration and adsorption capability for the removal of bacteria and hexavalent chromium ions from wastewater. The membranes demonstrated remarkable performance in terms of filtration efficiency and maximum adsorption capacity. Additionally, modified nanofibrous membranes were produced using recycled materials and showed excellent retention rates in dynamic adsorption processes.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Xiaoyan Wang, Zhikun Wang, Ben Jia, Chunling Li, Shuangqing Sun, Songqing Hu
Summary: Inspired by photosystem II, self-supported Fe-doped NiCoP nanowire arrays modified with carboxylate were constructed to boost industrial-level overall water splitting by employing the concerted proton-coupled electron transfer mechanism. The introduction of Fe and carboxyl ligand led to improved catalytic activity for HER and OER, and NCFCP@NF exhibited long-term durability for overall water splitting.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Pengyao Yu, Ge Yang, Yongming Chai, Lubomira Tosheva, Chunzheng Wang, Heqing Jiang, Chenguang Liu, Hailing Guo
Summary: Thin LTA zeolite membranes were prepared through secondary growth of nano LTA seeds in a highly reactive gel, resulting in membranes with superior permeability and selectivity in gas separation applications.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Baiqin Zhou, Huiping Li, Ziyu Wang, Hui Huang, Yujun Wang, Ruichun Yang, Ranran Huo, Xiaoyan Xu, Ting Zhou, Xiaochen Dong
Summary: The use of machine learning to predict the performance of specific adsorbents in phosphate adsorption shows great promise in saving time and revealing underlying mechanisms. However, the small size of the dataset and insufficient detailed information limits the model training process and the accuracy of results. To address this, the study employs a fuzzing strategy that replaces detailed numeric information with descriptive text messages on the physiochemical properties of adsorbents. This strategy allows the recovery of discarded samples with limited information, leading to accurate prediction of adsorption amount, capacity, and kinetics. The study also finds that phosphate uptake by adsorbents is generally through physisorption, with some involvement of chemisorption. The framework established in this study provides a practical approach for quickly predicting phosphate adsorption performance in urgent scenarios, using easily accessible information.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Paula Alejandra Lamprea Pineda, Joren Bruneel, Kristof Demeestere, Lisa Deraedt, Tex Goetschalckx, Herman Van Langenhove, Christophe Walgraeve
Summary: This study evaluates the use of four esterified fatty acids and three vegetable oils as absorption liquids for hydrophobic VOCs. The experimental results show that isopropyl myristate is the most efficient liquid for absorbing the target VOCs.
CHEMICAL ENGINEERING JOURNAL
(2024)
