期刊
CHEMICAL ENGINEERING JOURNAL
卷 244, 期 -, 页码 531-539出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2014.02.005
关键词
LaOBr:Er3+; Nanofiber; Nanoribbon; Up-conversion luminescence; Electrospinning
资金
- National Natural Science Foundation of China [NSFC 50972020, 51072026]
- Specialized Research Fund for the Doctoral Program of Higher Education [20102216110002, 20112216120003]
- Science and Technology Development Planning Project of Jilin Province [20130101001JC, 20070402, 20060504]
- Research Project of Science and Technology of Department of Education of Jilin Province 11th 5-year plan [2010JYT01]
- Key Research Project of Science and Technology of Ministry of Education of China [207026]
LaOBr:Er3+ nanofibers and nanoribbons were synthesized for the first time via calcinating the respective electrospun PVP/[La(NO3)(3) + Er(NO3)(3) + NH4Br] composites. The morphology, structure and luminescent properties of the final products were investigated in detail by field emission scanning electron microscopy (FESEM), energy dispersion spectroscopy (EDS), X-ray diffractometry (XRD) and fluorescence spectroscopy. The diameter of the LaOBr:Er3+ nanofibers with the pure tetragonal crystal phase are ca. 144.36 nm. The width and the thickness of LaOBr:Er3+ nanoribbons with the pure tetragonal in structure are ca. 5.66 mu n and 151 nm, respectively. Under the excitation of a 980-nm diode laser, LaOBr:Er3+ nanofibers and nanoribbons exhibit the characteristic up-conversion emissions of Er3+ ions, and the optimum doping concentration of Er3+ ions in the LaOBr:Er3+ nanofibers and nanoribbons is 3.0%. Interestingly, the luminescence intensity of LaOBr:Er3+ nanoribbons is obviously stronger than that of LaOBr:Er3+ nanofibers under the same measuring conditions. The color emissions of LaOBr:Er3+ nanostructures can be tuned from green emission to yellow emission by changing the concentration of doping Er3+ ions and the morphologies of nanostructures. Moreover, the predominant near-infrared emission at 1.50 mu m of LaOBr:Er3+ nanostructures are obtained under the excitation of a 532-nm laser. The formation mechanisms of LaOBr:Er3+ nanofibers and nanoribbons are also proposed. Electrospinning is a simple and efficient method for the synthesis of luminescent LaOBr:Er3+ nanostructures, which would be promising up-conversion luminescent nanomaterials. (C) 2014 Elsevier B.V. All rights reserved.
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